壳聚糖吸附处理低浓度重金属废水

doi:10.11894/1005-829x.2009.29(9).6

摘要/Abstract

摘要：

壳聚糖类生物质材料因其良好的吸附性能、广泛的来源以及低廉的成本,在水中重金属和有机污染物的吸附处理中被广泛使用。综述了壳聚糖吸附处理低浓度重金属废水的研究进展,重点比较了壳聚糖微球与壳聚糖膜对水体中重金属离子的吸附效果,总结了用以提高壳聚糖吸附剂性能(如吸附容量、吸附选择性、稳定性等)的各种途径及其改善效果。针对壳聚糖类重金属吸附剂应用中仍然存在的一些不足,结合废水处理的实际需求,探讨了今后的研究中值得关注的方向。

关键词: 壳聚糖微球, 壳聚糖膜, 吸附, 重金属离子

Abstract:

Because of its excellent adsorption capacity,easy obtainable sources and low cost,chitosan has been widely applied,as adsorbent,to the treatment of wastewater containing heavy metal and organic pollutants. The progress in the treatment of wastewater containing heavy metal by chitosan is summarized. The effects of the adsorptive efficiency of chitosan beads,chitosan membranes or films on the heavy metal ions in water body are compared emphatically. The ways of improving the heavy metal adsorbent performances,such as adsorbing volume,selectivity,stability,etc.,are summarized,too. Aiming at the deficiency in its application,and the real need of the wastewater treatment,the research direction worthy of concern in the future is discussed.

Key words: chitosan beads, chitosan membranes, adsorption, heavy metal ions

中图分类号:

X703.1

陈培榕, 吴耀国, 刘保超. 壳聚糖吸附处理低浓度重金属废水[J]. 工业水处理, 2009, 29(9): 6-10.

Chen Peirong, Wu Yaoguo, Liu Baochao. Progress of the treatment of wastewater containing heavy metal with low concentration by chitosan-based adsorbents[J]. INDUSTRIAL WATER TREATMENT, 2009, 29(9): 6-10.

