Preparation of polyacrylamide aqueous dispersion emulsion and its sludge dewatering capacity

Abstract

Abstract:

Cationic polyacrylamide （CPAM） has been prepared by dispersion polymerization of acrylamide （AM）and 2 -methylacryloylxyethl trimethyl ammonium chloride （DMC）.The structure and forming mechanisms of the product are analyzed with Fourier-transform infrared spectroscopy,1H nuclear magnetic resonance spectroscopy and microscopy.The sludge dewatering efficacy is evaluated with home-made CPAM.The results show that the turbidity removing rate of supernatants reaches 96% and water ratio decreases to 68%,when CPAM concentration is 0.15%,its dosage is 0.005%-0.01% of the total amount of wet sludge,and sludge pH is 3-7.

Key words: cationic polyacrylamide, aqueous dispersion emulsion, dispersion polymerization, sludge dewatering

摘要：

通过丙烯酰胺(AM)与甲基丙烯酰氧乙基三甲基氯化铵(DMC)的分散聚合制得阳离子聚丙烯酰胺(CPAM)水分散乳液,通过红外光谱(FT-IR)、核磁共振(1HNMR)、光学显微镜分析了产物的结构与形成机理,并用自制CPAM对污泥脱水效果进行了评定。结果表明,当CPAM质量分数为0.15%,投加量为湿泥总量0.005%～0.01%,污泥pH为3～7时,上清液浊度去除率达96%,滤饼含水率降至68%。

关键词: 阳离子聚丙烯酰胺, 水分散乳液, 分散聚合, 污泥脱水

CLC Number:

TU992.3

Huang Zhen, Shu Xin, Ran Qianping, Liu Jiaping. Preparation of polyacrylamide aqueous dispersion emulsion and its sludge dewatering capacity[J]. INDUSTRIAL WATER TREATMENT, 2013, 33(7): 61-65.

黄振, 舒鑫, 冉千平, 刘加平. 聚丙烯酰胺水分散乳液的制备及污泥脱水性能研究[J]. 工业水处理, 2013, 33(7): 61-65.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/Y2013/V33/I7/61

References

［1］张元成, 刘树强, 高宝玉. 污水处理用阳离子PAM 的开发现状和前景［J］. 工业水处理, 2002, 22（7）：15-17.
［2］严瑞瑄. 水溶性高分子［M］. 2 版.北京：化学工业出版社, 2010：13-18.
［3］胡瑞, 周华, 李田霞, 等. 复合引发体系制备阳离子絮凝剂在污水处理中的应用研究［J］. 工业水处理, 2006, 26（8）：32-35.
［4］李田霞, 陈峰, 胡瑞. 高分子质量阳离子聚丙烯酰胺的合成［J］.工业水处理, 2011, 31（4）：55-57.
［5］ Ezell R G, Gorman I, Lokitz B, et al. Stimuli-responsive ampholytic terpolymers of N-acryloyl-valine, acrylamide, and （3-acrylamidopropyl）trimethylammonium chloride：Synthesis, characterization, and solution properties ［J］. Journal of Polymer Science Part A：Polymer Chemistry, 2006, 44（9）：3125-3139.
［6］ Ge Xuewu, Ye Qiang, Xu Xiangling, et al. Studies of inverse emulsion copolymerization of （2 -methacryloyloxyethyl） trimethyl ammonium chloride and acrylamide ［J］. Journal of Applied Polymer Science, 1998, 67（6）：1005-1010.
［7］ Neyret S, Candau F, Selb J. Synthesis in microemulsion and characterization of low charge density ampholytic terpolymers ［J］. Acta Polymerica, 1996, 47（8）：323-332.
［8］ Hao Jingcheng. Microemulsion polymerization of acrylamide and styrene: Effect of the structures of reaction media ［J］. Journal of Polymer Science Part A：Polymer Chemistry, 2001, 39 （19）：3320-3334.
［9］ Ray B, Mandal B M. Dispersion polymerization of acrylamide ［J］.Langmuir, 1997, 13（8）：2191-2196.
［10］ Ray B, Mandal B M. Dispersion polymerization of acrylamide：PartⅡ. 2，2’ -azobisisobutyronitrile initiator ［J］. Journal of Polymer Science Part A：Polymer Chemistry, 1999, 37（4）：493-499.
［11］ Ye Qiang, Zhang Zhicheng, Jia Haiting, et al. Formation of monodisperse polyacrylamide particles by radiation-induced dispersion polymerization：Particle size and size distribution ［J］. Journal ofColloid and Interface Science, 2002, 253（2）：279-284.
［12］ Guha S, Mandal B M. Dispersion polymerization of acrylamide Ⅲ.Partial isopropyl ester of poly （vinyl methyl ether-alt-maleic anhydride） as a stabilizer ［J］. Journal of Colloid and Interface Science，2004, 271（1）：55-59.
［13］ Jin Zhengzhong, Zhu Yong, Hu Yongdong. Studies on the synthesis and the phase components of the water in water emulsions ［J］.Chemical Journal of Chinese Universities, 1991, 12 （7）：942 -945.
［14］ Lü Ting, Shan Guorong. Mechanism of the droplet formation and stabilization in the aqueous two-phase polymerization of acrylamide［J］. Journal of Applied Polymer Science, 2009, 112（5）：2859-2867.
［15］ Lü Ting, Shan Guorong. Droplet size and morphology for the aqueous two-phase polymerization of acrylamide in an aqueous poly（ethylene glycol） solution［J］. Journal of Applied Polymer Science, 2010, 116（3）：1747-1758.
［16］ Chen Dongnian, Liu Xiaoguang, Yue Yumei, et al. Dispersion copolymerization of acrylamide and cationic monomer in aqueous solution of ammonium sulfate ［J］. Acta Polymerica Sinica, 2006, 1（9）：1074-1077.
［17］ Chen Dongnian, Liu Xiaoguang, Yue Yumei, et al. Dispersion copolymerization of acrylamide with quaternary ammonium cationic monomer in aqueous salts solution ［J］. European Polymer Journal, 2006, 42（6）：1284-1297.
［18］ Wu Yumin, Wang Yupeng, Yu Yueqin, et al. Dispersion polymerization of acrylamide with 2- acrylamido - 2-methyl - 1- propane sulfonate in aqueous solution ［J］. Journal of Applied Polymer Science, 2006, 102（3）：2379-2385.
［19］ Wu Yumin, Chen Qingfen, Xu Jun, et al. Aqueous dispersion polymerization of acrylamide with quaternary ammonium cationic comonomer ［J］. Journal of Applied Polymer Science, 2008, 108（1）：134-139.
［20］ Mabire F, Audebert R, Quivoron C. Synthesis and solution properties of water soluble copolymers based on acrylamide and quaternary ammonium acrylic comonomer ［J］. Polymer, 1984, 25 （9）：1317 -1322.
［21］ Kabanov V A, Topchiev D A, Karaputa T. Some features of radical polymerization of acrylic and methacrylic acid salts in aqueous solutions［J］. Journal of Polymer Science：Polymer Symposia，1973，42（1）：173-183.
［22］ Vu C, Cabestany J. Characterization of cationic water - soluble polyacrylamides ［ J ］ 1991, 42（11）：2857-2869.

