Research progress on selective removal and resource recovery for heavy metals from wastewater

doi:10.19965/j.cnki.iwt.2022-1137

Abstract

Key words: heavy metals, adsorption, electrodeposition, selectivity, resourceization

CLC Number:

X703

Ziwen CHANG, Penghui SHAO, Jitao CHEN, Liming YANG, Lili FANG, Jiachuang SHAO, Dewei LI, Xubiao LUO. Research progress on selective removal and resource recovery for heavy metals from wastewater[J]. Industrial Water Treatment, 2023, 43(7): 1-13.

畅子雯, 邵鹏辉, 陈冀陶, 杨利明, 方俐俐, 邵家创, 李德伟, 罗旭彪. 废水中重金属的选择性去除与资源化回收研究进展[J]. 工业水处理, 2023, 43(7): 1-13.

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Figures/Tables 8

Fig. 1 Selective adsorption mechanism of adsorbent for heavy metal ions

Fig. 2 The construction of ion imprinting adsorbents

Table 1 Ion imprinting adsorbents and their selective adsorption performance

吸附剂	目标离子	平衡吸附量/（mg·g^-1）	共存离子	吸附系数/（L·g^-1）	参考文献
Ag（Ⅰ）-IIM	Ag（Ⅰ）	345.2	Pb（Ⅱ）、Cu（Ⅱ）、K（Ⅰ）	0.41	〔13〕
Cd-IIPs	Cd（Ⅱ）	65.5	Zn（Ⅱ）、Ni（Ⅱ）、Cu（Ⅱ）、Co（Ⅱ）	0.14	〔14〕
QAPs	Cr（Ⅵ）	211.8	SO₄ ^2-、NO₃ ^-、PO₄ ^3-	7.5	〔15〕
POPD-CoFe₂O₄	Cu（Ⅱ）	114.2	Cd（Ⅱ）、Fe（Ⅲ）、Zn（Ⅱ）		〔16〕
Cu（Ⅱ）-IIF	Cu（Ⅱ）	7.6	Cu（Ⅱ）、Zn（Ⅱ）、Ni（Ⅱ）		〔17〕
Hg-PMTF	Hg（Ⅱ）	360.5	Pb（Ⅱ）、Cd（Ⅱ）、Cu（Ⅱ）、Ni（Ⅱ）	964.78	〔18〕
Straw@IIP	La（Ⅲ）	125	Th（Ⅳ）、Ce（Ⅲ）、Nd（Ⅲ）、Zr（Ⅳ）	2.820	〔19〕
CoFe₂O₄@MPS	Ni（Ⅱ）	41.95	Zn（Ⅱ）、Cd（Ⅱ）、Cu（Ⅱ）	0.602	〔20〕
IIPs	Ni（Ⅱ）	51.62	Pb（Ⅱ）、Cu（Ⅱ）	7.33	〔21〕
IIP-MMT	Pb（Ⅱ）	201.84	Zn（Ⅱ）、Cd（Ⅱ）、Cu（Ⅱ）、Sn（Ⅳ）、Mn（Ⅱ）	0.254	〔22〕
Fe₃O₄@SiO₂@CNFs	Sb（Ⅲ）	47.4	Al（Ⅲ）、Cd（Ⅱ）、Cu（Ⅱ）、Sn（Ⅳ）、Zn（Ⅱ）	0.02	〔23〕

Fig. 3 Adsorption mechanism of specific coordination adsorbents

Table 2 Specific coordination adsorbents and their selective adsorption performance

吸附剂	目标离子	平衡吸附量/（mg·g^-1）	配位官能团	吸附系数/（L·g^-1）	参考文献
COF-SH	Ag（Ⅰ）	609.89	—SH	318.31	〔29〕
Fe₃O₄@SiO₂@TiO₂-IIP	Ag（Ⅰ）	35.48	—SH	29.96	〔30〕
PEI-LS	Au（Ⅲ）	313	单宁酸	1 104	〔31〕
OMS-TE-SH	Au（Ⅲ）	215.88	—SH	352.4	〔32〕
AHPP-MOF	Pd（Ⅱ）	98.96	C $̿$ N—OH	95.15	〔33〕
UiO-66-NH₂	Pb（Ⅱ）	200.17	—NH₂/—SH	850.43	〔34〕
Mag@silica-CIP-2	Co（Ⅱ）	78.9	—NH₂	1.92	〔35〕
壳聚糖	Ni（Ⅱ）	87.45	—NH₂		〔36〕
AAMA	Cd（Ⅱ）	175	—COOH O $̿$ C—NH₂		〔37〕
UB5	Cr（Ⅵ）	28.3	含O、N官能团		〔38〕
Cu-MG	Sb（V）	264.1	—OH	0.96	〔39〕

Table 2 Specific coordination adsorbents and their selective adsorption performance

吸附剂	目标离子	平衡吸附量/（mg·g^-1）	配位官能团	吸附系数/（L·g^-1）	参考文献
COF-SH	Ag（Ⅰ）	609.89	—SH	318.31	〔29〕
Fe₃O₄@SiO₂@TiO₂-IIP	Ag（Ⅰ）	35.48	—SH	29.96	〔30〕
PEI-LS	Au（Ⅲ）	313	单宁酸	1 104	〔31〕
OMS-TE-SH	Au（Ⅲ）	215.88	—SH	352.4	〔32〕
AHPP-MOF	Pd（Ⅱ）	98.96	C $̿$ N—OH	95.15	〔33〕
UiO-66-NH₂	Pb（Ⅱ）	200.17	—NH₂/—SH	850.43	〔34〕
Mag@silica-CIP-2	Co（Ⅱ）	78.9	—NH₂	1.92	〔35〕
壳聚糖	Ni（Ⅱ）	87.45	—NH₂		〔36〕
AAMA	Cd（Ⅱ）	175	—COOH O $̿$ C—NH₂		〔37〕
UB5	Cr（Ⅵ）	28.3	含O、N官能团		〔38〕
Cu-MG	Sb（V）	264.1	—OH	0.96	〔39〕

Fig. 4 Standard reduction potentials of different heavy metal ions（a） and mechanism of selective electroreduction deposition（b）

Fig. 5 Adsorption mechanism of HZO-201 to cupric citrate and the treatment effect in fixed bed （a）， and anti-fouling mechanism of PHEMA brush （b）

Fig. 6 Reactor design for selective adsorption technology

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