Research progress of electro-adsorption electrode materials

doi:10.19965/j.cnki.iwt.2020-1045

Abstract

Abstract:

Electro⁃adsorption is a kind of new and developing desalination technology. The electrode is the key factor which restricts electro⁃adsorption capacity and the hotspot of electro⁃adsorption research. The principle of electro⁃adsorption technology and the research progress of four kinds of electrode materials based on carbon were introduced，and the advantages and disadvantages of which were contrasted and analyzes. The adsorption capacity of a single electrode material was small and could not meet the industrial requirements. Therefore，how to modify electrode materials under low cost was the main research direction of electro⁃adsorption electrode materials in the future.

Key words: electro?adsorption, capacitive deionization, electrode materials

摘要：

电吸附除盐技术是一种正在发展的新型的除盐技术，其中电极材料是制约电吸附性能的关键，也是电吸附技术研究的热点。介绍了电吸附技术原理和4类碳基电极材料的研究进展，对比分析了4类电极材料的优缺点，指出单一电极材料的吸附容量小，不能满足其工业要求，在低成本的条件下对电极材料进行改性处理是今后电吸附电极材料的主要研究方向。

关键词: 电吸附, 电容去离子, 电极材料

CLC Number:

Xuming DONG, Shenghan ZHANG, Jie DI, Zhilin WANG, Weijian QI. Research progress of electro-adsorption electrode materials[J]. Industrial Water Treatment, 2022, 42(1): 48-55.

董旭明, 张胜寒, 狄杰, 王智麟, 祁伟健. 电吸附电极材料的研究进展[J]. 工业水处理, 2022, 42(1): 48-55.

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URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2020-1045

https://www.iwt.cn/EN/Y2022/V42/I1/48

Figures/Tables 3

References 46

1	CHEN Rong， HU Xien. Applications and research progress of electrosorption［J］. Progress in Chemistry，2006，18（1）：80-86.
2	HUANG Yongqiang， ZHU Yan， SHI Kai，et al. Treatment of tap water with membrane capacitive deionization composite electrode［J］. Chinese Journal of Environmental Engineering，2015，9（2）：807-811.
3	LEE J B， PARK K K，EUM H M，et al. Desalination of a thermal power plant wastewater by membrane capacitive deionization［J］. Desalination，2006，196（1/2/3）：125-134. doi:10.1016/j.desal.2006.01.011
4	孙晓慰，朱国富. 电吸附水处理技术（EST）的原理及构成［J］. 工业用水与废水，2002（4）：18-20. doi:10.3969/j.issn.1009-2455.2002.04.006
	SUN Xiaowei， ZHU Guofu. Principle and composition of electroadsorption water treatment technology（EST）［J］. Industrial water and wastewater，2002（4）：18-20. doi:10.3969/j.issn.1009-2455.2002.04.006
5	PORADA S， ZHAO R，et al. Review on the science and technology of water desalination by apacitive deionization［J］. Progress in Materials Science，2013，58（8）：1388-1442. doi:10.1016/j.pmatsci.2013.03.005
6	LI Wencui， LU Anhui， GUO Shucai. Preparation，properties and application of carbon aerogel［J］. Carbon Techniques，2001（2）：17-20. doi:10.1016/s0008-6223(00)00201-3
7	郭亚萍. 活性炭电吸附处理水中氯仿的研究［D］. 长春：东北师范大学，2002.
	GUO Yaping. Study on chloroform in activated carbon［D］. Chang chun：Northeast Normal University，2002.
8	HUANG C C， SIAO S F. Removal of copper ions from an aqueous solution containing a chelating agent by electrosorption on mesoporous carbon electrodes［J］. Journal of the Taiwan Institute of Chemical Engineers，2018，85：29-39. doi:10.1016/j.jtice.2018.02.005
9	FENG Cuijie， CHEN Yian， YU Changping. Highly porous activated carbon with multi⁃channeled structure derived from loofa sponge as a capacitive electrode material for deionization of brackish water［J］. Chemosphere，2018，208：285-293. doi:10.1016/j.chemosphere.2018.05.174
10	CHONG L G， CHEN P A， HUANG J Y，et al. Capacitive deionization of a RO brackish water by AC/graphene composite electrodes［J］. Chemosphere，2018，191：296-301. doi:10.1016/j.chemosphere.2017.10.064
11	ELISADIKI J， JANDE Y A C， MACHUNDA R L，et al. Porous carbon derived from Artocarpus heterophyllus peels for capacitive deionization electrodes［J］. Carbon，2019，147：582-593. doi:10.1016/j.carbon.2019.03.036
12	MOUNIR Z， SABIR H. Experimental investigation of activated carbon prepared from date stones adsorbent electrode for electrosorption of lead from aqueous solution［J］. Microchemical Journal，2019，146：164-169. doi:10.1016/j.microc.2018.12.041
13	GAO Tie， LI Haibo， FENG Zhou，et al. Mesoporous carbon derived from ZIF-8 for high efficient electrosorption［J］. Desalination，2019，452：133-138. doi:10.1016/j.desal.2017.06.021
14	KYUNG H K，DA H K， MIN J K，et al. Effect of C-F bonds introduced by fluorination on the desalination properties of activated carbon as the cathode for capacitive deionization［J］. Desalination，2019，457：1-7. doi:10.1016/j.desal.2018.12.005
15	LI Yingzhen， ZHANG Chang， JIANG Yanping，et al. Electrically enhanced adsorption and green regeneration for fluoride removal using Ti（OH）₄⁃loaded activated carbon electrodes［J］. Chemosphere，2018，200：554-560. doi:10.1016/j.chemosphere.2018.02.112
16	LI Yang， LIU Yuxin， SHEN Jiaming，et al. Design of nitrogen⁃doped cluster⁃like porous carbons with hierarchical hollow nanoarchitecture and their enhanced performance in capacitive deionization［J］. Desalination，2018，430：45-55. doi:10.1016/j.desal.2017.12.040
17	ZHANG Lu， LIU Yong， LU Ting，et al. Cocoon derived nitrogen enriched activated carbon fiber networks for capacitive deionization［J］. Journal of Electroanalytical Chemistry，2017，804：179-184. doi:10.1016/j.jelechem.2017.09.062
18	SONG Haiou， WU Yifan， ZHANG Shupeng，et al. Mesoporous generation⁃inspired ultrahigh capacitive deionization performance by sono⁃assembled activated carbon/inter⁃connected graphene network architecture［J］. Electrochimica Acta，2016，205：161-169. doi:10.1016/j.electacta.2016.04.082
19	LIU Y X，HIS H C， LI K C，et al. Electrodeposited manganese dioxide/activated carbon composite as a high⁃performance electrode material for capacitive deionization［J］. ACS Sustainable Chemistry and Engineering，2016，4（9）：4762-4770. doi:10.1021/acssuschemeng.6b00974
20	CHANG Liang， HU Yunhang. Surface⁃microporous graphene for high⁃performance capacitive deionization under ultralow saline concentration［J］. Journal of Physics and Chemistry of Solids，2019，125：135-140. doi:10.1016/j.jpcs.2018.10.018
21	CHANG Liang， HU Yunhang. 3D channel⁃structured grapheme as efficient electrodes for capacitive deionization［J］. Journal of Colloid and Interface Science，2019，538：420-425. doi:10.1016/j.jcis.2018.11.105
22	LI Haibo， ZOU Linda， PAN Likun，et al. Novel graphene⁃like electrodes for capacitive deionization［J］. Environmental Science and Technology，2010，44（22）：8692-8697. doi:10.1021/es101888j
23	EL⁃DEEN A G， BARAKAT N A M， KHALIL K A，et al. Graphene/SnO₂ nanocomposite as an effective electrode material for saline Graphene/SnO₂ nanocomposite as an effective electrode material for saline water desalination using capacitive deionization［J］. Ceramics International，2014，40（9）：14627-14634. doi:10.1016/j.ceramint.2014.06.049
