工业水处理 ›› 2015, Vol. 35 ›› Issue (4): 50-52. doi: 10.11894/1005-829x.2015.35(4).050

• 试验研究 • 上一篇    下一篇

活性炭掺杂WO3/ZnO复合薄膜制备及其光催化性能研究

亓新华1, 杨胜凯1, 王玉洁1, 王九霞1, 李超英2   

  1. 1. 河南科技学院化工系, 河南新乡 453003;
    2. 新乡医学院教务处, 河南新乡 453003
  • 收稿日期:2015-03-02 出版日期:2015-04-20 发布日期:2015-04-21
  • 作者简介:亓新华(1967-),硕士,副教授。电话:13937342796,E-mail:qixinhua123456@163.com。
  • 基金资助:

    河南省教育厅科技攻关项目(08B430007)

Study on the preparation of WO3/ZnO composite films doped with activated carbon and its photocatalysis

Qi Xinhua1, Yang Shengkai1, Wang Yujie1, Wang Jiuxia1, Li Chaoying2   

  1. 1. Department of Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China;
    2. Department of Teaching Administration, Xinxiang Medical College, Xinxiang 453003, China
  • Received:2015-03-02 Online:2015-04-20 Published:2015-04-21

摘要:

采用溶胶-凝胶法在铝箔上制备WO3/ZnO复合薄膜,并用活性炭对其改性,以甲基橙水溶液模拟有机污染物,研究了WO3/ZnO薄膜的光催化降解性能。实验结果表明:白炽灯照射2 h、WO3质量分数为2.5%时,WO3/ZnO/铝箔对甲基橙的降解率达到78.54%;紫外光照射下降解率达到99.89%。当活性炭掺杂量为10 g/L时,制得的WO3/ZnO复合薄膜均匀一致且光催化性能良好,可见光照射下甲基橙降解率达到85.71%。

关键词: 溶胶-凝胶法, WO3/ZnO薄膜, 活性炭, 光催化降解

Abstract:

WO3/ZnO composite films have been prepared on aluminum foil by sol-gel method,and its modification has been carried out with activated carbon. Taking methyl orange aqueous as simulated organic pollutant,photoca-talytic degradation performance of WO3-ZnO films is studied. The results show that the degradation rate of methyl orange by using WO3/ZnO on Al foil can reach 78.54%,when illuminated for 2 h and WO3 mass fraction is 2.5%. Under the illumination of UV light,the degradation rate is as high as 99.89%. When the doping amount of activated carbon is 10 g/L,the obtained WO3/ZnO composite films are uniform and have good photocatalytic performance. Under visible light,the degradation rate of methyl orange reaches 85.71%.

Key words: sol-gel method, WO3/ZnO thin film, activated carbon, photocatalytic degradation

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