石墨烯气凝胶复合材料制备及吸附性能的研究进展

doi:10.11894/iwt.2018-1098

工业水处理 ›› 2019, Vol. 39 ›› Issue (6): 1-6, 12. doi: 10.11894/iwt.2018-1098

• 专论与综述 • 下一篇

石墨烯气凝胶复合材料制备及吸附性能的研究进展

钟铠¹(),张弛¹,仲亚^1,^2,^3,*(),崔升^1,²,沈晓冬^1,²

1. 南京工业大学材料科学与工程学院, 江苏南京 210009
2. 宿迁市南京工业大学新材料研究院, 江苏宿迁 223800
3. 宿迁安吉奥科技有限公司, 江苏宿迁 223800

收稿日期:2019-02-13 出版日期:2019-06-20 发布日期:2019-08-07
通讯作者: 仲亚 E-mail:936950406@qq.com;yzhong@njtech.edu.cn
作者简介:钟铠(1996-),硕士。E-mail:936950406@qq.com
基金资助:
国家青年科学基金项目(51702156);江苏省自然科学基金-青年基金项目(BK20161002);江苏省科技型创业企业孵育计划项目(BC2016036);江苏省第十五批“六大人才高峰”创新人才团队项目(XCL-231);江苏省大学生创新创业训练计划项目(201810291019Z)

Research progress in the preparation and adsorption capability of graphene aerogel composite materials

Kai Zhong¹(),Chi Zhang¹,Ya Zhong^1,^2,^3,*(),Sheng Cui^1,²,Xiaodong Shen^1,²

1. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
2. Suqian Advanced Materials Institute, Nanjing Tech University, Suqian 223800, China
3. Suqian Anjiao Technology Co., Ltd., Suqian 223800, China

Received:2019-02-13 Online:2019-06-20 Published:2019-08-07
Contact: Ya Zhong E-mail:936950406@qq.com;yzhong@njtech.edu.cn
Supported by:
国家青年科学基金项目(51702156);江苏省自然科学基金-青年基金项目(BK20161002);江苏省科技型创业企业孵育计划项目(BC2016036);江苏省第十五批“六大人才高峰”创新人才团队项目(XCL-231);江苏省大学生创新创业训练计划项目(201810291019Z)

摘要/Abstract

摘要：

石墨烯气凝胶（GA）拥有以石墨烯为主体的多孔互联三维海绵状网络结构。作为一种新兴的纳米多孔材料，因其具有高疏水性、高比表面积、高孔隙率以及良好的化学稳定性，在吸附领域具有巨大的应用前景。结合相关研究，重点介绍了石墨烯、纤维素/石墨烯、碳纳米管/石墨烯、氮掺杂/石墨烯、金属氧化物/石墨烯等几种体系的气凝胶材料的制备方法，并对其吸附性能的研究进展进行了阐述。

关键词: 石墨烯, 气凝胶, 三维网络结构, 吸附性能

Abstract:

Graphene aerogel(GA) is a kind of porous interconnected three-dimensional spongy network structure dominated by graphene. As an emerging nanoporous material, it has high hydrophobicity, high specific surface area, high porosity and good chemical stability, enabling it to have great application prospects in the field of adsorption. Combined with relevant researches, the preparation methods of aerogel materials of several systems, such as graphene, cellulose/graphene, carbon nanotube/graphene, nitrogen-doped/graphene, metal oxide/graphene, etc. are introduced emphatically, and the research progress in their adsorption capability expounded.

Key words: graphene, aerogel, three-dimensional network structure, adsorption capability

中图分类号:

TB34
X703

钟铠,张弛,仲亚,崔升,沈晓冬. 石墨烯气凝胶复合材料制备及吸附性能的研究进展[J]. 工业水处理, 2019, 39(6): 1-6, 12.

