Research progress of Pb(Ⅱ) adsorption by attapulgite

doi:10.11894/iwt.2019-0797

Abstract

Abstract:

Due to its specific surface area, pore structure and permanent negative charge on the surface, attapulgite has obvious advantages in removing heavy metals from wastewater. Further, the adsorbent material synthesized from the attapulgite has characteristics such as low cost, greenness, and safety. In this paper, the research progress of attapulgite functional modification in adsorption of Pb(Ⅱ) in wastewater is reviewed.

Key words: attapulgite, modification, Pb(Ⅱ), adsorption

摘要：

凹凸棒土具有比表面积大、特殊的孔道结构及表面带有永久负电荷等特性，使其在去除废水中重金属方面有明显优势。改性凹凸棒土合成吸附材料具有低成本、绿色、安全等特性。综述了凹凸棒土功能性改性在吸附废水中Pb（Ⅱ）方面的研究进展。

关键词: 凹凸棒土, 改性, 铅离子, 吸附

CLC Number:

X703

Jiakang He,Baoming Wang,Bingyu Wu,Jianwei Tang,Jianyun Li,Quanxian Hua. Research progress of Pb(Ⅱ) adsorption by attapulgite[J]. Industrial Water Treatment, 2020, 40(8): 11-16.

何佳康,王保明,吴冰玉,汤建伟,李见云,化全县. 凹凸棒土吸附Pb(Ⅱ)的研究进展[J]. 工业水处理, 2020, 40(8): 11-16.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/iwt.2019-0797

