Research progress in the removal of alkyl-phenol substances from water bodies

doi:10.11894/1005-829x.2014.34(7).010

Abstract

Abstract: Alkyl-phenol substances are characterized by good chemical stability, refractory degradation and no volatility. They are widely distributed in water bodies, have estrogen effect and can interfere endocrine function of organism. The methods for treating the wastewater containing this kind of substances and research progress both in China and abroad are summarized. The experimental conditions, removing effectiveness, and limitation of methods for the removal of alkyl-phenol substances by methods, such as microbial degradation, advanced oxidation, adsorption technology etc. are expounded. The research emphasis and direction of this field are pointed out. It is put forward that combined technology in the future should be the research hotspot of the treatment of wastewater containing alkyl-phenol substances.

Key words: alkyl phenol, adsorption, advanced oxidation

摘要： 烷基酚类物质化学稳定性好，不易挥发且难降解，广泛分布于水体中，具有雌性激素效应，能扰乱生物体内的内分泌功能。就目前国内外处理含此类物质的废水去除方法及研究进展进行了综述，阐述了微生物降解法、高级氧化法、吸附法等应用于烷基酚类物质去除时的实验条件和去除效果及方法的局限性，指出了该领域的研究重点及方向，提出了联合工艺应用是未来处理含烷基酚废水的研究热点。

关键词: 烷基酚, 吸附, 高级氧化

CLC Number:

X703.1

Fan Ronggui, Li Mei, Gao Haijuan, Chen Yao, Dong Shuangshuang. Research progress in the removal of alkyl-phenol substances from water bodies[J]. INDUSTRIAL WATER TREATMENT, 2014, 34(7): 10-14.

范荣桂, 李美, 高海娟, 陈瑶, 董双双. 水体中烷基酚类物质的去除研究进展[J]. 工业水处理, 2014, 34(7): 10-14.

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https://www.iwt.cn/EN/Y2014/V34/I7/10

References

[1] 杨颖,黄国兰,孙红文. 烷基酚和烷基酚聚氧乙烯醚的环境行为[J]. 安全与环境学报,2005,5(6):38-43.

[2] Stasinakis A S,Kordoutis C I,Tsiouma V C,et al. Removal of selected endocrine disrupters in activated sludge systems:Effect of sludge retention time on their sorption and biodegradation[J]. Bioresource Technology,2010,101(7):2090-2095.

[3] Hayashi S,Saito S,Kim J H. Aerobic biodegradation behavior of nonylphenol polyethoxylates and their metabolites in the presence of organic matter[J]. Environmental Science & Technology,2005,39 (15):5626-5633.

[4] Del Rio J G,Hayes D G,Urban V S. Partitioning behavior of an acid-cleavable,1,3-dioxolane alkyl ethoxylate,surfactant in single and binary surfactant mixtures for 2-and 3-phase microemulsion systems according to ethoxylate head group size[J]. Journal of Colloid and Interface Science,2010,352(2):424-435.

[5] Liu Guangming,Zheng Shourong,Yin Daqiang,et al. Adsorption of aqueous alkylphenol ethoxylate surfactants by mesoporous carbon CMK-3[J]. Journal of Colloid and Interface Science,2006,302(1): 47-53.

[6] 刘光明,尹大强. 黏土矿物对烷基酚聚氧乙烯醚的吸附行为[J]. 生态环境,2008,17(2):593-597.

[7] 刘易,夏四清,陈玲,等. 烷基酚类内分泌干扰物污染现状及去除研究进展[J]. 净水技术,2007,26(6):7-10.

[8] 赵娟,吕剑,何义亮,等. 1株异养脱氮菌降解壬基酚聚氧乙烯醚的研究[J]. 环境科学,2008,29(7):1977-1981.

[9] 张志刚,徐德强,李光明,等. 固定化优势菌种降解2,6-二叔丁基酚[J]. 中国环境科学,2005,25(1):57-60.

[10] 蒋俊,李秀艳,赵雅萍. 2株分别降解壬基酚和双酚A细菌的分离、鉴定和降解特性[J]. 环境科学研究,2010,23(9):1196-1203.

