诱导结晶法回收磷的影响因素及应用研究进展

doi:10.19965/j.cnki.iwt.2023-0926

摘要/Abstract

摘要：

随着社会经济的发展和人类频繁的工业活动，磷逐渐从磷矿石转变为磷酸盐进入水体，废水中磷的存在会导致水体污染和富营养化。由于磷酸盐岩体消耗量不断增加，磷矿资源逐渐成为一种稀缺资源，磷的回收再利用具有重大意义，而含磷废水被认为是一种潜在的磷回收源。借用反应器的诱导结晶法具有设计简单、操作简便、回收效率高、对环境影响小等优点，是一种理想的磷回收方法。首先从动力学和热力学角度简要描述了诱导结晶法的原理，其次分析了羟基磷灰石（HAP）和鸟粪石（MAP）两种常用的诱导结晶法回收磷的影响因素，包括过饱和度、酸碱度（pH）、离子物质的量比、水力停留时间（HRT）、上升流速以及反应器类型等，再次介绍了两种诱导结晶法在实际回收磷领域的应用，最后对诱导结晶法回收利用磷资源的发展前景及工艺应用条件优化进行了展望。

关键词: 磷酸盐, 反应器, 诱导结晶, 磷回收, 羟基磷灰石, 鸟粪石

Abstract:

With the development of economy and frequent industrial activities by humans, phosphorus is gradually transformed from phosphate ore to phosphate and into water bodies. The presence of phosphorus in wastewater can lead to water pollution and eutrophication. Moreover, due to the increasing consumption of phosphate rock, phosphate ore resources have gradually become a scarce resource. Therefore, the recycling and reuse of phosphorus resources is of great significance, and phosphorus containing wastewater is considered a potential source for phosphorus recovery. The induced crystallization method using a reactor for phosphorus resource recovery has the advantages of simple design, easy operation, high recovery efficiency, and minimal environmental impact, which makes it an ideal phosphorus recovery method. Firstly, the principle of induced crystallization method was briefly described from the perspectives of kinetics and thermodynamics. Secondly, the influencing factors of two commonly used induced crystallization methods, hydroxyapatite(HAP) and microbially available phosphorus(MAP), for phosphorus recovery were analyzed, including supersaturation, pH, ion ratio, hydraulic retention time(HRT), rising flow rate, and reactor type. Thirdly, the application of the two induced crystallization methods in the actual field of phosphorus recovery was introduced. Finally, the development prospects and optimization of process application conditions for the recovery and utilization of phosphorus resources by induced crystallization method were discussed.

Key words: phosphate, reactor, induced crystallization, phosphorus recovery, hydroxyapatite, microbially available phosphorus

中图分类号:

X703

齐震, 刘汝鹏, 徐林煦, 房金峰, 朱炜臣, 樊浩宇, 乔一木. 诱导结晶法回收磷的影响因素及应用研究进展[J]. 工业水处理, 2024, 44(9): 41-49.

Zhen QI, Rupeng LIU, Linxu XU, Jinfeng FANG, Weichen ZHU, Haoyu FAN, Yimu QIAO. Research on influencing factors and application of phosphorus recovery by induced crystallization method[J]. Industrial Water Treatment, 2024, 44(9): 41-49.

