工业水处理 ›› 2004, Vol. 24 ›› Issue (2): 23-25. doi: 10.11894/1005-829x.2004.24(2).23

• 试题研究 • 上一篇    下一篇

二元酸废水的生物-光催化氧化组合处理技术

于永辉1, 刘守新1,2, 李作臣3, 孙承林1, 肖羽堂1   

  1. 1. 中国科学院大连化学物理研究所, 辽宁大连 116023;
    2. 东北林业大学, 黑龙江哈尔滨 150040;
    3. 中国石油辽河油田分公司沈阳采油厂, 辽宁沈阳 11000
  • 收稿日期:2003-09-20 出版日期:2004-02-20 发布日期:2010-10-01
  • 作者简介:于永辉(1973- ),1996年毕业于吉林化工学院,工程师.电话:0411-4379326.
  • 基金资助:

    中国博士后科学基金资助项目(编号:2002032174)

Treatment of diacid wastewater by the combinationof biological and photocatalytical oxidation methods

Yu Yonghui1, Liu Shouxin1,2, 3, Li Zuochen1, Sun Chenglin1   

  1. 1. Dalian Institute of Chemical Physics, The Chinese Academy of Science, Dalian 116023, China;
    2. Northeast Forestry University, Harbin 150040, China;
    3. Shenyang Oil Extraction Mill, Petro China Liaohe Oilfield Co., Shenyang 110000, China
  • Received:2003-09-20 Online:2004-02-20 Published:2010-10-01

摘要:

针对混合(C4~C6)二元酸废水特点,以CODCr、色度作为评价指标,采用生物流化床-Ag/TiO2光催化氧化组合处理技术对其进行处理,并对反应条件进行优化。结果表明,采用该组合处理技术可有效去除二元酸废水CODCr及色度。当生物流化床水力停留时间10h,出水采用Ag/TiO2光催化氧化处理技术,反应器内停留时间45min,CODCr去除率96.1%,色度去除率>97.4%,完全达到二级排放要求。

关键词: 二元酸废水, 生物流化床, Ag/TiO2光催化

Abstract:

Based on the characteristics of (C4 ~ C6) mixed diacid wastewater, it is treated by the combination of biological and photocatalytical methods, and the treatment condition is optimized. The result shows that this combination processing technology can remove CODCr and chroma efficiently, especially for chroma. When the retention time at biological fluidized-bed is 10 h, then the effluent is faced to photocatalytic treatment for 45 min, the removal rate of CODCr and chroma reaches 96.1% and 97.4% respectively.

Key words: diacid wastewater, biological fluidized-bed, Ag/TiO2 photocatalysis

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