Research progress of preparation process of graphene/ semiconductor metal oxide composite photocatalysts

doi:10.19965/j.cnki.iwt.2022-1287

Abstract

Abstract:

Photocatalysts are widely used in water pollution treatment，air purification，disease treatment and environmental remediation because of their strong oxidation，high chemical stability，environmentally friendly and non-toxicity. In order to improve the photo-response range，adding graphene-based series materials has become a hotspot all over the world. This paper reviewed the research status of the graphene-based materials and semiconductor metal oxide composite photocatalysts. The effects of preparation process on the morphological structure and photocatalytic performance of the graphene/semiconductor metal oxide composites were summarized. The advantages and disadvantages of the preparation processes of the graphene /semiconductor metal oxide composites were compared. Relevant problems of the processes were stated briefly， and the development direction of the graphene/semiconductor metal oxide composite photocatalysts was prospected.It was expected to provide a reference for improving the photocatalytic performance of semiconductor metal oxide photocatalysts and optimizing the preparation process of the graphene/semiconductor metal oxide composites.

Key words: graphene, semiconductor metal oxide, photocatalyst, preparation process

摘要：

光催化剂因其具有强氧化性、高化学稳定性、环保、无毒性等优点，广泛应用于污水处理、空气净化、疾病治疗、环境修复等领域。为改善纳米光催化剂的光响应范围，添加石墨烯基系列材料已成为国内外的研究热点。综述了石墨烯基材料与半导体金属氧化物复合光催化剂研究现状，总结了不同制备工艺对石墨烯基/半导体金属氧化物复合光催化剂形貌结构和光催化性能的影响，对各类制备工艺的优缺点进行了比较，并指出了相关工艺需要克服的关键技术问题，展望了石墨烯基/半导体金属氧化物复合光催化剂未来发展方向，以期为提高半导体金属氧化物的光催化性能和石墨烯基/半导体金属氧化物复合光催化剂制备工艺的优化提供参考。

关键词: 石墨烯, 半导体金属氧化物, 光催化剂, 制备工艺

CLC Number:

TQ426

Ning WANG, Jiayi LI, Tao LI, An XUE, Lu CHEN, Yang LI. Research progress of preparation process of graphene/ semiconductor metal oxide composite photocatalysts[J]. Industrial Water Treatment, 2024, 44(2): 63-72.

王宁, 林家一, 李涛, 薛安, 陈璐, 黎阳. 石墨烯基/半导体金属氧化物复合光催化剂制备工艺研究进展[J]. 工业水处理, 2024, 44(2): 63-72.

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URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2022-1287

https://www.iwt.cn/EN/Y2024/V44/I2/63

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制备工艺	优点	缺点
溶胶-凝胶法	生产周期短、易于工业化生产、副反应少	产物易团聚
水热/溶剂热法	粒径可控、晶粒发育完整、反应条件温和、产物不易团聚	反应条件要求严格、产率低
静电自组装法	产物结构稳定	表面活性剂的选择要求严格
超声喷雾热解法	产物形状规则、尺寸均匀、纯度高	操作要求高、工业化生产困难
原位生长法	反应条件温和、能耗低、产物性能稳定	需要其他制备工艺辅助
微波辅助法	无需催化剂或表面活性剂辅助、加热均匀且速率快	微波辅助所需能量高
紫外辅助光催化还原法	无需稳定剂、制备过程绿色环保	紫外辅助所需能量高
声化学法	产物不易团聚	超声波辐射所需能量高
液相沉积法	无需热处理、操作简单、重现性好	反应条件要求严格、多用于制备薄膜材料
化学气相沉积法	产物质量高、尺寸及层数可控	高温高压所需能量高

制备工艺	优点	缺点
溶胶-凝胶法	生产周期短、易于工业化生产、副反应少	产物易团聚
水热/溶剂热法	粒径可控、晶粒发育完整、反应条件温和、产物不易团聚	反应条件要求严格、产率低
静电自组装法	产物结构稳定	表面活性剂的选择要求严格
超声喷雾热解法	产物形状规则、尺寸均匀、纯度高	操作要求高、工业化生产困难
原位生长法	反应条件温和、能耗低、产物性能稳定	需要其他制备工艺辅助
微波辅助法	无需催化剂或表面活性剂辅助、加热均匀且速率快	微波辅助所需能量高
紫外辅助光催化还原法	无需稳定剂、制备过程绿色环保	紫外辅助所需能量高
声化学法	产物不易团聚	超声波辐射所需能量高
液相沉积法	无需热处理、操作简单、重现性好	反应条件要求严格、多用于制备薄膜材料
化学气相沉积法	产物质量高、尺寸及层数可控	高温高压所需能量高

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