https://www.iwt.cn/CN/Y2024/V44/I9/41

图/表 2

参考文献 63

1	刘艳飞. 中国磷矿供需趋势研究［D］. 北京：中国地质大学（北京），2016.
	LIU Yanfei. Study on supply and demand trend of phosphate rock in China［D］. Beijing：China University of Geosciences，2016.
2	刘颐华. 我国与世界磷资源及开发利用现状［J］. 磷肥与复肥，2005，20（5）：1-5.
	LIU Yihua. Phosphorus resources at home & abroad，and the currents ituation of their exploitation & utilization［J］. Phosphate & Compound Fertilizer，2005，20（5）：1-5.
3	胡慧蓉，郭安，王海龙. 我国磷资源利用现状与可持续利用的建议［J］. 磷肥与复肥，2007，22（2）：1-5.
	HU Huirong， GUO An， WANG Hailong. Present status of China’s phosphorus resource utilization & some suggestions for sustainable development［J］. Phosphate & Compound Fertilizer，2007，22（2）：1-5.
4	DOCKX L， CALUWÉ M， DE VLEESCHAUWER F，et al. Impact of the substrate composition on enhanced biological phosphorus removal during formation of aerobic granular sludge［J］. Bioresource Technology，2021，337：125482. doi:10.1016/j.biortech.2021.125482
5	李航，董立春，方建飞，等. 初沉池优化运行对改良型A²/O工艺脱氮除磷的影响［J］. 环境工程技术学报，2021，11（6）：1189-1195.
	LI Hang， DONG Lichun， FANG Jianfei，et al. Effect of optimizing operation of primary sedimentation tank on nitrogen and phosphorus removal of modified A²/O process［J］. Journal of Environmental Engineering Technology，2021，11（6）：1189-1195.
6	贾胜男，周锐，赵福祥，等. 同步化学除磷对A²O性能影响及微生物特性研究［J］. 水处理技术，2021，47（10）：99-103.
	JIA Shengnan， ZHOU Rui， ZHAO Fuxiang，et al. Study on effect of simultaneous chemical phosphorus removal on A²O performance and microbial characteristics［J］. Technology of Water Treatment，2021，47（10）：99-103.
7	ZOU Haiming， WANG Yan. Optimization of induced crystallization reaction in a novel process of nutrients removal coupled with phosphorus recovery from domestic wastewater［J］. Archives of Environmental Protection，2017，43（4）：33-38. doi:10.1515/aep-2017-0037
8	傅浩洋，盛杰，凌岚. 无机物结晶新视角：非经典成核与生长［J］. 科学通报，2021，66（33）：4256-4267. doi:10.1360/tb-2021-0197
	FU Haoyang， SHENG Jie， LING Lan. A new perspective of inorganic crystallization：Non-classical nucleation and growth［J］. Chinese Science Bulletin，2021，66（33）：4256-4267. doi:10.1360/tb-2021-0197
9	任文芝，强伟丽，廉士俊，等. 碳酸镁结晶过程离子团簇与扩散成核机制［J］. 无机盐工业，2022，54（3）：51-58.
	REN Wenzhi， QIANG Weili， LIAN Shijun，et al. Ionic clusters and diffusion nucleation mechanism during crystallization of magnesium carbonate［J］. Inorganic Chemicals Industry，2022，54（3）：51-58.
10	TURNBULL D， FISHER J C. Rate of nucleation in condensed systems［J］. The Journal of Chemical Physics，1949，17（1）：71-73. doi:10.1063/1.1747055
11	GUAN W， JI F Y， CHEN Q K，et al. Phosphorus recovery using porous calcium silicate hydrate as seed crystal in form of hydroxyapatite［J］. Materials Research Innovations，2014，18（1）：43-49. doi:10.1179/1433075x13y.0000000112
12	CHEN Yunnen， LIU Chen， GUO Lin，et al. Removal and recovery of phosphate anion as struvite from wastewater［J］. Clean Technologies and Environmental Policy，2018，20（10）：2375-2380. doi:10.1007/s10098-018-1607-2
13	DANESHGAR S， BUTTAFAVA A， CALLEGARI A，et al. Economic and energetic assessment of different phosphorus recovery options from aerobic sludge［J］. Journal of Cleaner Production，2019，223：729-738. doi:10.1016/j.jclepro.2019.03.195
14	SONG Yonghui， QIU Guanglei， YUAN Peng，et al. Nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization without chemical additions［J］. Journal of Hazardous Materials，2011，190（1/2/3）：140-149. doi:10.1016/j.jhazmat.2011.03.015
15	KIM D， RYU H D， KIM M S，et al. Enhancing struvite precipitation potential for ammonia nitrogen removal in municipal landfill leachate［J］. Journal of Hazardous Materials，2007，146（1/2）：81-85. doi:10.1016/j.jhazmat.2006.11.054
16	YOU J， GREENMAN J， MELHUISH C，et al. Electricity generation and struvite recovery from human urine using microbial fuel cells［J］. Journal of Chemical Technology & Biotechnology，2016，91（3）：647-654. doi:10.1002/jctb.4617
17	SONG Yonghui， YUAN Peng， ZHENG Binghui，et al. Nutrients removal and recovery by crystallization of magnesium ammonium phosphate from synthetic swine wastewater［J］. Chemosphere，2007，69（2）：319-324. doi:10.1016/j.chemosphere.2007.06.001
18	GONG Weijia， LI Yan， LUO Lina，et al. Application of struvite-MAP crystallization reactor for treating cattle manure anaerobic digested slurry：Nitrogen and phosphorus recovery and crystal fertilizer efficiency in plant trials［J］. International Journal of Environmental Research and Public Health，2018，15（7）：1397. doi:10.3390/ijerph15071397
19	LIU Zhigang， ZHAO Qingliang， LEE D J，et al. Enhancing phosphorus recovery by a new internal recycle seeding MAP reactor［J］. Bioresource Technology，2008，99（14）：6488-6493. doi:10.1016/j.biortech.2007.11.039
20	LE ROUZIC M， CHAUSSADENT T， PLATRET G，et al. Mechanisms of k-struvite formation in magnesium phosphate cements［J］. Cement and Concrete Research，2017，91：117-122. doi:10.1016/j.cemconres.2016.11.008
21	PASTOR L， MANGIN D， BARAT R，et al. A pilot-scale study of struvite precipitation in a stirred tank reactor：Conditions influencing the process［J］. Bioresource Technology，2008，99（14）：6285-6291. doi:10.1016/j.biortech.2007.12.003
22	SONG Y， HAHN H H， HOFFMANN E. The effect of carbonate on the precipitation of calcium phosphate［J］. Environmental Technology，2002，23（2）：207-215. doi:10.1080/09593332508618427
23	YANG C W， LUI T S. Kinetics of hydrothermal crystallization under saturated steam pressure and the self-healing effect by nanocrystallite for hydroxyapatite coatings［J］. Acta Biomaterialia，2009，5（7）：2728-2737. doi:10.1016/j.actbio.2009.03.014
24	MOKONE T P， VAN HILLE R P， LEWIS A E. Metal sulphides from wastewater：Assessing the impact of supersaturation control strategies［J］. Water Research，2012，46（7）：2088-2100. doi:10.1016/j.watres.2012.01.027
25	KARAPINAR N， HOFFMANN E， HAHN H H. P-recovery by secondary nucleation and growth of calcium phosphates on magnetite mineral［J］. Water Research，2006，40（6）：1210-1216. doi:10.1016/j.watres.2005.12.041
26	LIU Xin， PAN Haobo， FU Hailuo，et al. Conversion of borate-based glass scaffold to hydroxyapatite in a dilute phosphate solution［J］. Biomedical Materials，2010，5（1）：15005. doi:10.1088/1748-6041/5/1/015005
27	DAI Hongliang， LU Xiwu， PENG Yonghong，et al. Effects of supersaturation control strategies on hydroxyapatite（HAP） crystallization for phosphorus recovery from wastewater［J］. Environmental Science and Pollution Research，2017，24（6）：5791-5799. doi:10.1007/s11356-016-8236-2
28	COSTODES V C T， LEWIS A E. Reactive crystallization of nickel hydroxy-carbonate in fluidized-bed reactor：Fines production and column design［J］. Chemical Engineering Science，2006，61（5）：1377-1385. doi:10.1016/j.ces.2005.08.038
39	PAN H B， DARVELL B W. Solubility of hydroxyapatite by solid titration at pH 3-4［J］. Archives of Oral Biology，2007，52（7）：618-624. doi:10.1016/j.archoralbio.2006.12.007
30	ZHANG Tao， DING Lili， REN Hongqiang，et al. Thermodynamic modeling of ferric phosphate precipitation for phosphorus removal and recovery from wastewater［J］. Journal of Hazardous Materials，2010，176（1/2/3）：444-450. doi:10.1016/j.jhazmat.2009.11.049
31	CRUTCHIK D， GARRIDO J M. Kinetics of the reversible reaction of struvite crystallisation［J］. Chemosphere，2016，154：567-572. doi:10.1016/j.chemosphere.2016.03.134
32	MATYNIA A， KORALEWSKA J， WIERZBOWSKA B，et al. The influence of process parameters on struvite continuous crystallization kinetics［J］. Chemical Engineering Communications，2006，193（2）：160-176. doi:10.1080/009864490949008
33	RAHMAN M M， SALLEH M A M， RASHID U，et al. Production of slow release crystal fertilizer from wastewaters through struvite crystallization：A review［J］. Arabian Journal of Chemistry，2014，7（1）：139-155. doi:10.1016/j.arabjc.2013.10.007