[1]	Jing ZHANG, Yanping ZHANG, Jiahua PEI, Xiaosai JIA, Yibing LI, Ning LÜ. Study on the waste activated sludge dewatering effect and mechanism conditioned by persulfate induced with iron-based sludge biochar [J]. Industrial Water Treatment, 2024, 44(3): 142-151.
[2]	Lin HAN, Yongming CHENG, Dongmei WANG, Yajuan LI, Jie ZHANG. Problem diagnosis and analysis of advanced treatment system for reclaimed water in a power plant [J]. Industrial Water Treatment, 2024, 44(3): 206-210.
[3]	Jie ZHANG, Yue LAI, Chaohui YANG, Hao LIN, Shungui ZHOU, Jie YE, Changgeng LIU. Research advance and application exploration of sludge dewatering flocculants [J]. Industrial Water Treatment, 2024, 44(2): 48-62.
[4]	Xinhe YE, Junwei LIU, Hongjun CE, Rui WANG. Research progress in the improvement of sludge dewatering by physical conditioning [J]. Industrial Water Treatment, 2022, 42(8): 51-59.
[5]	Yizhi LIU, Xiantao ZHOU, Tong YANG. Study on improving sludge dewatering performance by combining biological shell powder with CPAM [J]. Industrial Water Treatment, 2022, 42(12): 154-159.
[6]	Xieping Xue,Yanping Zhang,Xuemeng Sun,Songchao Zheng,Xiangshi Peng. Deep dewatering of sludge by the coordination of the modified sludge and FeCl₃ [J]. Industrial Water Treatment, 2021, 41(7): 82-87.
[7]	Lingmin Cai,Xizi Luo,Min Zhou,Junhu Li,Lihua Zhang,Haitao Zhang. Research on CPAM and CPAM coupled with FeCl₃ for the improvement of sludge dewatering capability [J]. Industrial Water Treatment, 2019, 39(6): 81-85.
[8]	Guo Manman, Zhang Bin, Ma Libiao, Liu Rongzhan. Application of polyacrylic acid flocculant to the low temperature thermal treatment of textile dyeing sludge [J]. INDUSTRIAL WATER TREATMENT, 2019, 39(4): 29-32.
[9]	Qingtao Li,Chunzhi Zhang,Jizhi Zhou,Yongsheng Lu,Tingyi Lu,Yifei Gu,Jianjun Min. Improvement of sludge dewatering capability with modified polyaluminium chloride residue [J]. Industrial Water Treatment, 2019, 39(12): 79-81.
[10]	Yang Wenfeng, Zhang Qingfang, Yang Qiyong, Zhu Qiong. A review on municipal sludge dewatering and bioleaching conditioning technologies [J]. INDUSTRIAL WATER TREATMENT, 2018, 38(4): 11-16.
[11]	Jia Xiuming, Li Yanping, Shi Yanwei, Du Rong. Upgrading modification design of the sludge dewatering system in a sewage treatment plant and its economic and technical analysis [J]. INDUSTRIAL WATER TREATMENT, 2017, 37(7): 103-106.
[12]	Ma Chao, Zhu Qianqian, Pan Minglei, Su Chao, Zhou Chao. Discussion on the flocculation effect of the temperature-sensitive polymer in thick oil wastewater [J]. INDUSTRIAL WATER TREATMENT, 2017, 37(5): 50-52,53.
[13]	Zheng Huaili, Shou Qianying, Li Xiang, Zhou Yuhao, Liu Bingzhi, Zhao Chuanliang, Jiang Jiaxian. Research progress in the polymerization and application of cationic polyacrylamide [J]. INDUSTRIAL WATER TREATMENT, 2016, 36(12): 12-15.
[14]	Wang Xuechuan, Pan Bo, Qiang Taotao, Zhang Feifei. Study on the application of cationic collagen flocculant to the improvement of sludge dewaterability [J]. INDUSTRIAL WATER TREATMENT, 2015, 35(7): 19-23.
[15]	Lin Xialiang, Zhou Xingqiu, Wu Jiandong, Zhu Liang, Zheng Long. Influence of the co-conditioning of inorganic coagulants combined with chitosan on sludge dewatering effects [J]. INDUSTRIAL WATER TREATMENT, 2015, 35(10): 38-41.

Please choose a citation manager

Content to export