[11] Tuan N N,Lin Y W,Huang S L. Catabolism of 4-alkylphenols by Acinetobacter sp. OP5:Genetic organization of the oph gene cluster and characterization of alkylcatechol 2,3-dioxygenase[J]. Biore-source Technology,2013,131:420-428.

[12] 古新,张昱,张晶,等. Rhodobacter sp. NP25b菌株缺氧降解壬基酚聚氧乙烯醚的研究[J]. 环境工程学报,2008,2(7):880-885.

[13] 颜丙花,杨海君,魏建宏. 制革废水中壬基酚聚氧乙烯醚降解菌的分离及特性[J]. 微生物学通报,2011,38(5):750-757.

[14] 刘易. 低浓度辛基酚的好氧生物降解特性和群落多样性[J]. 环境科学学报,2012,32(3):590-594.

[15] 乔大磊. 膜生物反应器-纳滤耦合去除壬基酚聚氧乙烯醚[J]. 水处理技术,2010,36(5):107-110.

[16] 胡翔,李进,皮运正,等. 臭氧氧化水中壬基酚的反应机理研究[J]. 环境科学,2007,28(3):584-587.

[17] Nagarnaik P M,Boulanger B. Advanced oxidation of alkylphenol ethoxylates in aqueous systems[J]. Chemosphere,2011,85(5):854-860.

[18] 刘光明,魏芳,余华锋. 烷基酚聚氧乙烯醚的光降解行为和雌激素效应[J]. 净水技术,2011,30(6):19-22.

[19] 黑晓慧,陶红,蔡孝辉,等. 新型微介孔复合材料La/13X/MCM-41光催化降解壬基酚的研究[J]. 水资源与水工程学报,2012, 23(6):62-65.

[20] 高峰,张中华,严志蓉,等. 二氧化钛膜光催化降解水中壬基酚的研究[J]. 环境科技,2009,22(4):11-14.

[21] Liu Guangming,Zheng Shourong,Xing Xiaoli,et al. Fe(Ⅲ)-oxalate complexes mediated photolysis of aqueous alkylphenol ethoxylates under simulated sunlight conditions[J]. Chemosphere,2010,78(4):402-408.

[22] Wang Pan,Bian Xiufang,Li Yanxin. Catalytic oxidation of phenol in wastewater:A new application of the amorphous Fe78Si9B13 alloy[J]. Chinese Science Bulletin,2012,57(1):33-40.

[23] 张波,李坤,曹长青,等. 4-n-壬基酚的激光闪光光解和紫外光降解[J]. 中国科学:化学,2012,42(2):175-181.

[24] 曲华. SnO₂改性纳米ZnO光催化剂降解NPE-10[J]. 兰州大学学报:自然科学版,2012,48(5):139-144.

[25] 黄婷婷,陶艳辉,陆文莲,等. Ti-Ce-MCM-41介孔分子筛光催化降解壬基酚的研究[J]. 水资源与水工程学报,2010,21(1): 51-53.

[26] 彭章娥,冯劲梅,何淑英. 含藻水中壬基酚的光降解转化研究[J]. 环境科学,2012,33(10):3466-3472.

[27] 张青梅,刘凤玲,郑寿荣,等. 胺基树脂吸附去除水中的壬基酚聚氧乙烯醚[J]. 环境科学研究,2011,24(5):548-552.

[28] 刘光明,尹大强. 大孔吸附树脂对烷基酚聚氧乙烯醚的吸附行为[J]. 生态环境,2008,17(5):1769-1773.

[29] 汤垣炜. 改性泥炭吸附水体中疏水性有机污染物及其机理研究[D]. 广州:华东理工大学, 2010.

[30] 鲁萍. 木屑材料改性及其吸附水中双酚A、壬基酚研究[D]. 广州:华东理工大学,2012.

[31] Skold M E,Thyne G D,Drexler J W,et al. Solubility enhancement of seven metal contaminants using carboxymethyl-beta-cyclodextrin(CMCD)[J]. Journal of Contaminant Hydrology,2009(107):108-113.

[32] 李丹,董锁拽,杨婷婷,等. 蚕丝纤维对烷基酚聚氧乙烯醚的吸附行为研究[J]. 浙江理工大学学报,2011,28(6):855-859.

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