生物炭复合材料在废水处理中的应用研究进展

doi:10.11894/iwt.2019-0390

摘要/Abstract

摘要： 本研究通过大量的文献调研，系统地综述了生物炭复合材料的制备方法及其在废水处理中的应用。梳理和总结了生物炭-纳米复合材料、生物炭-磁性复合材料和生物炭-无机复合材料的制备方法和特点，以及炭复合材料在重金属废水处理、有机工业废水处理中的应用研究进展，并对未来研究发展提出了建议。

关键词: 生物炭, 复合材料, 吸附剂, 工业废水处理, 研究进展

Abstract: In this paper,the preparation methods of biochar composites and their applications in wastewater treatment were systematically reviewed. The preparation methods and characteristics of biochar-nano composite,biochar-magnetic composite and biochar-inorganic composite were summarized,and the application of biochar composite in heavy metal wastewater treatment and organic industrial wastewater treatment were also reviewed. Some suggestions for future research and development are also given.

Key words: biochar, composite materials, adsorbent, industrial wastewater treatment, research progress

中图分类号:

X703

蒲生彦, 贺玲玲, 刘世宾. 生物炭复合材料在废水处理中的应用研究进展[J]. 工业水处理, 2019, 39(9): 1-7.

Pu Shengyan, He Lingling, Liu Shibin. Review on the preparation of biochar composites and its applications in wastewater treatment[J]. Industrial Water Treatment, 2019, 39(9): 1-7.

