工业水处理 ›› 2018, Vol. 38 ›› Issue (1): 87-89,102. doi: 10.11894/1005-829x.2018.38(1).087

• 试验研究 • 上一篇    下一篇

混凝沉淀-微电解-Fenton氧化处理颜料废水的研究

赵选英1, 戴建军1,2, 杨峰1, 郑刚1, 李鹏章1,2   

  1. 1. 南京大学盐城环保技术与工程研究院, 江苏盐城 224001;
    2. 江苏省产业技术研究所水环境工程技术研究所, 江苏盐城 224001
  • 收稿日期:2017-10-05 出版日期:2018-01-20 发布日期:2018-02-12
  • 作者简介:赵选英(1981-),硕士,工程师。电话:18261290007,E-mail:zxuanying@qq.com。

Research on the treatment of dyeing wastewater by coagulating sedimentation-microeletrolysis-Fenton oxidation process

Zhao Xuanying1, Dai Jianjun1,2, Yang Feng1, Zheng Gang1, Li Pengzhang1,2   

  1. 1. Nanjing University & Yancheng Academy of Environmental Protection Technology and Engineering, Yancheng 224001, China;
    2. Institute of Water Environmental Engineering and Technology, Jiangsu Industrial Technology Research Institute, Yancheng 224001, China
  • Received:2017-10-05 Online:2018-01-20 Published:2018-02-12

摘要: 对某颜料企业高浓度洗涤废水进行了混凝沉淀、微电解-Fenton氧化的处理研究。结果表明,在pH=12,PAC投加量为250 mg/L时,COD、LAS、SS去除率分别为47.8%、47%、52%。微电解-Fenton氧化的最佳条件为:铸铁粉投加量为0.3 g/L,微电解反应时间为1 h,双氧水投加量为10 mL/L,Fenton氧化时间为3 h。研究发现将混凝沉淀置于微电解-Fenton氧化前可提高处理效率,COD、LAS总去除率分别高达77.9%、98%。

关键词: 混凝沉淀, 铁碳微电解, Fenton氧化, 污泥呼吸, 生物毒性

Abstract: The research on the coagulating sedimentation-microeletrolysis-Fenton oxidation process for treating high-ly concentrated washing wastewater in a pigment enterprise has been accomplished. The results show that when pH=12, polyaluminium chloride dosage is 250 mg/L, removing rates of COD, LAS, and SS are 47.8%, 47% and 52% res-pectively, the optimal conditions of microeletrolysis-Fenton oxidation process are as follows:the dosage of cast iron powder is 0.3 g/L, reaction time of microelectrolysis 1 h, dosage of hydrogen peroxide 10 mL/L, and oxidation time of Fenton 3 h. The results show that setting coagulation sedimentation ahead of microelectrolysis-Fenton oxidation can improve the efficiency of wastewater treatment. The total removing rates of COD and LAS are as high as 77.9% and 98% respectively.

Key words: coagulating sedimentation, iron-carbon microeletrolysis, Fenton oxidation, sludge respiration, biotoxicity

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