工业水处理 ›› 2015, Vol. 35 ›› Issue (3): 34-36. doi: 10.11894/1005-829x.2015.35(3).034

• 试验研究 • 上一篇    下一篇

高梯度磁化控制纳滤膜无机垢污染的研究

陈秋1, 冯玉芳2, 董冰洁3   

  1. 1. 国网河北省电力公司电力科学研究院, 河北石家庄 050021;
    2. 河北青年管理干部学院, 石家庄 050031;
    3. 天津工业大学环境与化学工程学院, 天津 300387
  • 收稿日期:2014-11-16 出版日期:2015-03-20 发布日期:2015-03-23
  • 作者简介:陈秋(1975-),高工。电话:13930149938,E-mail:fengyufang74@163.com。
  • 基金资助:

    国家自然科学基金项目(5130839)

Research on inorganic scale pollution control of nano-filtration membrane using high gradient magnetizing pretreatment

Chen Qiu1, Feng Yufang2, Dong Bingjie3   

  1. 1. State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, China;
    2. Hebei Youth Cadres Administrative College, Shijiazhuang 050031, China;
    3. School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China
  • Received:2014-11-16 Online:2015-03-20 Published:2015-03-23

摘要:

实验对比分析了有无磁化预处理条件下纳滤膜的无机垢污染情况。研究结果发现,磁化预处理能够有效减缓膜比通量的衰减,低压冲洗后膜比通量恢复率可高达90%,而无磁化预处理的纳滤膜通量恢复率仅为68%。SEM分析发现,加上磁化预处理后,纳滤膜表面生成的CaCO3垢不再是致密的方解石,而是质地松软、易脱落的文石结构,这更有利于维持纳滤膜的稳定运行。

关键词: 高梯度磁场, 无机钙垢, 膜污染, 纳滤

Abstract:

The situation of inorganic scale pollution of nano-filtration(NF) membrane by or not by magnetizing pretreatment has been contrasted and analyzed. It is found that magnetizing pretreatment can effectively retard the decline of membrane specific flux. After rinsed under low pressure, the membrane specific flux recovering rate can be as high as 90%. But the flux recovering rate of nano-filtration membrane that has not been pretreated by magnetization process is only 68%. According to SEM analysis, after being pretreated by magnetization process, the CaCO3 scale formed on the surface of nano-filtration membrane is soft and caduceus aragonite, instead of dense calcite. The fact is more advantageous for the nano-filtration membrane to keep stable operation.

Key words: high gradient magnetic field, inorganic calcium scale, membrane pollution, nano-filtration membrane

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