https://www.iwt.cn/CN/Y2019/V39/I9/1

参考文献

[1] Zhang P,Sun H,Min L,et al. Biochars change the sorption and degradation of thiacloprid in soil:insights into chemical and biological mechanisms[J]. Environmental Pollution,2018,236:158-167.
[2] Sizmur T,Fresno T,Akgül G,et al. Biochar modification to enhance sorption of inorganics from water[J]. Bioresource Technology,2017, 246:34-47.
[3] Sun K,Ro K,Guo M X,et al. Sorption of bisphenol A,17α-ethinyl estradiol and phenanthrene on thermally and hydrothermally produced biochars[J]. Bioresource Technology,2011,102(10):5757-5763.
[4] Shaheen S M,Khan N N,Hassan N,et al. Wood-based biochar for the removal of potentially toxic elements in water and wastewater:a critical review[J]. International Materials Reviews,2018,64(4):1-32.
[5] Brewer C E. Biochar characterization and engineering[D]. Iowa:Iowa State University,2012.
[6] 郭平,王观竹,许梦,等. 不同热解温度下生物质废弃物制备的生物质炭组成及结构特征[J]. 吉林大学学报(理学版),2014,52(4):855-860.
[7] 孙涛,朱新萍,李典鹏,等. 不同原料生物炭理化性质的对比分析[J]. 农业资源与环境学报,2017,34(6):543-549.
[8] 朱丹丹,周启星. 功能纳米材料在重金属污染水体修复中的应用研究进展[J]. 农业环境科学学报,2018(8):7-20.
[9] Li K,Huang Z,Zhu S,et al. Removal of Cr(Ⅵ) from water by a biochar-coupled g-C₃N₄ nanosheets composite and performance of a recycled photocatalyst in single and combined pollution systems[J]. Applied Catalysis B:Environmental,2019,243:386-396.
[10] Yan L,Kong L,Qu Z,et al. Magnetic biochar decorated with ZnS nanocrytals for Pb(Ⅱ) removal[J]. ACS Sustainable Chemistry & Engineering,2015,3(1):125-132.
[11] Tan X. Biochar-based nano-composites for the decontamination of wastewater:a review[J]. Bioresour. Technol.,2016,212:318-333.
[12] Devi P,Saroha A K. Simultaneous adsorption and dechlorination of pentachlorophenol from effluent by Ni-ZVI magnetic biochar composites synthesized from paper mill sludge[J]. Chemical Engineering Journal,2015,271:195-203.
[13] 周银,张平,李四坤,等. 磁性生物炭材料的研究进展[J]. 当代化工研究,2018,35(11):9-11.
[14] 吴明山,马建锋,杨淑敏,等. 磁性生物炭复合材料研究进展[J]. 功能材料,2016,47(7):7028-7033.
[15] 张越,林珈羽,刘沅,等. 改性生物炭对镉离子吸附性能研究[J]. 武汉科技大学学报,2015,39(1):48-52.
[16] Zhang Y,Cao B,Zhao L,et al. Biochar-supported reduced graphene oxide composite for adsorption and coadsorption of atrazine and lead ions[J]. Applied Surface Science,2017,427:147-155.
[17] Mubarak N M,Kundu A,Sahu J N,et al. Synthesis of palm oil empty fruit bunch magnetic pyrolytic char impregnating with FeCl₃ by microwave heating technique[J]. Biomass and Bioenergy,2014,61:265-275.
[18] Zhou L,Huang Y F,Qiu W W,et al. Adsorption properties of nanoMnO₂-biochar composites for copper in aqueous solution[J]. Molecules,2017,22(1):173.
[19] Rajendran M,Shi L Z,Wu C,et al. Effect of sulfur and sulfur-iron modified biochar on cadmium availability and transfer in the soilrice system[J]. Chemosphere,2019,222:314-322.
[20] Jung K W,Lee S Y,Lee Y J. Hydrothermal synthesis of hierarchically structured birnessite-type MnO₂/biochar composites for the adsorptive removal of Cu(Ⅱ) from aqueous media[J]. Bioresource Technology,2018,260:204-212.
[21] Liu Yuyan,Sohi S P,Liu Siyuan,et al. adsorption and reductive degradation of Cr(Ⅵ) and TCE by a simply synthesized zero valent iron magnetic biochar[J]. Journal of Environmental Management, 2019,235:276-281.
[22] Nguyen N T,Hsiao S S,Chen S S,et al. Preparation of Zn-doped amino functionalized biochar from hazardous waste for arsenic removal[J]. Journal of Nanoscience and Nanotechnology,2019,19(5):2649-2657.
[23] Park J H,Wang J J,et al. Removing mercury from aqueous solution using sulfurized biochar and associated mechanisms[J]. Environmental Pollution,2018,244:627-635.
[24] Wang S S,Gao B,Zimmerman A R,et al. Removal of arsenic by magnetic biochar prepared from pinewood and natural hematite[J]. Bioresource Technology,2015,175:391-395.
[25] Song Z,Lian F,Yu Z,et al. Synthesis and characterization of a novel MnOx-loaded biochar and its adsorption properties for Cu²⁺ in aqueous solution[J]. Chemical Engineering Journal,2014,242:36-42.
[26] Hu X,Ding Z H,Zimmerman A R,et al. Batch and column sorption of arsenic onto iron-impregnated biochar synthesized through hydrolysis[J]. Water Research,2015,68:206-216.
[27] Wang S Y,Tang Y K,Chen C,et al. Regeneration of magnetic biochar derived from eucalyptus leaf residue for lead(Ⅱ) removal[J]. Bioresource Technology,2015,186:360-364.
[28] Vithanage M,Mayakaduwa S S,Herath I,et al. Kinetics,thermodynamics and mechanistic studies of carbofuran removal using biochars from tea waste and rice husks[J]. Chemosphere,2016,150:781-789.