24	WIMALASIRI Y， ZOU L D. Carbon nanotube/graphene composite for enhanced capacitive deionization performance［J］. Carbon，2013，59：464-471. doi:10.1016/j.carbon.2013.03.040
25	VENGATESAN M R， ALHSEINAT E， ARANGADI F A，et al. Ag⁃doped sepiolite intercalated graphene nanostructure for hybrid capacitive deionization system［J］. Separation and Purification Technology，2019，229：115799. doi:10.1016/j.seppur.2019.115799
26	EL⁃DEEN A G， BOOM R M， KIM H Y，et al. Flexible 3D nanoporous graphene for desalination and bio⁃decontamination of brackish water via asymmetric capacitive deionization［J］. ACS Applied materials & Interfaces，2016，8（38）：25313-25325. doi:10.1021/acsami.6b08658
27	MI Mengjuan， LIU Xiaojun， KONG Weiqing，et al. Hierarchical composite of N⁃doped carbon sphere and holey grapheme hydrogel for high⁃performance capacitive deionization［J］. Desalination，2019，464：18-24. doi:10.1016/j.desal.2019.04.014
28	XU Xingtao， SUN Zhuo， DANIEL H C，et al. Novel nitrogen doped grapheme sponge with ultrahigh capacitive deionization performance［J］. Scientific Reports，2015，5：11225. doi:10.1038/srep11225
29	BHARATH G， ALHSEINAT L E， PONPANDIAN N，et al. Development of adsorption and electrosorption techniques for removal of organic and inorganic pollutants from wastewater using novel magnetite/porous graphene⁃based nanocomposites［J］. Separation and Purification Technology，2017，188：206-218. doi:10.1016/j.seppur.2017.07.024
30	QUAN Xueping， FU Zhibing， YUAN Lei，et al. Capacitive deionization of NaCl solutions with ambient pressure dried carbon aerogel microsphere electrodes［J］. RSC Advances，2017，7（57）：35875-35882. doi:10.1039/C7RA05226J
31	ZHANG Chen， WANG Xiaodong， WANG Hongqiang，et al. A positive⁃negative alternate adsorption effect for capacitive deionization in nano⁃porous carbon aerogel electrodes to enhance desalination capacity［J］. Desalination，2019，458：45-53. doi:10.1016/j.desal.2019.01.023
32	XU Pei， DREWES J E， HEIL D，et al. Treatment of brackish produced water using carbon aerogel⁃based capacitive deionization technology［J］. Water Research，2008，42（10/11）：2605-2617. doi:10.1016/j.watres.2008.01.011
33	YANG Chunmo， CHOI W H， NA B K，et al. Capacitive deionization of NaCl solution with carbon aerogel⁃silica gel composite electrodes［J］. Desalination，2005，174（2）：125-133. doi:10.1016/j.desal.2004.09.006
34	LIU Yong， NIE Chunyang， PAN Likun，et al. Carbon aerogels electrode with reduced graphene oxide additive for capacitive deionization with enhanced performance［J］. Inorganic Chemistry Frontiers，2014，1（3）：249-255. doi:10.1039/C3QI00102D
35	LIU Xiaojun， LIU Hui， MI Mengjuan，et al. Nitrogen⁃doped hierarchical porous carbon aerogel for high⁃performance capacitive deionization［J］. Separation and Purification Technology，2019，224：44-50. doi:10.1016/j.seppur.2019.05.010
36	KUMAR R， GUPTA S S， KATIYAR S，et al. Carbon aerogels through organo⁃inorganic co⁃assembly and their application in water desalination by capacitive deionization［J］. Carbon，2016，99：375-383. doi:10.1016/j.carbon.2015.12.004
37	LIU Yihan， ZHANG Xiongfei， GU Xiao，et al. One⁃step turning leather wastes into heteroatom doped carbon aerogel for performance enhanced capacitive deionization［J］. Microporous and Mesoporous Materials，2020，303：110303. doi:10.1016/j.micromeso.2020.110303
38	CAO Ziling， ZHANG Chen， YANG Zhuoxin，et al. Preparation of carbon aerogel electrode for electrosorption of copper ions in aqueous solution［J］. Materials（Basel，Switzerland），2019，12（11）：1864. doi:10.3390/ma12111864
39	WANG Gang， PAN Chao， WANG Liuping，et al. Activated carbon nanofiber webs made by electrospinning for capacitive deioniza⁃tion［J］. Electrochimica Acta，2012，69：65-70. doi:10.1016/j.electacta.2012.02.066
40	BAI Yu， HUANG Zhenghong， YU Xiaoliang，et al. Graphene oxide⁃embedded porous carbon nanofiber webs by electrospinning for capacitive deionization［J］. Physicochemical and Engineering Aspects，2014，444：153-158. doi:10.1016/j.colsurfa.2013.12.053
41	LI Yanjiang， LIU Yong， WANG Miao，et al. Phosphorus⁃doped 3D carbon nanofiber aerogels derived from bacterial⁃cellulose for highly⁃efficient capacitive deionization［J］. Carbon，2018，130：377-383. doi:10.1016/j.carbon.2018.01.035
42	MA C Y， HUANG S C， CHOU P H，et al. Application of a multiwalled carbon nanotube⁃chitosan composite as an electrode in the electrosorption process for water purification［J］. Chemosphere，2016，146：113-120. doi:10.1016/j.chemosphere.2015.12.012
43	SHI Wenbo， ZHOU Xuechen， LI Jinyang，et al. High performance capacitive deionization via manganese oxide⁃coated，vertically ali⁃gned carbon nanotubes［J］. Environmental Science and Technology Letters，2018，5（11）：692-700. doi:10.1021/acs.estlett.8b00397
44	ZHANG Dengsong， YAN Tingting， SHI Liyi，et al. Enhanced capacitive deionization performance of graphene/carbon nanotube composite［J］. Journal of Materials Chemistry，2012，22（29）：14696-14704. doi:10.1039/c2jm31393f
45	WANG Yue， ZHANG Liwen， WU Yafei，et al. Polypyrrole/carbon nanotube composites as cathode material for performance enhancing of capacitive deionization technology［J］. Desalination，2014，354：62-67. doi:10.1016/j.desal.2014.09.021
46	WANG Hualan， HAO Qingli， YANG Xujie，et al. Graphene oxide doped polyaniline for supercapacitors［J］. Electrochemistry Communications，2009，11（6）：1158-1161. doi:10.1016/j.elecom.2009.03.036

