工业水处理 ›› 2011, Vol. 31 ›› Issue (12): 39-42. doi: 10.11894/1005-829x.2011.31(12).39

• 专论与综述 • 上一篇    下一篇

改性松树叶对六价铬的去除研究

杜婷,戴友芝,贾明畅,王辉,郭丽丽   

  1. 湘潭大学环境科学与工程系重金属污染控制湖南省普通高等学校重点实验室, 湖南湘潭 411105
  • 收稿日期:2011-09-27 修回日期:2011-09-27 出版日期:2011-12-20 发布日期:2011-12-31
  • 作者简介:杜婷( 1987-) , 2009级在读硕士研究生电话:13487326131, E-mail : mengting-911@163.com
  • 基金资助:

    湖南省科学技术厅科技计划重点项目(2011SK2016)

Research on the removal of chromium(VI)with modified pine needles

Du Ting,Dai Youzhi,Jia Mingchang,Wang Hui,Guo Lili   

  1. Department of Environmental Engineering,Key Laboratory of Heavy Metal Pollution Control,College of Hunan Province,Xiangtan University,Xiangtan 411105,China
  • Received:2011-09-27 Revised:2011-09-27 Online:2011-12-20 Published:2011-12-31

摘要:

采用氢氧化钠-异丙醇对松树叶进行化学改性,同时将改性松树叶用于对Cr(Ⅵ)的吸附实验。通过单因素实验,考察了处理条件对Cr(Ⅵ)吸附效果的影响。结果表明,对50 mL质量浓度为10.0 mg/L的Cr(Ⅵ)溶液,在溶液pH=3.0,投加改性松树叶0.2 g,温度30℃,接触时间90 min的条件下,Cr(Ⅵ)的去除率可达82%以上。改性松树叶在20~30℃对Cr(Ⅵ)的吸附是吸热过程,以离子交换吸附为主,吸附过程遵循Freundlich吸附等温线。

关键词: 改性松树叶, 吸附, Cr(Ⅵ)

Abstract:

The pine needles have been modified synchronously with the solution of sodium hydroxide-isopropanol.Then,the modified pine needles are used for adsorbing chromium(Ⅵ).The effects of treating conditions on adsorbing efficiency are studied through single-factor tests.The results show that when pH=3.0,the dosage of modified pine needles 0.2 g,temperature 30 ℃,and contact time 90 min,the Cr(Ⅵ) removing rate for 50 mL of Cr(Ⅵ)solution,whose mass concentration is 10.0 mg/L,reaches above 82%.The adsorption of Cr(Ⅵ) by modified pine needles at 20 ℃ to 30 ℃ is an endothermic process.It is mainly ion exchange adsorption.The adsorbing process follows the Freundlich adsorption isotherm.

Key words: modifying pine needles, adsorption, Chromium(VI)

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