https://www.iwt.cn/EN/Y2020/V40/I8/11

Figures/Tables 1

References 29

1	Wang Lihua , Sheng Jing . Preparation and properties of polypropylene/org-attapulgite nanocomposites[J]. Polymer, 2005, 46 (16): 6243- 6249. doi: 10.1016/j.polymer.2005.05.067
2	An Li , Wang Aiqin , Chen Jianmin . Studies on poly(acrylic acid)/attapulgite superabsorbent composite. Ⅰ. Synthesis and characterization[J]. Applied Polymer, 2004, 92 (3): 1596- 1603. doi: 10.1002/app.20104
3	田煦, 郑自立. 中国坡缕石矿石特征及物化性能研究[J]. 矿产综合利用, 1996, (6): 1- 4. URL
4	Chi Yaling , Chen Yuantao , Liu Xia , et al. Impact of environmental conditions on the sorption behavior of Pb(Ⅱ) onto attapulgite[J]. Journal of Radioanalytical and Nuclear Chemistry, 2013, 295 (2): 1589- 1596. doi: 10.1007/s10967-012-2324-7
5	周守勇, 薛爱莲, 张艳, 等. 磷酸改性凹凸棒黏土对Pb²⁺的吸附研究[J]. 环境污染治理技术与设备, 2006, (5): 31- 34. URL
6	王红艳, 张艳, 周守勇, 等. 硫酸改性凹凸棒黏土的性能表征及吸附Pb(Ⅱ)工艺研究[J]. 淮阴师范学院学报:自然科学版, 2005, (1): 47- 50. doi: 10.3969/j.issn.1671-6876.2005.01.012
7	杨恩, 刘红, 王佩, 等. 颗粒型凹凸棒土的高温活化及其吸附富集水中Pb²⁺的研究[J]. 硅酸盐通报, 2016, 35 (1): 6- 11. URL
8	Lin Shaohua , Zhou Tingting , Yin Shenshen . Properties of thermally treated granular montmorillonite palygorskite adsorbent(GMPA) and use to remove Pb²⁺ and Cu²⁺ from aqueous solutions[J]. Clays and Clay Minerals, 2017, 65 (3): 184- 192. doi: 10.1346/CCMN.2017.064058
9	方月梅, 杨恩, 范先媛, 等. 13X分子筛/凹凸棒土材料吸附Pb(Ⅱ)的研究[J]. 非金属矿, 2018, 41 (2): 88- 91. URL
10	刘文杰, 杨彤, 徐蛟, 等. 凹凸棒石/脱硅稻壳炭复合材料吸附Pb²⁺、Cu²⁺、Ni²⁺的对比研究[J]. 化工新型材料, 2015, 43 (5): 169- 173. URL
11	Tang Jie , Mu Bin , Wang Wenbo , et al. Fabrication of manganese dioxide/carbon/attapulgite composites derived from spent bleaching earth for adsorption of Pb(Ⅱ) and Brilliant green[J]. RSC Advances, 2016, 6 (43): 36534- 36543. doi: 10.1039/C5RA26362J
12	Yang Facui , Sun Shiqi , Chen Xiaoqi , et al. Mg-Al layered double hydroxides modified clay adsorbents for efficient removal of Pb²⁺, Cu²⁺ and Ni²⁺ from water[J]. Applied Clay Science, 2016, 123, 134- 140. doi: 10.1016/j.clay.2016.01.026
13	Chen Lifeng , Liang Haiwei , Lu Yang , et al. Synthesis of an attapulgite clay@carbon nanocomposite adsorbent by a hydrothermal carbonization process and their application in the removal of toxic metal ions from water[J]. Langmuir, 2011, 27 (14): 8998- 9004. doi: 10.1021/la2017165
14	Zou Mingfeng , Chen Xiangying , Lin Xiajie , et al. Fabrication of magnetic carboxyl-functionalized attapulgite/calcium alginate beads for lead ion removal from aqueous solutions[J]. International Journal of Biological Macromolecules, 2018, 120, 789- 800. doi: 10.1016/j.ijbiomac.2018.08.144
15	Mao Xinyou , Duan Yanyan , Wang Chuanyi . Mechanistic understanding of the adsorption behavior of metal lead ions by attapulgiteinduced porous nanocomposite hydrogels[J]. Journal of Chemical & Engineering Data, 2018, 63 (11): 4241- 4247. URL
16	Liu Peng , Jiang Liping , Zhu Longxiang , et al. Attapulgite/poly(acrylic acid) nanocomposite(ATP/PAA) hydrogels with multifunctionalized attapulgite(org-ATP) nanorods as unique cross-linker:preparation optimization and selective adsorption of Pb(Ⅱ) ion[J]. ACS Sustainable Chemistry & Engineering, 2014, 2 (4): 643- 651.
17	Liu Peng , Jiang Liping , Zhu Longxiang , et al. Synthesis of covalently crosslinked attapulgite/poly(acrylic acid-co-acrylamide) nanocomposite hydrogels and their evaluation as adsorbent for heavy metal ions[J]. Journal of Industrial and Engineering Chemistry, 2015, 23, 188- 193. doi: 10.1016/j.jiec.2014.08.014
18	Zhang Junpeng , Jin Yeling , Wang Aiqin . Rapid removal of Pb(Ⅱ) from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite/sodium humate composite hydrogels[J]. Environmental Technology, 2011, 32 (5): 523- 531. doi: 10.1080/09593330.2010.504748
19	Jiang Liping , Liu Peng . Design of magnetic attapulgite/fly ash/poly (acrylic acid) ternary nanocomposite hydrogels and performance evaluation as selective adsorbent for Pb²⁺ ion[J]. ACS Sustainable Chemistry & Engineering, 2014, 2 (7): 1785- 1794. URL
20	Yu Jie , Zheng Jidong , Liu Quanfang , et al. Selective adsorption and reusability for Pb²⁺ of chitosan-based microporous polymer[J]. Polymer-Korea, 2017, 41 (3): 480- 489.
21	Deng Yuehua , Gao Zhanqi , Liu Benzhi , et al. Selective removal of lead from aqueous solutions by ethylenediamine-modified attapulgite[J]. Chemical Engineering Journal, 2013, 223, 91- 98. doi: 10.1016/j.cej.2013.03.020
22	周守勇, 薛爱莲, 张艳, 等. 聚丙烯酸改性凹土对Pb²⁺、Ni²⁺和Cr³⁺的选择性吸附[J]. 化工学报, 2015, 66 (2): 618- 625. URL
23	王晓鹏, 于波, 张俊平, 等. 凹凸棒黏土接枝聚丙烯腈的制备及其对Pb²⁺的吸附性能[J]. 非金属矿, 2008, (6): 52- 54. URL
24	Liang Xuefeng , Xu Yingming , Tan Xin , et al. Heavy metal adsorbents mercapto and amino functionalized palygorskite:preparation and characterization[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2013, 426, 98- 105. URL
25	Zhou Shouyong , Xue Ailian , Zhang Yan , et al. Novel polyamidoamine dendrimer-functionalized palygorskite adsorbents with high adsorption capacity for Pb²⁺ and reactive dyes[J]. Applied Clay Science, 2015, 107, 220- 229. doi: 10.1016/j.clay.2015.01.032
26	Shirvani M , Sherkat Z , Khalili B , et al. Sorption of Pb(Ⅱ) on palygorskite and sepiolite in the presence of amino acids:equilibria and kinetics[J]. Geoderma, 2015, 249-250, 21- 27. doi: 10.1016/j.geoderma.2015.03.006
27	Rusmin R , Sarkar B , Tsuzuki T , et al. Removal of lead from aqueous solution using superparamagnetic palygorskite nanocomposite:material characterization and regeneration studies[J]. Chemosphere, 2017, 186, 1006- 1015. doi: 10.1016/j.chemosphere.2017.08.036
28	姜立萍, 陈倩, 李翠林, 等. Fe₃O₄/PAA/ATP纳米复合磁性微凝胶吸附剂对Pb(Ⅱ)吸附动力学和吸附热力学研究[J]. 化学研究与应用, 2017, 29 (3): 348- 352. doi: 10.3969/j.issn.1004-1656.2017.03.011
29	Jiang Liping , Liu Peng , Zhao Shibin . Magnetic ATP/FA/Poly(AA-co-AM) ternary nanocomposite microgel as selective adsorbent for removal of heavy metals from wastewater[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2015, 470, 31- 38. URL

改性方法	主要吸附机理	外部主要影响因素	吸附过程	吸附模型
酸改性	化学吸附	pH、离子强度	准二级吸附动力模型	Langmuir模型
热处理	化学吸附、离子交换吸附	pH、离子强度	准二级吸附动力模型	Langmuir模型
复合改性	离子交换、化学吸附	pH、离子强度	准二级吸附动力模型、二级吸附动力模型	Freundlich模型、Langmuir模型
水凝胶	化学吸附	pH、离子强度	准二次动力学模型	Langmuir模型Freundlich模型
有机改性	化学吸附	pH、离子强度	准二次动力学模型	Langmuir模型
铁顺磁性	化学吸附	pH、离子强度	准二次动力学模型	Freundlich模型

改性方法	主要吸附机理	外部主要影响因素	吸附过程	吸附模型
酸改性	化学吸附	pH、离子强度	准二级吸附动力模型	Langmuir模型
热处理	化学吸附、离子交换吸附	pH、离子强度	准二级吸附动力模型	Langmuir模型
复合改性	离子交换、化学吸附	pH、离子强度	准二级吸附动力模型、二级吸附动力模型	Freundlich模型、Langmuir模型
水凝胶	化学吸附	pH、离子强度	准二次动力学模型	Langmuir模型Freundlich模型
有机改性	化学吸附	pH、离子强度	准二次动力学模型	Langmuir模型
铁顺磁性	化学吸附	pH、离子强度	准二次动力学模型	Freundlich模型

[1]	Hengjun TANG, Biao QIU, Weiping SIMA, Jian TANG. Study on the removal of Cr(Ⅵ) by acid-modified distillers’ grains biochar [J]. Industrial Water Treatment, 2025, 45(3): 144-151.
[2]	Wei JIANG, Xiaodie CAI, Xinyu WEN, Sili CHEN, Jinsong WANG, Zhengke ZHANG. Preparation of mesoporous silica/sodium alginate composites and its removal performance of radioactive Sr²⁺ [J]. Industrial Water Treatment, 2025, 45(3): 90-98.
[3]	Qingyuan WANG, Yanping ZHANG, Yibing LI, Fen LI. Adsorption of methylene blue by biochar prepared using straw mixed with agricultural film [J]. Industrial Water Treatment, 2025, 45(3): 110-120.
[4]	Yabin JIN, Tiantian XU, Dezhong ZHAO, Le ZHANG, Zhenjie WAN, Gaoming ZHANG. Advances in the synthesis of Bi₂O₃-based composite photocatalysts and the applications in water treatment [J]. Industrial Water Treatment, 2025, 45(3): 10-21.
[5]	Yasong CHEN, Shiyu MIAO, Chi ZHANG, Mingran LI, Jiaqi WANG, Yanyu ZHANG, Wei JIANG. Research progress on the preparation and the adsorption mechanisms of phosphorus removal adsorbents [J]. Industrial Water Treatment, 2025, 45(2): 1-9.
[6]	Wenhao WANG, Yexing CHENG, Yuyin WANG, Tingting HOU, Xiaofeng WU, Yucai LI. Effect of different types of activated carbon on the adsorption- reduction of Cr(Ⅵ) by mZVI/activated carbon [J]. Industrial Water Treatment, 2025, 45(2): 150-158.
[7]	Qing LIU, Jianbin HUANG, Weifan LI, Guodong ZHAO, Jingjing YANG. Performance of U(Ⅵ) enrichment by tannic acid sodium and alginate composite microspheres [J]. Industrial Water Treatment, 2025, 45(1): 58-65.
[8]	Weiye ZHANG, Jing SHEN, Zihe PAN, Yipeng SONG, Huaigang CHENG, Huirong ZHANG. Analysis of heel formation and influencing factors during the thermal regeneration process of saturated activated carbon [J]. Industrial Water Treatment, 2025, 45(1): 17-25.
[9]	Cuihong ZHANG, Jing WANG, Jie WANG, Wenjiao YUAN. Preparation of quaternary ammonium-modified silica and its adsorption of vanadium(V) [J]. Industrial Water Treatment, 2025, 45(1): 104-114.
[10]	Zhihua DENG, Rui LIU, Biqing LI. Preparation of different biochars and their adsorption performance for heavy metals and antibiotics [J]. Industrial Water Treatment, 2025, 45(1): 94-103.
[11]	Zirui GUO, Hongyan LI, Feng ZHANG, Jiali CUI, Qun YANG, Yun LI. Performance and mechanism of catalytic degradation of benzotriazole in water by Fe₂O₃-CuO/rCG [J]. Industrial Water Treatment, 2024, 44(9): 118-126.
[12]	Qin DENG, Yijian ZHONG, Jincheng LI, Huihui SHI, Chunman WEI, Jiajia QIN. Preparation and regeneration ability test of a new type of phosphorus removal filler [J]. Industrial Water Treatment, 2024, 44(8): 140-148.
[13]	Ya HU, Xiaolei SUN, Jingyu LU, Xiuyun SUN. Preparation of Tymycin waste salt activated carbon and its adsorption performance for EDTA-Pb(Ⅱ) [J]. Industrial Water Treatment, 2024, 44(8): 133-139.
[14]	Haoyu ZHANG, Yikang ZHOU, Yan WANG, Le PAN, Yunfei WANG, Dezhang ZHU, Yan WU. Preparation and adsorption study of waste tea-based porous carbon for methyl orange dyes [J]. Industrial Water Treatment, 2024, 44(8): 171-177.
[15]	Yiwei PAN, Qifeng FAN, Ganwei ZHANG, Shusu SHEN. Progress in preparation and application of water treatment membranes modified with imine based covalent organic frameworks [J]. Industrial Water Treatment, 2024, 44(8): 29-37.

Please choose a citation manager

Content to export