https://www.iwt.cn/CN/Y2009/V29/I9/6

参考文献

[1] Crini G.Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment[J].Progress in Polymer Science,2005,30(1):38-70.
[2] Rinaudo M.Chitin and chitosan:Properties and applications[J].Progress in Polymer Science,2006,31(7):603-632.
[3] 孙胜玲,王丽,吴瑾,等.壳聚糖及其衍生物对金属离子的吸附研究(上)[J].高分子通报,2005(5):58-68.
[4] Paulino A T,Santos L B,Nozaki J.Removal of Pb²⁺,Cu²⁺,and Fe³⁺ from battery manufacture wastewater by chitosan produced from silkworm chrysalides as a low-cost adsorbent[J].Reactive ＆ Functional Polymers,2008,68(2):634-642.
[5] Wu Zhongbiao,Ni Weimin,Guan Baohong.Application of chitosan as flocculant for coprecipitation of Mn(Ⅱ) and suspended solids from dual-alkali FGD regenerating process[J].Journal of Hazardous Materials,2008,152(2):757-764.
[6] Ngah W W S,Kamari A,Koay Y J.Equilibrium and kinetics studies of adsorption of copper(Ⅱ) on chitosan and chitosan/PVA beads[J].International Journal of Biological Macromolecules,2004,34(3):155-161.
[7] Shafaei A,Ashtiani F,Kaghazchi T.Equilibrium studies oftbe sorption of Hg(Ⅱ) ions onto chitosan[J].Chemical Engineering Journal,2007,133(1f2/3):311-316.
[8] Demetgu C,Serin S.Synthesis and characterization of a new vicdioxime derivative of chitosan and its transition metal complexes[J].Carbohydrate Polymers,2008,72(3):506-512.
[9] Ramesh A,Hasegawa H,Sugimato W,et al.Adsorption of gold(Ⅲ),platinum(Ⅳ) and palladium(Ⅱ) onto glycine modified cross linked chitosan resin[J].Bioresource Technology,2008,99(9):3801-3809.
[10] Tabakci M,Yilmaz M.Synthesis of a chitosan-linked calix(4) arene chelating polymer and its sorption ability toward heavy metals and dichromate anions[J].Bioresource Technology,2008,99(14):6642-6645.
[11] Zhan Fan,Yu Binyu,Yue Zhengrong,et al.Preparation of porous chitosan gel beads for copper(Ⅱ) ion adsorption[J].Journal of Hazardous Materials,2007,147(1/2):67-73.
[12] Merrifield J,Davids W,MacRae J,et al.Uptake of mercury by thiol-grafted chitosan gel beads[J].Water Research,2004,38(13):3132-3138.
[13] Zha Fei,Li Shaoguang,Chang Yue.Preparation and adsorption property of chitosan beads bearing β-cyclodextrin cross-linked by 1,6-hexamethylene diisocyanate[J].Carbohydrate Polymers,2008,72(3):456-461.
[14] Kim W T,Chung H,Shin I S.Characterization of calcium alginate and chitosan-treated calcium alginate gel beads entrapping allyl isothiocyanate[J].Carbohydrate Polymers,2008,71(4):566-573.
[15] Vijaya Y,Popuri S,Beddu V,et al.Modified ehitosan and calcium alginate biopolymer sorbents for removal of nickel(Ⅱ) through adsorption[J].Carbohydrate Polymers,2008,72(2):261-271.
[16] Hasan S,Ghosh T,Viswanath D,et al.Dispersion of chitosan on perlite for enhancement of copper(Ⅱ) adsorption capacity[J].Journal of Hazardous Materials,2008,152(2):826-837.
[17] Chen Fei,Dao Guangsheng,Yang Weiwei.Preparation and adsorption ability of polysulfone microcapsules containing modified chitosan gel[J].Tsinghua Science and Technology,2005,10(5):535-541.
[18] 韩德艳,蒋霞,谢长生.交联壳聚糖磁性微球的制备及其对金属离子的吸附性能[J].环境化学,2006,25(6):748-751.
[19] 周利民,王一平,黄群武,等.改性磁性壳聚糖微球对Cu²⁺、Cd²⁺和Ni²⁺的吸附性能[J].物理化学学报,2007,23(12):1979-1984.
[20] 周利民,王一平,刘峙嵘,等.羧甲基化壳聚糖-Fe3O4纳米粒子的制备及对Zn²⁺的吸附行为[J].物理化学学报,2006,22(11):1342-1344.
[21] Donia A,Atia A,Eiwakeel K.Selective separation of mercury(Ⅱ) using magnetic ehitosan resin modified with Schiff's base derived from thiourea and glutaraldehyde[J].Journal of Hazardous Materials,2008,151(2/3):372-379.
[22] Hsieh F M,Huang C,Lin T F,et al.Study of sodium tripolyphosphate-cresslinked ehitesan beads entrapped with Pseudomonas putida for phenol degradation[J].Process Biochemistry,2008,43(1):83-92.
[23] Onal S,Baysal S H,Ozdemir G.Studies on the applicability of alginate-entrapped Chryseomonas luteola TEM 05 for heavy metal biosorption[J].Journal of Hazardous Materials,2007,146(1/2):417-420.
[24] Lin C C,Lai Y T.Adsorption and recovery of lead(Ⅱ) from aqueous solutions by immobilized Pseudomonas Aeruginosa PU21 beads[J].Journal of Hazardous Materials A,2006,137(1):99-105.
[25] Chang M Y,Kao H C,Juang R S.Thermal inactivation and reactivity of β-glueosidase immobilized on chitosan-clay composite[J].International Journal of Biological Macromolecules,2008,43(1):48-53.
[26] Bai Pengli,Cao Fuming,Lan Xiaorong,et al.Chitesan gel beads immobilized Cu(Ⅱ) for selective adsorption of amino acids[J].Biochem.Biophys.Methods,2008,70(6):903-908.
[27] Wang Yujun,Wang Xianghua,Luo Guangsheng,et al.Adsorption of bovin serum albumin(BSA) onto the magnetic chitosan nanoparticles prepared by a mieroemulsion system[J].Bioresource Technology,2008,99(9):3881-3884.
[28] Cestari A,Vieira E,Mattos C.Thermodynamics of the Cu(Ⅱ) adsorption on thin vanillin-modified chitosan membranes[J].J.Chem.Thermodynamics,2006,38(9):1092-1099.
[29] Vieira R,Beppu M.Dynamic and static adsorption and desorption of Hg(Ⅱ) ions on chitosan membranes and spheres[J].Water Research,2006,40(8):1726-1734.
[30] Liu Chunxiu,Bai Renbi.Adsorptive removal of copper ions with highly porous chitosan/cellulose acetate blends hollow fiber membranes[J].Journal of Membrane Science,2006,284(1/2):313-322.
[31] Beppu M,Arruda E,Vieira R,et al.Adsorption of Cu(Ⅱ) on porous ehitosan membranes funetionalized with histidine[J].Journal of Membrane Science,2004,240(1/2):227-235.
[32] Baroni P,Vieira R S,Meneghetti E,et al.Evaluation of batch adsorption of chromium ions on natural and cross-linked ehitasan membranes[J].Journal of Hazardous Materials,2008,152(3):1155-1163.
[33] Han Wei,Liu Chunxiu,Bai Renbi.A novel method to prepare high chitosan content blend hollow fiber membranes using a nonacidie dope solvent for highly enhanced adsorptive performance[J].Journal of Membrane Science,2007,302(1/2):150-159.
[34] Akkaya R,Ulusoy U.Adsorptive features of chitosan entrapped in polyacrylamide hydrogel for Pb²⁺,UO2²⁺,and Th4+[J].Journal of Hazardous Materials,2008,151(2/3):380-388.
[35] Gotoh T,Matsushima K,Kikuchi K.Preparation of alginate-chitosan hybrid gel beads and adsorption of divalent metal ions[J].Chemosphere,2004,55(1):135-140.
[36] Lans R,Geremias R,Vasconcelos H,et al.Reduction of acidity and removal of metal ions from coal mining effluents using chitosan microspheres[J].Journal of Hazardous Materials,2007,149(2):471-474.
[37] Copello G,Varela F,Vivot R,et al.Immobilized chitosan as biosorbent for the removal of Cd(Ⅱ),Cr(Ⅲ) and Cr(Ⅳ) from aqueous solutions[J].Bioresource Technology,2008,99(14):6538-6544.
[38] Li Feng,Du Ping,Chen Wei,et al.Preparation of silica-sopported porous sorbent for heavy metal ions removal in wastewater treatment by organic-inorganic hybridization combined with sucrose and polyethylene glycol imprinting[J].Analytica Chimica Acta,2007,585(2):211-218.
[39] 唐雪娇,曹梦,毕成良,等.球形Ni²⁺模板交联壳聚糖吸附剂的多胺化及其对Ni²⁺的吸附性能[J].离子交换与吸附,2008,24(1):47-54.
[40] Li Guiyin,Jiang Yuren,Huang Kelong,et al.Preparation and properties of magnetic Fe3O4-chitasan nanopartieles[J].Journal of Alloys and Compounds,2008,466(1/2):451-456.

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