煤化工废水处理工艺技术的研究及应用进展

doi:10.11894/1005-829x.2016.36(3).016

摘要/Abstract

摘要：

对煤化工废水处理技术的研究和应用现状进行了综合评述。首先,分类介绍了煤化工废水的工艺来源及污染特征。继而对废水处理技术进行了系统的分析和讨论,重点包括:针对难降解有机物的预处理技术、新型生物反应器和生物强化技术、用于深度处理的化学处理技术和膜处理技术。之后,对某煤制油高浓废水处理工程案例进行了介绍分析。最后,对技术研究应用热点和发展趋势进行了总结和展望。

关键词: 煤化工废水, 预处理, 生物处理, 深度处理

Abstract:

An integrated review on the research and application progress in the treatment technology of coal chemical industrial wastewater is brought forward. Firstly, the sources and pollution characteristics of coal-chemical industrial wastewater process are introduced. Then, corresponding wastewater treatment technologies are analyzed systematically, mainly including the pretreatment technology for degradation of persistent organic, novel biological reactor and bioaugmentation technology, chemical treatment and membrane treatment technologies used for advanced treatment. Then, the case study on a treatment project of highly concentrated coal-to-oil wastewater is introduced and analyzed. At the end, the hotspot of technical research and application and developing trends of the treatment technology is summarized and predicted.

Key words: coal-chemical industrial wastewater, pretreatment, biological treatment, advanced treatment

中图分类号:

X703.1

姚硕, 刘杰, 孔祥西, 孙惠, 刘志刚. 煤化工废水处理工艺技术的研究及应用进展[J]. 工业水处理, 2016, 36(3): 16-21.

Yao Shuo, Liu Jie, Kong Xiangxi, Sun Hui, Liu Zhigang. Progress in the application of the treatment technology of coal-chemical industrial wastewater[J]. INDUSTRIAL WATER TREATMENT, 2016, 36(3): 16-21.