[29] Meili L,Lins P V,Zanta C L P S,et al. MgAl-LDH/Biochar composites for methylene blue removal by adsorption[J]. Applied Clay Science,2019,168:11-20.
[30] Zhang Y,Fan R M,Zhang Q K,et al. Synthesis of CaWO₄-biochar nanocomposites for organic dye removal[J]. Materials Research Bulletin,2019,110:169-173.
[31] Jiang X Y,Ouyang Z Z,Zhang Z F,et al. Mechanism of glyphosate removal by biochar supported nano-zero-valent iron in aqueous solutions[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2018,547:64-72.
[32] Gao M,Zhang Y,Gong X,et al. Removal mechanism of di-n-butyl phthalate and oxytetracycline from aqueous solutions by nano-manganese dioxide modified biochar[J]. Environmental Science and Pollution Research,2017,25(8):7796-7807.
[33] Zhang M,Gao B,Yao Y,et al. Synthesis,Characterization,and environmental implications of graphene-coated biochar[J]. Science of the Total Environment,2012,435/436:567-572.
[34] Inyang M,Gao B,Zimmerman A,et al.Synthesis,characterization, and dye sorption ability of carbon nanotube-biochar nanocomposites[J]. Chemical Engineering Journal,2014,236:39-46.
[35] Tang J C,Lü H,Gong Y Y,et al. Preparation and characterization of a novel graphene/biochar composite for aqueous phenanthrene and mercury removal[J]. Bioresource Technology,2015,196:355-363.
[36] Karakoyun N,Kubilay S,Aktas N,et al. Hydrogel-biochar composites for effective organic contaminant removal from aqueous media[J]. Desalination,2011,280(1/2/3):319-325.
[37] Devi P,Saroha A K. Synthesis of the magnetic biochar composites for use as an adsorbent for the removal of pentachlorophenol from the effluent[J]. Bioresource Technology,2014,169:525-531.
[38] Li H,Dong X,Da Silva E B,et al. Mechanisms of metal sorption by biochars:biochar characteristics and modifications[J]. Chemosphere,2017,178:466-478.
[39] Lu H,Zhang W,Yang Y,et al. Relative distribution of Pb²⁺ sorption mechanisms by sludge-derived biochar[J]. Water Research,2012, 46(3):854-862.
[40] Wang X,Li X,Liu G,et al. Mixed heavy metal removal from wastewater by using discarded mushroom-stick biochar:adsorption properties and mechanisms[J]. Environmental Science:Processes & Impacts,2019,21(3):584-592.
[41] Li Boyu,Li Kunquan. Effect of nitric acid pre-oxidation concentration on pore structure and nitrogen/oxygen active decoration sites of ethylenediamine-modified biochar for mercury(Ⅱ) adsorption and the possible mechanism[J]. Chemosphere,2019,220:28-39.
[42] Fan Z,Zhang Q,Li M,et al. Investigating the sorption behavior of cadmium from aqueous solution by potassium permanganate-modified biochar:quantify mechanism and evaluate the modification method[J]. Environmental Science and Pollution Research,2018,25(9):8330-8339.
[43] Chen B L,Zhou D D,Zhu L Z. Transitional adsorption and partition of nonpolar and polar aromatic contaminants by biochars of pine needles with different pyrolytic temperatures[J]. Environmental Science & Technology,2008,42(14):5137-5143.
[44] Keiluweit M,Nico P S,Johnson M G,et al. Dynamic molecular structure of plant biomass-derived black carbon(biochar)[J]. Environmental Science & Technology,2010,44(4):1247-1253.
[45] Sun K,Jin J,Keiluweit M,et al. Polar and aliphatic domains regulate sorption of phthalic acid esters(PAEs) to biochars[J]. Bioresource Technology,2012,118(8):120-127.
[46] Chen C P,Zhou W J,Lin D H. Sorption characteristics of N-nitrosodimethylamine onto biochar from aqueous solution[J]. Bioresource Technology,2015,179:359-366.
[47] Sewu D D,Jung H,Kim S S,et al. Decolorization of cationic and anionic dye-laden wastewater by steam-activated biochar produced at an industrial-scale from spent mushroom substrate[J]. Bioresource Technology,2019,277:77-86.
[48] 季雪琴,吕黎,陈芬,等. 秸秆生物炭对有机染料的吸附作用及机制[J]. 环境科学学报,2016,36(5):1648-1654.
[49] 刘世功,武治勇. 含酚废水处理技术研究[J]. 化工管理,2018(2):131-131.
[50] Lee C G,Hong S H,Hong S G,et al. Production of biochar from food waste and its application for phenol removal from aqueous solution[J]. Water,Air,& Soil Pollution,2019,230(3):70.
[51] Mohammed N A S,Abu-Zurayk R A,Hamadneh I,et al. Phenol adsorption on biochar prepared from the pine fruit shells:Equilibrium, kinetic and thermodynamics studies[J]. Journal of Environmental Management,2018,226:377-385.
[52] Fitzgerald S,Kolar P,Classen J,et al. Swine manure char as an adsorbent for mitigation of p-cresol[J]. Environmental Progress & Sustainable Energy,2014,34(1):125-131.
[53] Silvani L,Cornelissen G,Hale S E. Sorption of α-, β-, γ- and δ- hexachlorocyclohexane isomers to three widely different biochars:Sorption mechanisms and application[J]. Chemosphere, 2019, 219:1044-1051.

选择文件类型/文献管理软件名称

选择包含的内容