工业水处理 ›› 2019, Vol. 39 ›› Issue (7): 42-45. doi: 10.11894/iwt.2018-0621

• 试验研究 • 上一篇    下一篇

活化剂对活性炭处理矿山废水Mn2+的影响研究

周剑林(),刘伟银,冯涛*(),曹运江,陈章,李志贤,陈国梁,陈远其   

  1. 湖南科技大学煤炭资源清洁利用与矿山环境保护湖南省重点实验室, 湖南湘潭 411201
  • 收稿日期:2019-04-26 出版日期:2019-07-20 发布日期:2019-08-07
  • 通讯作者: 冯涛 E-mail:jianlinzhou@hnust.edu.cn;tfeng@hnust.edu.cn
  • 作者简介:周剑林(1982-),博士,讲师。电话:0731-58290339, E-mail:jianlinzhou@hnust.edu.cn
  • 基金资助:
    国家自然科学基金资助项目(31671635);湖南省科技厅资助项目(2017SK2385);湖南省科技厅资助项目(018JJ2114)

Effect of activators on adsorption ability of activated carbon to Mn2+ in mine wastewater

Jianlin Zhou(),Weiyin Liu,Tao Feng*(),Yunjiang Cao,Zhang Chen,Zhixian Li,Guoliang Chen,Yuanqi Chen   

  1. Hunan Province Key Lab of Coal Clean Utilization and Environment Protection, Hunan University of Science and Technology, Xiangtan 411201, China
  • Received:2019-04-26 Online:2019-07-20 Published:2019-08-07
  • Contact: Tao Feng E-mail:jianlinzhou@hnust.edu.cn;tfeng@hnust.edu.cn
  • Supported by:
    国家自然科学基金资助项目(31671635);湖南省科技厅资助项目(2017SK2385);湖南省科技厅资助项目(018JJ2114)

摘要:

采用HCl、KCl、NaOH和Fe(NO33四种活化剂预处理褐煤,制备得到了活性炭吸附剂,分析了不同活化剂处理获得的褐煤活性炭的比表面积、孔容和吸附性能,研究了不同活化剂处理对活性炭吸附废水中Mn2+的影响。结果表明:负载KCl制备得到的煤基活性炭比表面积和孔容最大;在吸附剂投加量为5 g,温度为25℃,pH=7,吸附时间为60 min时,对水体中的Mn2+去除率顺序为:K-AC > Na-AC > H-AC > SL-AC > Fe-AC,K-AC对Mn2+的去除率达到97.4%。

关键词: 褐煤, 催化, 活性炭制备, 矿山废水, Mn2+吸附

Abstract:

The activated carbon adsorbents were prepared by pretreatment of lignite with HCl, KCl, NaOH and Fe(NO3)3 activators. The specific surface area, pore volume and adsorption properties of lignite activated carbon obtained by different activator treatments were analyzed. The effects of different activator treatment on the adsorption of Mn2+ in wastewater by activated carbon were also studied. The results showed that the specific surface area and pore volume of the coal-based activated carbon prepared by loading KCl was the largest, when the adsorbent dosage was 5 g, the temperature was 25℃, the pH was 7 and the adsorption time was 60 min, the order of the removal rates of Mn2+ in the water was:K-AC > Na-AC > H-AC > SL-AC > Fe-AC, and the removal rate of Mn2+ by K-AC reached 97.4%.

Key words: lignite, catalysis, activated carbon preparation, mine wastewater, Mn2+ adsorption

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