Kai Zhong,Chi Zhang,Ya Zhong,Sheng Cui,Xiaodong Shen. Research progress in the preparation and adsorption capability of graphene aerogel composite materials[J]. Industrial Water Treatment, 2019, 39(6): 1-6, 12.

https://www.iwt.cn/CN/Y2019/V39/I6/1

图/表 1

参考文献 50

1	Chae H K , Siberiopérez D Y , Kim J , et al. A route to high surface area, porosity and inclusion of large molecules in crystals[J]. Nature, 2004, 427 (6974): 523- 527. doi: 10.1038/nature02311
2	Eda G , Chhowalla M . Graphene-based composite thin films for electronics[J]. Nano Letters, 2009, 9 (2): 814- 818. doi: 10.1021/nl8035367
3	Wang Xuan , Zhi Linjie , Müllen K . Transparent, conductive graphene electrodes for dye-sensitized solar cells[J]. Nano Letters, 2008, 8 (1): 323- 327. doi: 10.1021/nl072838r
4	Schedin F , Geim A K , Morozov S V , et al. Detection of individual gas molecules adsorbed on graphene[J]. Nature Materials, 2007, 6 (9): 652- 655. doi: 10.1038/nmat1967
5	Sutter P W , Flege J I , Sutter E A . Epitaxial graphene on ruthenium[J]. Nature Materials, 2008, 7 (5): 406- 411. doi: 10.1038/nmat2166
6	Zaman I , Kuan H C , Dai J , et al. From carbon nanotubes and silicate layers to graphene platelets for polymer nanocomposites[J]. Nanoscale, 2012, 4 (15): 4578- 4586. doi: 10.1039/c2nr30837a
7	Chen Wufeng , Li Sirong , Chen Chunhua , et al. Self-assembly and embedding of nanoparticles by in situ reduced graphene for preparation of a 3D graphene/nanoparticle aerogel[J]. Advanced Materials, 2011, 23 (47): 5679- 5683. doi: 10.1002/adma.v23.47
8	Nardecchia S , Carriazo D , Ferrer M L , et al. Three dimensional macroporous architectures and aerogels built of carbon nanotubes and/or graphene:Synthesis and applications[J]. Chemical Society Reviews, 2013, 44 (21): 794- 830. URL
9	Fricke J . Aerogels and their applications[J]. Journal of Non-Crystalline Solids, 1992, 147/148:356- 362. doi: 10.1016/S0022-3093(05)80644-1
10	Gross J , Fricke J , Hrubesh L W . Sound propagation in SiO₂ aerogels[J]. Journal of the Acoustical Society of America, 1992, 91 (4): 2004- 2006. doi: 10.1121/1.403684
11	Vinod S , Tiwary C S , Autreto P A D S , et al. Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers[J]. Nature Communications, 2014, 5:4541. doi: 10.1038/ncomms5541
12	Bai Hua , Li Chun , Wang Xiaolin , et al. On the gelation of graphene oxide[J]. Journal of Physical Chemistry C, 2011, 115 (13): 5545- 5551. doi: 10.1021/jp1120299
13	Wu Zhongshuai , Zhou Guangmin , Yin Lichang , et al. Graphene/metal oxide composite electrode materials for energy storage[J]. Nano Energy, 2012, 1 (1): 107- 131. doi: 10.1016/j.nanoen.2011.11.001
14	Xiao Jianliang , Lv Weiyang , Song Yihu , et al. Graphene/nanofiber aerogels:Performance regulation towards multiple applications in dye adsorption and oil/water separation[J]. Chemical Engineering Journal, 2018, 338:202- 210. doi: 10.1016/j.cej.2017.12.156
15	Wang Chunchun , Yang Sudong , Ma Qing , et al. Preparation of carbon nanotubes/graphene hybrid aerogel and its application for the adsorption of organic compounds[J]. Carbon, 2017, 118:765- 771. doi: 10.1016/j.carbon.2017.04.001
16	Cao Jianyu , Song Lingzheng , Tang Jiali , et al. Enhanced activity of Pd nanoparticles supported on Vulcan XC72R carbon pretreated via a modified Hummers method for formic acid electrooxidation[J]. Applied Surface Science, 2013, 274 (2): 138- 143. URL
17	Xu Yuxi , Sheng Kaixuan , Li Chun , et al. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]. ACS Nano, 2010, 4 (7): 4324- 4330. doi: 10.1021/nn101187z
18	Sun Haiyan , Xu Zhen , Gao Chao . Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels[J]. Advanced Materials, 2013, 25 (18): 2554- 2560. doi: 10.1002/adma.201204576
