工业水处理 ›› 2009, Vol. 29 ›› Issue (3): 52-54. doi: 10.11894/1005-829x.2009.29.(03).52

• 试验研究 • 上一篇    下一篇

鸟粪石沉淀法在汽油精炼废水处理中的应用

邵文妹1, 宋玉2, 黄仁华3, 赵由才4   

  1. 1. 上海南汇区环境监测站,上海 201300;

    2. 上海同济建设有限公司,上海 200092;

    3. 上海老港废弃物处置有限公司,上海 201302;

    4. 同济大学污染控制与资源化研究国家重点实验室,上海 200092
  • 收稿日期:2008-11-30 出版日期:2009-03-20 发布日期:2010-10-01
  • 作者简介:邵文妹(1965- ),1987 年毕业于华东师范大学,主任,工程师。电话:13611924102。
  • 基金资助:

    教育部基金(305005);上海市科委重大专项(05DZ12003)

Application of struvite precipitation to the treatment of gasoline refinerywastewater

ShaoWenmei1, SongYu2, Huang Renhua3, ZhaoYoucai4   

  1. 1. Environmental Monitoring Station of Nanhui District,Shanghai,Shanghai 201300, China;
    2. Shanghai Tongji Construction Co.,Ltd.,Shanghai 200092, China;
    3. Shanghai Laogang Waste Disposal Plant,Shanghai 201302, China;
    4. National Key Laboratory of Pollution Control and Resource Reuse,Tongji University,Shanghai 200092, China
  • Received:2008-11-30 Online:2009-03-20 Published:2010-10-01

摘要:

针对汽油精炼废水中C/N低的现状,研究了鸟粪石沉淀法对后续生化工艺的影响。实验选择硫酸镁和磷酸二氢钾作沉淀剂,研究了不同pH和硫化物浓度下氨氮的去除效率。鸟粪石沉淀法能够将C/N提高到20左右,强化了后续生化处理工艺的出水水质。最终出水的氨氮质量浓度<5 mg/L,COD<50 mg/L,完全满足回用要求,达到了节水和环境保护的目的。

关键词: 磷酸氨镁, 汽油精炼, 硫化物, 鸟粪石, 生化处理

Abstract:

According to the low C/N in gasoline refinery wastewater (GRW), the effect of struvite precipitation(magnesium ammonium phosphate, MAP) on the sequent biological process has been investigated. MgSO4 andKH2PO4 are used as precipitants and the removing efficiency of NH4+-N with different pH and sulfide concentrationhas been studied. The precipitation of struvite could increase the ratio of C/N to about 20, which will enhance thesequent biological process and ameliorate the quality of effluent. The concentrations of NH4+-N and COD are lessthan 5 mg/L and 50 mg/L respectively. The effluent could meet the requirements of recycle, which effectively savesthe fresh water and protects the environment.

Key words: magnesium ammonium phosphate, gasoline refinery, sulfide, struvite, biological treatment

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