		活性炭基电极	石墨烯基电极	碳气凝胶基电极	碳纳米基电极
优点	比表面积大	√		√
	孔隙率高	√	√	√
	比电容高	√	√		√
	孔径可控			√
	导电性好		√		√
	导热性好		√	√	√
	密度低		√		√
	化学稳定好			√	√
	再生性好	√		√
	技术成熟度	技术较成熟，有一定工业应用	正逐渐走向工业化	处于研究阶段	处于研究阶段
	应用前景广泛	√	√	√	√
缺点	导电性差	√
	易团聚		√
	工艺复杂	√	√	√	√
	成本高		√	√	√
	规模化生产难度大			√	√
	有环境污染风险		√		√

		活性炭基电极	石墨烯基电极	碳气凝胶基电极	碳纳米基电极
优点	比表面积大	√		√
	孔隙率高	√	√	√
	比电容高	√	√		√
	孔径可控			√
	导电性好		√		√
	导热性好		√	√	√
	密度低		√		√
	化学稳定好			√	√
	再生性好	√		√
	技术成熟度	技术较成熟，有一定工业应用	正逐渐走向工业化	处于研究阶段	处于研究阶段
	应用前景广泛	√	√	√	√
缺点	导电性差	√
	易团聚		√
	工艺复杂	√	√	√	√
	成本高		√	√	√
	规模化生产难度大			√	√
	有环境污染风险		√		√

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[7]	Xiaoyan Liu,Yinan Wang,Xiejuan Lu,Cai Chen,Xiaohui Wu,Juan Mao. Study on the removal of arsenic by CPC modified activated carbon electrode [J]. Industrial Water Treatment, 2020, 40(2): 23-27.
[8]	Liu Xiaoyan, Li Guiju, Zhang Zhen, Zhao Ruihua. Research on the application of membrane-electrode to the treatment of wastewater from mining [J]. INDUSTRIAL WATER TREATMENT, 2016, 36(7): 86-89,100.
[9]	Liu Yanhui, Xu Ke, Zhang Xiaochen. Research on polypyrrole/activated carbon composite electrode used for the electro-adsorbability for different ions [J]. INDUSTRIAL WATER TREATMENT, 2016, 36(10): 28-31.
[10]	Xiao Shubin, Xu Ke, Ruan Guoling. Influence of activated carbon loading on the deionization performance of electrode capacitance [J]. INDUSTRIAL WATER TREATMENT, 2012, 32(9): 32-34.
[11]	Chen Zhaolin, Song Cunyi, Sun Xiaowei, Guo Hongfei. Progress in the research on the electrosorption desalination technology and its application [J]. INDUSTRIAL WATER TREATMENT, 2011, 31(4): 11-14.
[12]	Sun Shiqiang, Cheng Jie, Cao Gaoping, Yang Yusheng. Development of electrostaticdesalination techniques [J]. INDUSTRIAL WATER TREATMENT, 2006, 26(10): 1-5.

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