19	Bai Hua , Sheng Kaixuan , Zhang Pengfei , et al. Graphene oxide/conducting polymer composite hydrogels[J]. Journal of Materials Chemistry, 2011, 21 (46): 18653- 18658. doi: 10.1039/c1jm13918e
20	Wang Z , Shen X , Han N M , et al. Ultralow electrical percolation in graphene aerogel/epoxy composites[J]. Chemistry of Materials, 2016, 28 (18): 6731- 6741. doi: 10.1021/acs.chemmater.6b03206
21	Park S , An J , Potts J R , et al. Hydrazine-reduction of graphiteand graphene oxide[J]. Carbon, 2011, 49 (9): 3019- 3023. doi: 10.1016/j.carbon.2011.02.071
22	Zhang Xuetong , Sui Zhuyin , Xu Bin , et al. Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources[J]. Journal of Materials Chemistry, 2011, 21 (18): 6494- 6497. doi: 10.1039/c1jm10239g
23	Worsley M A , Kucheyev S O , Mason H E , et al. Mechanically robust 3D graphene macroassembly with high surface area[J]. Chemical Communications, 2012, 48 (67): 8428- 8430. doi: 10.1039/c2cc33979j
24	Shinkai T , Sugiyama K , Ito K , et al. Nanoporous fabrication of block copolymers via carbon dioxide swelling:Difference between CO₂-swollen and nanoporous block copolymers[J]. Polymer, 2016, 100:19- 27. doi: 10.1016/j.polymer.2016.08.011
25	Ma Xiaomei , Li Yanhong , Wang Wenchao , et al. Temperature-sensitive poly(N-isopropylacrylamide)/graphene oxide nanocomposite hydrogels by in situ polymerization with improved swelling capability and mechanical behavior[J]. European Polymer Journal, 2013, 49 (2): 389- 396. doi: 10.1016/j.eurpolymj.2012.10.034
26	Hu Han , Zhao Zongbin , Wan Wubo , et al. Ultralight and highly compressible graphene aerogels[J]. Advanced Materials, 2013, 25 (15): 2219- 2223. doi: 10.1002/adma.201204530
27	Vickery J L , Patil A J , Mann S . Fabrication of grapheme-polymer nanocomposites with higher-order three-dimensional architectures[J]. Advanced Materials, 2010, 21 (22): 2180- 2184. URL
28	Pandele A M , Ionita M , Crica L , et al. Novel chitosan-poly(vinylalcohol)/graphene oxide biocomposites 3D porous scaffolds[J]. Composites Part B:Engineering, 2017, 126:81- 87. doi: 10.1016/j.compositesb.2017.06.010
29	Chen Zongping , Ren Wencai , Gao Libo , et al. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J]. Nature Materials, 2011, 10 (6): 424- 428. doi: 10.1038/nmat3001
30	Estevinho B N , Martins I , Ratola N , et al. Removal of 2, 4-dichlorophenol and pentachlorophenol from waters by sorption using coal fly ash from a Portuguese thermal power plant[J]. Journal of Hazardous Materials, 2007, 143 (1): 535- 540. URL
31	Zhang Long , Zhang Fan , Yang Xi , et al. Porous 3D graphene-based bulk materials with exceptional high surface area and excellent conductivity for supercapacitors[J]. Scientific Reports, 2013, 3:1408. doi: 10.1038/srep01408
32	Chen Kunfeng , Liu Fei , Song Shuyan , et al. Water crystallization to create ice spacers between graphene oxide sheets for highly electroactive graphene paper[J]. CrysTengComm, 2014, 16 (33): 7771- 7776. doi: 10.1039/C4CE01030B
33	Riaz M A , Hadi P , Abidi I H , et al. Recyclable 3D graphene aerogel with bimodal pore structure for ultrafast and selective oil sorption from water[J]. RSC Advances, 2017, 7 (47): 29722- 29731. doi: 10.1039/C7RA02886E
34	Ren Ruipeng , Li Wei , Lv Yongkang . A robust, superhydrophobic graphene aerogel as a recyclable sorbent for oils and organic solvents at various temperatures[J]. Journal of Colloid Interface Science, 2017, 500:63- 68. doi: 10.1016/j.jcis.2017.01.071
35	Dai Jian , Huang Ting , Tian Suqi , et al. High structure stability and outstanding adsorption performance of graphene oxide aerogel supported by polyvinyl alcohol for waste water treatment[J]. Materials & Design, 2016, 107:187- 197. URL
