Industrial Water Treatment ›› 2020, Vol. 40 ›› Issue (6): 87-90. doi: 10.11894/iwt.2019-0677

• Water Treatment in Oil-Gas Field • Previous Articles     Next Articles

Synthetization of copolymer flocculant by using polymerizable surfactants and DPM and its performance and mechanism on treating polymerized sewage

Nianting Si()   

  1. Tianjin Branch of CNOOC(China) Co., Ltd., Tianjin 300451, China
  • Received:2020-04-29 Online:2020-06-20 Published:2020-06-20

一种可聚合表活与DPM共聚物处理含聚污水及机理

司念亭()   

  1. 中海石油(中国)有限公司天津分公司, 天津 300451
  • 作者简介:司念亭(1974—), 硕士, 高工。E-mail:sint@cnooc.com.cn

Abstract:

In this study, a copolymer flocculant P[DPM/DC12MAAC] was firstly synthesized by using dodecyl methallyl ammonium chloride and N-(3-dimethylaminopropyl)methacrylamide. Then the prepared flocculant was used to treat polymer-containing sewage, and its flocculation performance was evaluated. The results showed that the turbidity reduction rate was as high as 99.53%, and the minimum weight gain per unit surface area of the iron sheet was 43.02 g/m2, which reduced 74.90% of flocs. The field test results showed that, under the premise of ensuring the water quality index, the flocculant could reduce the production of viscous flocs by about 70.5%. The flocculant destroys the diffusion double electron layer of oil droplets by electrostatic adsorption, thereby neutralizing the negative charge on its surface.

Key words: polymerized sewage, polymerized sludge, long chain quaternary ammonium salt, flocculation

摘要:

使用双十二烷基甲基烯丙基氯化铵(DC12MAAC)与N-(3-二甲氨基丙基)甲基丙烯酰胺(DPM)进行共聚,合成了P[DPM/DC12MAAC]共聚物絮凝剂。以含聚污水为处理对象,对其絮凝性能进行了评价。评价结果表明:浊度降低率最高达99.53%,单位表面积铁片增重量最低为43.02 g/m2,可减少74.90%的絮体。现场试验结果表明,在保证水质指标的前提下,该絮凝剂可使黏性絮体产生量下降约70.5%。该絮凝剂通过静电吸附破坏油滴的扩散双电子层,从而中和其表面负电荷。

关键词: 含聚污水, 含聚油泥, 长链季铵盐, 絮凝

CLC Number: