工业水处理 ›› 2002, Vol. 22 ›› Issue (3): 53-55. doi: 10.11894/1005-829x.2002.22(3).53

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微滤膜-胺基膦酸树脂法处理含镍电镀废水

史红文1, 李晓湘1, 夏畅斌1, 冯镜元2   

  1. 1. 湘潭高科环境设备有限公司 湖南湘潭 411201;
    2. 湘潭工学院化学工程系 湖南湘潭 411201
  • 收稿日期:2001-08-19 出版日期:2002-03-20 发布日期:2010-10-01
  • 作者简介:史红文(1967- ),1989年毕业于湖南大学环境工程专业,讲师,现就职于湘潭工学院化工系。

Treatment of nickel-containing electroplating wastewater by micro-filtration membrane and amidocyanogen-phosphonic acid resin

SHI Hongwen1, Li Xiaoxiang1, XIA Changbin1, FENG Jingyuan2   

  1. 1. Dept. of Chemical Eng. of Xiangtan Polytechnic University, Xiangtan 411201, China;
    2. Xiangtan High tech Environmental Protection Equipment Co., Ltd., Xiangtan 411000, China
  • Received:2001-08-19 Online:2002-03-20 Published:2010-10-01

摘要:

介绍了微滤膜-胺基膦酸树脂法处理含镍电镀废水工艺:采用无机陶瓷微滤膜进行预过滤,防止杂质、油污带入而引起树脂中毒失效,利用胺基膦酸树脂高效回收电镀废水中的Ni2+。该工艺简单、操作稳定、运行成本较低,回收的Ni2+浓度大、纯度高,可直接返回电镀生产工序使用。并确定了主要技术参数:无机微滤膜孔径0.8μm,交换操作流速5.2m/h,再生液4%~5%(质量分数)H2SO4,再生液用量3~3.5BV,再生流速1~2BV/h,再生方式顺流。实际应用表明效果良好。

关键词: 微滤, 树脂, 电镀废水

Abstract:

The technique of treating nickel containing electroplating wastewater by micro filtration membrane and amidocyanogen phosphonic acid resin is introduced: inorganic membrane is used to prefiltrate to prevent impurity and oil from entering resin before Ni2+ is high efficiently recycled with it.The process is characterized by its simplicity,stability and lower cost.The concentration and purity of Ni2+ recycled is so high that it can reuse in manufacture process.The main technical parameters are determined:0.8 μm of inorganic micro filtration pore size,5.2 m/h of exchanging velocity,4%~5% H 2SO 4 concentration,3~3.5BV of regeneration fluid,1~2 BV/ h of regenerating velocity,regenerating in the same direction.The result shown in practice is good.

Key words: micro filtration, resin, electroplating wastewater

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