34	LE CORRE K S， VALSAMI-JONES E， HOBBS P，et al. Struvite crystallisation and recovery using a stainless steel structure as a seed material［J］. Water Research，2007，41（11）：2449-2456. doi:10.1016/j.watres.2007.03.002
35	刘旭东，何欧文，陈艳红，等. 骨碳诱导HAP结晶除磷的影响因素研究［J］. 沈阳建筑大学学报（自然科学版），2015，31（5）：944-951.
	LIU Xudong， HE Ouwen， CHEN Yanhong，et al. Study of influence factors on phosphorus removal from wastewater with bone charcoal using induced HAP crystallization process［J］. Journal of Shenyang Jianzhu University（Natural Science），2015，31（5）：944-951.
36	KULKARNI S A， KADAM S S， MEEKES H，et al. Crystal nucleation kinetics from induction times and metastable zone widths［J］. Crystal Growth & Design，2013，13（6）：2435-2440. doi:10.1021/cg400139t
37	LI Yanbo， QIU Liping. Phosphorus removal and recovery in novel seed crystal media filter［J］. Applied Mechanics and Materials，2011，90/91/92/93：2969-2972. doi:10.4028/www.scientific.net/amm.90-93.2969
38	BELLIER N， CHAZARENC F， COMEAU Y. Phosphorus removal from wastewater by mineral apatite［J］. Water Research，2006，40（15）：2965-2971. doi:10.1016/j.watres.2006.05.016
39	CHEN Xuechu， KONG Hainan， WU Deyi，et al. Phosphate removal and recovery through crystallization of hydroxyapatite using xonotlite as seed crystal［J］. Journal of Environmental Sciences（China），2009，21（5）：575-580. doi:10.1016/s1001-0742(08)62310-4
40	YU Rongtai， GENG Jinju， REN Hongqiang，et al. Struvite pyrolysate recycling combined with dry pyrolysis for ammonium removal from wastewater［J］. Bioresource Technology，2013，132：154-159. doi:10.1016/j.biortech.2013.01.015
41	JIANG J Q， WU L. Preliminary study of calcium silicate hydrate（tobermorite） as crystal material to recovery phosphate from wastewater［J］. Desalination and Water Treatment，2010，23（1/2/3）：49-54. doi:10.5004/dwt.2010.1866
42	SU C C， ABARCA R R M， DE LUNA M D G，et al. Phosphate recovery from fluidized-bed wastewater by struvite crystallization technology［J］. Journal of the Taiwan Institute of Chemical Engineers，2014，45（5）：2395-2402. doi:10.1016/j.jtice.2014.04.002
43	李钰泽，张守彬，杨焱明，等. 废水流化床结晶除磷工况优化及效能稳定性［J］. 环境化学，2020，39（8）：2187-2195.
	LI Yuze， ZHANG Shoubin， YANG Yanming，et al. Efficiency stability and operating conditions optimization of phosphorus removal by crystallization in wastewater fluidized bed reactor［J］. Environmental Chemistry，2020，39（8）：2187-2195.
44	FATTAH K P， MAVINIC D S， KOCH F A. Influence of process parameters on the characteristics of struvite pellets［J］. Journal of Environmental Engineering，2012，138（12）：1200-1209. doi:10.1061/(asce)ee.1943-7870.0000576
45	CADDARAO P S， GARCIA-SEGURA S， BALLESTEROS F C JR，et al. Phosphorous recovery by means of fluidized bed homogeneous crystallization of calcium phosphate. Influence of operational variables and electrolytes on brushite homogeneous crystallization［J］. Journal of the Taiwan Institute of Chemical Engineers，2018，83：124-132. doi:10.1016/j.jtice.2017.12.009
46	CASTRO F， FERREIRA A， ROCHA F，et al. Characterization of intermediate stages in the precipitation of hydroxyapatite at 37 ℃［J］. Chemical Engineering Science，2012，77：150-156. doi:10.1016/j.ces.2012.01.058
47	DAI Hongliang， LU Xiwu， PENG Yonghong，et al. An efficient approach for phosphorus recovery from wastewater using series-coupled air-agitated crystallization reactors［J］. Chemosphere，2016，165：211-220. doi:10.1016/j.chemosphere.2016.09.001
48	YE Xin， YE Zhilong， LOU Yaoyin，et al. A comprehensive understanding of saturation index and upflow velocity in a pilot-scale fluidized bed reactor for struvite recovery from swine wastewater［J］. Powder Technology，2016，295：16-26. doi:10.1016/j.powtec.2016.03.022
