工业水处理 ›› 2015, Vol. 35 ›› Issue (9): 76-78. doi: 10.11894/1005-829x.2014.35(9).076

• 油气田水处理 • 上一篇    下一篇

复合混凝剂-催化氧化处理采油污水的研究

刘伟1, 刘素伊2, 王佳楠1, 李国东1, 王素芳3   

  1. 1. 南开大学滨海学院环境科学与工程系, 天津 300270;
    2. 国网冀北电力有限公司经济技术研究院, 北京 100055;
    3. 中海油天津化工研究设计院, 天津 300131
  • 收稿日期:2015-07-20 出版日期:2015-09-20 发布日期:2015-09-23
  • 通讯作者: 李国东,博士,副教授。E-mail:gd_liww@126.com。 E-mail:gd_liww@126.com
  • 作者简介:刘伟(1981-),博士,副教授。E-mail:123beauty@163.com。
  • 基金资助:

    天津市科技兴海专项(KJKX2012-07)

Research on the treatment of wastewater from oil production by composite coagulant and catalytic oxidation

Liu Wei1, Liu Suyi2, Wang Jia'nan1, Li Guodong1, Wang Sufang3   

  1. 1. Department of Environmental Science and Engineering, Nankai University Binhai College, Tianjin 300270, China;
    2. State Grid Jibei Electric Power Co., Ltd. Economic & Technical Research Institute, Beijing 100055, China;
    3. CNOOC Tianjin Chemical Research & Design Institute, Tianjin 300131, China
  • Received:2015-07-20 Online:2015-09-20 Published:2015-09-23

摘要:

针对采油污水高COD、高油质量浓度的情况,采用粉煤灰、烟道灰及硫酸铝以不同物质的量比配成复合混凝剂,联合Fenton氧化对其进行处理。考察了复合混凝剂的物质的量比、pH、混凝剂的投药量和反应时间等因素对处理效果的影响。试验结果表明:当复合混凝剂的最佳物质的量比为2:2:1,pH为6.8,投药量为60g/L,Fenton氧化反应时间为35 min时,COD去除率达98.7%、除油率达到97.0%。

关键词: 采油污水, 复合混凝剂, Fenton

Abstract:

Aiming at the high COD and high oil content of the wastewater from oil production,fly ash,flue dust,and aluminum sulfate with different mass flow ratios have been used for preparing composite coagulants. The wastewater has been treated with the coagulants by combining with Fenton oxidation. The influential factors, such as mass flow ratio,pH,coagulant dosage,reaction time,etc. On treatment effects are investigated. The experimental results show that when the optimal mass flow ratio of composite coagulants are 2:2:1,pH is 6.8,coagulant dosage 60 g/L and Fenton oxidation reaction time 35 min,COD removing rate reaches 98.7%,and oil removing rate reaches 97.0%.

Key words: wastewater from oil production, composite coagulant, Fenton

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