工业水处理 ›› 2002, Vol. 22 ›› Issue (6): 32-35. doi: 10.11894/1005-829x.2002.22(6).32

• 试验研究 • 上一篇    下一篇

固体三元稳态ClO2杀菌剂稳定性、腐蚀性及杀菌消毒特性研究

李新杰, 唐淑娟, 包训祥   

  1. 南京理工大学化工学院, 江苏, 南京 210094
  • 收稿日期:2001-11-22 出版日期:2002-06-20 发布日期:2010-10-01
  • 作者简介:李新杰(1966-),1988年沈阳工业学院环境监测专业毕业,硕士,在职博士生,南京理工大学化工学院水处理工程技术中心工程师.联系电话:025-4316732,13805181091,E-mail:lxjie@public1.ptt.js.cn.

Research on the stability,corrodibility and disinfection actions of trinary solid stable chlorine dioxide

LI Xinjie, TANG Shujuan, BAO Xunxiang   

  1. Chemical School, Nanjing University of Science and Technology, Nanjing 210094, China
  • Received:2001-11-22 Online:2002-06-20 Published:2010-10-01

摘要:

对固体三元稳态二氧化氯杀菌剂的稳定性、腐蚀性及杀菌消毒特性进行研究后发现, 该杀菌剂ClO2 活化得率在95.5%以上 ;活化酸度为pH=4.84;于 (54±1)℃放置 14d, ClO2 含量的下降率为3.1%;用ClO2 质量浓度 80mg/L的消毒液作用 3~ 5min, 对大肠杆菌和金黄色葡萄球菌的杀灭率为100% ;ClO2质量浓度400mg/L的消毒液作用60min对枯草杆菌黑色变种芽孢的杀灭率为100% ;ClO2质量浓度300mg/L的消毒液作用20min, 可以完全破坏悬液中HBsAg的抗原性 ;ClO2质量浓度800mg/L的消毒液对不锈钢基本无腐蚀, 对铜片、碳钢、铝片均有中度腐蚀。

关键词: 固体三元稳态, 二氧化氯, 稳定性, 腐蚀性, 杀菌消毒特性

Abstract:

Trinary solid stable chlorine dioxide is a new type of powerful disinfectant which possesses the properties of high efficiency and speed, low acidity and less loss of ClO2 in activating reaction. In order to learn more about the disinfectant, experiments have been carried out to study its stability, corrodibility, and disinfecting actions, etc. The results show that (1) the gain rate of ClO2 is 96.5%, acidity of activating solution is pH=4.84, and the decreasing rate of ClO2 is 3.1% followed by a storage for 14 days at (54±1) ℃; (2)its solution containing ClO2 80 mg/L can kill 100% Escherichia coli and Staphylococcus aureus in 3~5 min, its solution containing ClO2 400 mg/L can also kill 100% Bacillus subtilis var. niger spores in 60 min, its solution containing ClO2 300 mg/L can fully destroy antigenicity of HBsAg in a 20 min contact time;(3) a solution of the disinfectant at a concentration of 800 mg/L ClO2 is essentially non corrosive to stainless steel and moderate corrosive to carbon steel, copper, and aluminum.

Key words: trinary solid in stable state, chlorine dioxide, stability, corrodibility, disinfection

中图分类号: