工业水处理 ›› 2011, Vol. 31 ›› Issue (9): 26-29. doi: 10.11894/1005-829x.2011.31(9).26

• 试验研究 • 上一篇    下一篇

固定化血红蛋白催化去除废水中的五氯酚

李晓燕, 程四清   

  1. 乐山师范学院化学与生命科学系, 四川乐山 614000
  • 收稿日期:2011-07-23 修回日期:2011-07-23 出版日期:2011-09-20 发布日期:2011-09-29
  • 作者简介:李晓燕(1960- ),1983 年毕业于四川师范大学,教授。E-mail:ddli0833@163.com。
  • 基金资助:

    国家自然科学基金项目(20973087)

Removal of pentachlorophenol from wastewater by immobilized hemoglobin

Li Xiaoyan, Cheng Siqing   

  1. Department of Chemistry and Life Science, Leshan Normal University, Leshan 614000, China
  • Received:2011-07-23 Revised:2011-07-23 Online:2011-09-20 Published:2011-09-29

摘要:

以海藻酸钙胶囊固定活性炭和血红蛋白,研究了H2O2存在下其对水溶液中五氯酚的吸附催化去除作用。讨论H 2O2及五氯酚的初始浓度、血红蛋白固定量以及pH等对五氯酚去除率的影响。结果表明,当溶液的pH为7 H2O2浓度为8.5×10-4 mol/L、血红蛋白固定量为6.6×10-6 mol/L、反应温度为25℃,反应时间为280 min时,五氯酚去除率可达到81.8%,且固定化血红蛋白可被反复使用多次。

关键词: 五氯酚, 血红蛋白, 固定化, 海藻酸钙

Abstract:

Activated carbon and hemoglobin are immobilized in calcium alginate capsules. In the presence ofhydrogen peroxide (H2O2),the removal of aqueous pentachlorophenol (PCP) by the adsorption catalysis of hemoglobin has been studied. The effects of the initial concentrations of H2O2and pentachlorophenol,the dosage ofhemoglobin immobilized and pH on the removal rate of pentachlorophenol from water are discussed. The results showthat the removal rate of PCP can reach 81.8%,when the solution pH is 7,H2O2 concentration 8.5×10-4 mol/L,thedosage of immobilized hemoglobin 6.6×10-6mol/L,reaction temperature 25 ℃ and reaction time 280 min. The immobilizedhemoglobin could be used repeatedly for many times.

Key words: pentachlorophenol, hemoglobin, immobilization, calcium alginate

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