https://www.iwt.cn/CN/Y2016/V36/I3/16

参考文献

[1] 吴高明. 焦化废水(液)物化处理技术研究[D]. 武汉:华中科技大学,2006.
[2] 刘相伟. 工业含酚废水处理技术的现状与进展[J]. 工业水处理,1998,18(2):4-7.
[3] 郭树才,胡浩权. 煤化工工艺学[M]. 3版. 北京:化学工业出版社,2012:351.
[4] 武晓毅. 焦化废水预处理技术的应用与展望[J]. 科技情报开发与经济,2005,15(13):139-141.
[5] 蔡昌卫. 焦化废水的预处理[J]. 冶金丛刊,2002(3):44-45.
[6] Cheng Hefa,Xu Weipu,Liu Junliang,et al. Pretreatment of waste-water from triazine manufacturing by coagulation,electrolysis,and internal microelectrolysis[J].Journal of Hazardous Materials,2007, 146(1/2):385-392.
[7] 张键,季俊杰,徐乃东,等. 铁炭流化床预处理染料废水研究[J].中国给水排水,2001,17(8):6-9.
[8] 秦树林,高亮. 多元氧化微电解填料及其制备方法:中国, 201110151328. X[P]. 2011-06-08.
[9] 宁平. 超声辐照-活性污泥联合处理焦化废水[J].环境科学, 2003,24(3):65-69.
[10] 谢成,晏波,韦朝海,等. 焦化废水Fenton氧化预处理过程中主要有机污染物的去除[J]. 环境科学学报,2007,27(7):1101-1106.
[11] Navalon S,Alvaro M,Garcia H. Heterogeneous Fenton catalysts based on clays,silicas and zeolites[J].Applied Catalysis B:Environ-mental,2010,99(1/2):1-26.
[12] 范树军,张焕彬,付建军. 铁炭微电解/Fenton氧化预处理高浓度煤化工废水的研究[J]. 工业水处理,2010,30(8):93-95.
[13] Liu Wenwu,Tu Xueyan,Wang Xiuping,et al. Pretreatment of coking wastewater by acid out,micro-electrolysis process with in situ elec-trochemical peroxidation reaction[J]. Chemical Engineering Journal,2012,200/201/202:720-728.
[14] Li Huiqiang,Han Hongjun,Du Maoan,et al. Removal of phenols, thiocyanate and ammonium from coal gasification wastewater using moving bed biofilm reactor[J].Bioresource Technology,2011,102(7):4667-4673.
[15] Shi Xiaolei,Hu Xiaobing,Wang Zhi,et al. Effect of reflux ratio on COD and nitrogen removals from coke plant wastewaters[J].Water Science and Technology,2010,61(12):3017-3025.
[16] 魏谷. IC/MBBR工艺处理高COD、高氨氮煤化工废水[J]. 中国给水排水,2012,28(20):121-128.
[17] Lu Yong,Yan Lianhe,Wang Ying,et al. Biodegradation of phenolic compounds from coking wastewater by immobilized white rot fungus Phanerochaete chrysosporium[J]. Journal of Hazardous Materials,2009,165(1/2/3):1091-1097.
[18] Bai Yaohui,Sun Qinghua,Zhao Cui,et al. Simultaneous biodegradation of pyridine and quinoline by two mixed bacterial strains[J]. Applied Microbiology and Biotechnology,2009,82(5):963-973.
[19] Zhu Xiaobiao,Tian Jinping,Chen Lujun. Phenol degradation by isolated bacterial strains:kinetics study and application in coking wastewater treatment[J].Journal of Chemical Technology and Biotechnology,2012,87(1):123-129.
[20] Wang Jianlong,Quan Xiangchun,Han Liping,et al. Microbial degradation of quinoline by immobilized cells of Burkholderia pickettii[J].Water Research,2002,36(9):2288-2296.
[21] Bai Yaohui,Sun Qinghua,Sun Renhua,et al. Bioaugmentation and adsorption treatment of coking wastewater containing pyridine and quinoline using zeolite-biological aerated filters[J]. Environmental Science & Technology,2011,45(5):1940-1948.
[22] Bai Yaohui,Sun Qinghua,Zhao Cui,et al. Bioaugmentation treatment for coking wastewater containing pyridine and quinoline in a sequencing batch reactor[J].Applied Microbiology and Biotechnology,2010,87(5):1943-1951.
[23] Wang Jianlong,Quan Xiangchun,Wu Libo,et al. Bioaugmentation as a tool to enhance the removal of refractory compound in coke plant wastewater[J]. Process Biochemistry,2002,38(5):777-781.
[24] Fang Fang,Han Hongjun,Zhao Qian,et al. Bioaugmentation of biological contact oxidation reactor(BCOR) with phenol-degrading bacteria for coal gasification wastewater(CGW) treatment[J]. Bioresource Technology,2013,150:314-320.
[25] Park D,Lee D S,Kim Y M,et al. Bioaugmentation of cyanide-de-grading microorganisms in a full-scale cokes wastewater treatment facility[J]. Bioresource Technology,2008,99(6):2092-2096.
[26] Lai Peng,Zhao Huazhang,Wang Chao,et al. Advanced treatment of coking wastewater by coagulation and zerovalent iron processes[J].Journal of Hazardous Materials,2007,147(1/2):232-239.
[27] Zhu Xiuping,Ni Jinren,Lai Peng. Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation us-ing boron-doped diamond electrodes[J]. Water Research,2009,43(17):4347-4355.
[28] 闻晓今,周正,魏钢,等. 超滤-纳滤对焦化废水深度处理的试验研究[J]. 水处理技术,2010,36(3):93-95.
[29] Jin Xuewen,Li Enchao,Lu Shuguang,et al. Coking wastewater treatment for industrial reuse purpose:Combining biological processes with ultrafiltration,nanofiltration and reverse osmosis[J]. Journal of Environmental Sciences,2013,25(8):1565-1574.

选择文件类型/文献管理软件名称

选择包含的内容