水中硼的去除方法研究进展

doi:10.11894/1005-829x.2012.32(3).14

摘要/Abstract

摘要：

硼广泛应用于现代工业的各个领域,随之而来的含硼废水也开始引起人们的关注。苦咸水和海水由于硼含量较高,作为饮用水或灌溉水之前必须进行除硼处理。水中硼的去除方法逐渐成为人们关注和研究的热点之一。概述了硼的相关环境标准及水中硼的去除方法,分析了各种方法的优缺点,探讨了除硼方法的发展趋势。

关键词: 除硼, 选择性离子交换树脂, 反渗透, 吸附, 电混凝

Abstract:

Boron has been widely used in every field of modern industries.Therefore,the boron-containing wastewater has caught more attention than ever before.Because of the high content of boron in brackish water and sea water,it is necessary to remove boron from brackish water and sea water before being used as drinking or irrigation water.Now,boron removal from water has gradually become one of the research hotspots and focus of attention.The environment standard relating to boron and the methods for removing boron from water are introduced briefly.The advantages and disadvantages of various methods are analyzed,and the development trends of boron removal are investigated.

Key words: boron removal, selective ion-exchange resin, reverse osmosis, adsorption, electro-coagulations

中图分类号:

X703

侯若昕, 顾平, 韦晓竹, 张光辉. 水中硼的去除方法研究进展[J]. 工业水处理, 2012, 32(3): 14-18.

Hou Ruoxin, Gu Ping, Wei Xiaozhu, Zhang Guanghui. Study on the removal of boron from water[J]. INDUSTRIAL WATER TREATMENT, 2012, 32(3): 14-18.

https://www.iwt.cn/CN/Y2012/V32/I3/14

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［21］ Koseoglu H，Kabay N，Yuksel M，et al. Boron removal from seawater using high rejection SWRO membranes：Impact of pH，feed concentration，pressure，and cross-flow velocity［J］. Desalination，2008，227（1/2/3）：253-263.

［22］ Oo M H，Song L F. Effect of pH and ionic strength on boron removal by RO membranes［J］. Desalination，2009，246（1/2/3）：605-612.

［23］ Hyung H，Kim J H. A mechanistic study on boron rejection by sea water reverse osmosis membranes［J］. Journal of Membrane Sci-ence，2006，286（1/2）：269-278.

［24］ Yilmaz A E，Boncukcuoglu R，Kocakerim M M. A quantitative comparison between electrocoagulation and chemical coagulation for boron removal from boron-containing solution［J］. Journal of Hazardous Materials，2007，149（2）：475-481.

［25］ Yilmaz A E，Boncukcuoglu R，Kocakerim M M，et al. Boron removal from geothermal waters by electrocoagulation［J］. Journal of Hazardous Materials，2008，153（1/2）：146-151.

［26］ Jiang J Q，Xu Y，Simon J，et al. Removal of boron （B） from wasteliquors［J］. Water Science and Technology，2006，53（11）：73-79.

［27］ Bektas N，Oncel S，Akbulut H Y，et al. Removal of boron by electrocoagulation［J］. Environmental Chemistry Letters，2004，2（2）：51-54.

［28］ Vasudevan S，Sheela S M，Lakshmi J，et al. Optimization of the process parameters for the removal of boron from drinking water by electrocoagulation：A clean technology［J］. Journal of ChemicalTechnology and Biotechnology，2010，85（7）：926-933.

［29］ Kluczka J，Trojanowska J，Zolotajkin M，et al. Boron removal from wastewater using adsorbents［J］. Environmental Technology，2007，

28（1）：105-113.

［30］ Kluczka J，Ciba J，Trojanowska J，et al. Removal of boron dissolved in water［J］. Environmental Progress，2007，26（1）：71-77.

［31］ Celik Z C，Can B Z，Kocakerim M M. Boron removal from aqueous solutions by activated carbon impregnated with salicylic acid［J］. Journal of Hazardous Materials，2008，152 （1）： 415-422.

［32］闫春燕，伊文涛，邓小川，等. 活性炭对海水中硼的吸附研究［J］. 无机盐工业，2007， 39（3）：34-36.

［33］ Bouguerra W，Mnif A，Hamrouni B，et al. Boron removal by adsorption onto activated alumina and by reverse osmosis［J］. Desalina-tion，2008，223（1/2/3）：31-37.

［34］王路明. Mg（OH）2对海水中硼的吸附效果［J］. 海湖盐与化工，2003，32（5）：5-7.

［35］ Ferreira O P，Moreas S G，Duran N，et al. Evaluation of boron removal from water by hydrotalcite-like compounds［J］. Chemo-sphere，2006，62（1）：80-88.

［36］ Jiang Jiaqian，Xu Yonglan，Quill K，et al. Laboratory study of boron removal by Mg/Al double-layered hydroxides［J］. Industrial and

Engineering Chemistry Research，2007，46（13）：4577-4583.

［37］ Cengeloglu Y，Tor A， Arslan G，et al. Removal of boron from aqueous solution by using neutralized red mud［J］. Journal of Hazardous Materials，2007，142（1/2）：412-417.

［38］ Yuksel S，Yurum Y. Removal of Boron from aqueous solutions by adsorption using fly ash，zeolite，and demineralized lignite［J］. Separation Science and Technology，2010，45（1）： 105-115.

［39］ Chong M F，Lee K P，Chieng H J，et al. Removal of boron from ceramic industry wastewater by adsorption-flocculation mechanism using palm oil mill boiler （POMB） bottom ash and polymer［J］. Water Research，2009，43（13）：3326-3334.

［40］ Kabay N，Yilmaz I，Bryjak M，et al. Removal of boron from aqueous solutions by a hybrid ion exchange-membrane process［J］. Desali-nation，2006，198（1/2/3）：158-165.

［41］ Wolska J，Bryjak M，Kabay N. Polymeric microspheres with N-methyl-D-glucamine ligands for boron removal from water solution by adsorption?鄄membrane filtration process［J］. Environmental Geochemistry and Health，2010，32（4）：349-352.

［42］ Bryjak M，Wolska J，Soroko I，et al. Adsorption-membrane filtration process in boron removal from first stage seawater RO permeate［J］. Desalination，2009，241（1/2/3）：127-132.

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