49	邓权庆，聂小保，万俊力，等. 诱导结晶反应器型式对低磷污水磷回收的影响［J］. 中国环境科学，2023，43（5）：2296-2302.
	DENG Quanqing， NIE Xiaobao， WAN Junli，et al. Influences of induced crystallization reactor styles on phosphorous recovery from low phosphorous sewage［J］. China Environmental Science，2023，43（5）：2296-2302.
50	LU Yongsheng， LIU Hui， FENG Wei，et al. A new and efficient approach for phosphorus recovery from wastewater in the form of vivianite mediated by iron-reducing bacteria［J］. Journal of Water Process Engineering，2021，42：102200. doi:10.1016/j.jwpe.2021.102200
51	肖辉毅，聂小保，万俊力，等. HAP诱导磷酸钙结晶回收低磷污水中的磷［J］. 中国环境科学，2022，42（4）：1681-1687.
	XIAO Huiyi， NIE Xiaobao， WAN Junli，et al. Phosphorous recovery from wastewater with low phosphorous concentration by means of HAP-seeded crystallization of calcium phosphate［J］. China Environmental Science，2022，42（4）：1681-1687.
52	JANG H， KANG S H. Phosphorus removal using cow bone in hydroxyapatite crystallization［J］. Water Research，2002，36（5）：1324-1330. doi:10.1016/s0043-1354(01)00329-3
53	KIM E H， LEE D W， HWANG H K，et al. Recovery of phosphates from wastewater using converter slag：Kinetics analysis of a completely mixed phosphorus crystallization process［J］. Chemosphere，2006，63（2）：192-201. doi:10.1016/j.chemosphere.2005.08.029
54	邱琪，卢立泉，赵保卫，等. 流化床结晶反应器回收化粪池污水中氮、磷的研究［J］. 中国给水排水，2018，34（13）：14-19.
	QIU Qi， LU Liquan， ZHAO Baowei，et al. Recovery of nitrogen and phosphorus from septic tank wastewater by fluidized bed crystallization reactor［J］. China Water & Wastewater，2018，34（13）：14-19.
55	周梨. 污水厂尾水的流化床诱导HAP结晶除磷技术研究［D］. 长沙：长沙理工大学，2020.
	ZHOU Li. Research on phosphorus removal technology of the effluent based on HAP crystallization with FBR［D］. Changsha：Changsha University of Science & Technology，2020.
56	KIM D， KIM J， RYU H D，et al. Effect of mixing on spontaneous struvite precipitation from semiconductor wastewater［J］. Bioresource Technology，2009，100（1）：74-78. doi:10.1016/j.biortech.2008.05.024
57	刘小宁，胡正义，王金枝，等. 水力停留时间和搅拌速率对搅拌反应器回收尿液中磷的研究［J］. 环境科学学报，2014，34（1）：67-72.
	LIU Xiaoning， HU Zhengyi， WANG Jinzhi，et al. Effect of hydraulic retention time and stirring speed on phosphorus recovery from urine in a stirred reactor［J］. Acta Scientiae Circumstantiae，2014，34（1）：67-72.
58	EGLE L， RECHBERGER H， KRAMPE J，et al. Phosphorus recovery from municipal wastewater：An integrated comparative technological，environmental and economic assessment of P recovery technologies［J］. Science of the Total Environment，2016，571：522-542. doi:10.1016/j.scitotenv.2016.07.019
59	郭杰，曾光明，张盼月，等. 结晶法磷回收工艺在废水处理中的应用［J］. 水处理技术，2006，32（10）：1-4.
	GUO Jie， ZENG Guangming， ZHANG Panyue，et al. Application of crystallization technologies for phosphorus recovery in wastewater treatment［J］. Technology of Water Treatment，2006，32（10）：1-4.
60	DUAN Jinming， CAO Yinlan， HE Biyan. Phosphates recovery through hydroxyapatite crystallization from wastewater using converter slag as a seed crystal［C］//2010 4th International Conference on Bioinformatics and Biomedical Engineering. Chengdu，China. IEEE，2010：1-4. doi:10.1109/icbbe.2010.5518291
61	万锐，吕锡武，朱光灿，等. 诱导结晶法回收磷的试验研究［J］. 中国给水排水，2009，25（15）：82-85.
	WAN Rui， Xiwu LÜ， ZHU Guangcan，et al. Study on phosphorus recovery by induced crystallization［J］. China Water & Wastewater，2009，25（15）：82-85.
62	SUZUKI K， TANAKA Y， KURODA K，et al. Removal and recovery of phosphorous from swine wastewater by demonstration crystallization reactor and struvite accumulation device［J］. Bioresource Technology，2007，98（8）：1573-1578. doi:10.1016/j.biortech.2006.06.008
63	WANG Jinsong， YE Xin， ZHANG Zhaoji，et al. Selection of cost-effective magnesium sources for fluidized struvite crystallization［J］. Journal of Environmental Sciences（China），2018，70：144-153. doi:10.1016/j.jes.2017.11.029

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