INDUSTRIAL WATER TREATMENT ›› 2002, Vol. 22 ›› Issue (12): 21-23. doi: 10.11894/1005-829x.2002.22(12).21

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Study and optimization on treatment of wastewater containing phenol and formaldehyde

YAO Lin, YU Ping, LUO Yunbai, LIAO Dongmei   

  1. College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China
  • Received:2002-06-07 Online:2002-12-20 Published:2010-10-01

酚醛废水预处理工艺优化的试验研究

姚琳, 于萍, 罗运柏, 廖冬梅   

  1. 武汉大学化学与分子科学学院, 湖北武汉 430072
  • 作者简介:姚琳(1978- ),2000年武汉大学硕士研究生,主要从事水和废水处理及水质分析方面的研究.E-mail:sunningsmile@163.com.

Abstract:

The wastewater from a phenolic resins plant is treated by urea-phenol-formaldehyde basic co-condensation process.Based on uniform design and regression analysis,the effect of factors such as proportioning,catalyst,temperature and time of reaction on processing results is investigated.The optimum process is gained.After purified,99.8 %of phenol and 99.2 % of formaldehyde in the wastewater can be removed.The output meets the need of biological treatment,and a certain amount of phenolic resins can also be recovered.The optimization method can also be applied to increasing the yield of phenolic resins production

Key words: uniform design, regression analysis, wastewater containing phenol and formaldehyde, optimization

摘要:

以某酚醛树脂厂的生产废水为对象,采用尿素-苯酚-甲醛碱性缩合预处理工艺,基于均匀设计和回归分析,建立了多元回归模型,研究了配比、催化剂、反应时间及温度等因素对处理效果的影响,优化了预处理的工艺条件,酚、醛去除率分别可达99。8%、99。2%,出水可满足进一步进行生化处理的要求,并可回收苯酚改性脲醛树脂。同时,还为提高酚醛树脂合成产率提供了有效的优化思路,可从根本上降低树脂厂生产废水中酚、醛的污染程度。

关键词: 均匀设计, 回归分析, 酚醛废水, 优化

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