36	Medeiros E S D , Agnelli J A M , Joseph K , et al. Mechanical properties of phenolic composites reinforced with jute/cotton hybrid fabrics[J]. Polymer Composites, 2005, 26 (1): 1- 11. URL
37	Júnior C Z P , Carvalho L H D , Fonseca V M , et al. Analysis of the tensile strength of polyester/hybrid ramie-cotton fabric composites[J]. Polymer Testing, 2004, 23 (2): 131- 135. doi: 10.1016/S0142-9418(03)00071-0
38	Wei Xiao , Huang Ting , Yang Jinghui , et al. Green synthesis of hybrid graphene oxide/microcrystalline cellulose aerogels and their use as superabsorbents[J]. Journal of Hazardous Materials, 2017, 335:28- 38. doi: 10.1016/j.jhazmat.2017.04.030
39	Mi Haoyang , Jing Xin , Politowicz A L , et al. Highly compressible ultra-light anisotropic cellulose/graphene aerogel fabricated by bidirectional freeze drying for selective oil absorption[J]. Carbon, 2018, 132:199- 209. doi: 10.1016/j.carbon.2018.02.033
40	Adebajo M O , Frost R L , Kloprogge J T , et al. Porous materials for oil spill cleanup:A review of synthesis and absorbing properties[J]. Journal of Porous Materials, 2003, 10 (3): 159- 170. doi: 10.1023/A:1027484117065
41	Wan Wenchao , Zhang Ruiyang , Li Wei , et al. Graphene-carbon nanotube aerogel as an ultra-light, compressible and recyclable highly efficient absorbent for oil and dyes[J]. Environmental Science:Nano, 2016, 3 (1): 107- 113. doi: 10.1039/C5EN00125K
42	Zhan Wenwei , Yu Siruo , Gao Liang , et al. Bioinspired assembly of carbon nanotube into graphene aerogel with "cabbagelike" hierarchical porous structure for highly efficient organic pollutants cleanup[J]. ACS Applied Materials & Interfaces, 2018, 10 (1): 1093- 1103. URL
43	Shu Di , Feng Feng , Han Hongliang , et al. Prominent adsorption performance of amino-functionalized ultra-light graphene aerogel for methyl orange and amaranth[J]. Chemical Engineering Journal, 2017, 324:1- 9. doi: 10.1016/j.cej.2017.04.136
44	Du Yongxu , Liu Libin , Xiang Yu , et al. Enhanced electrochemical capacitance and oil-absorbability of N-doped graphene aerogel by using amino-functionalized silica as template and doping agent[J]. Journal of Power Sources, 2018, 379:240- 248. doi: 10.1016/j.jpowsour.2018.01.047
45	Ren Hongbo , Shi Xianpan , Zhu Jiayi , et al. Facile synthesis of N-doped graphene aerogel and its application for organic solvent adsorption[J]. Journal of Materials Science, 2016, 51 (13): 6419- 6427. doi: 10.1007/s10853-016-9939-y
46	Tran D , Kabiri S , Wang L , et al. Engineered grapheme-nanoparticle aerogel composites for efficient removal of phosphate from water[J]. Journal of Materials Chemistry A, 2015, 3 (13): 6844- 6852. doi: 10.1039/C4TA06308B
47	Wu Tao , Chen Mingxi , Zhang Lei , et al. Three-dimensional graphene-based aerogels prepared by a self-assembly process and its excellent catalytic and absorbing performance[J]. Journal of Materials Chemistry A, 2013, 1 (26): 7612- 7621. doi: 10.1039/c3ta10989e
48	Zhang Y , Yan X , Yan Y , et al. The utilization of a three-dimensional reduced graphene oxide and montmorillonite composite aerogel as a multifunctional agent for wastewater treatment[J]. RSC Advances, 2018, 8:4239- 4248. doi: 10.1039/C7RA13103H
49	Chen Long , Li Yanhui , Du Qiuju , et al. High performance agar/graphene oxide composite aerogel for methylene blue removal[J]. Carbohydrate Polymers, 2017, 155:345- 353. doi: 10.1016/j.carbpol.2016.08.047
50	Yu Ruomeng , Shi Yongzheng , Yang Dongzhi , et al. Graphene oxide/chitosan aerogel microspheres with honeycomb-cobweb and radially oriented microchannel structures for broad-spectrum and rapid adsorption of water contaminants[J]. ACS Applied Materials & Interfaces, 2017, 9 (26): 21809- 21819. URL

[1]	唐朝春, 徐豪佑, 陈钧杰, 冯文涛, 阮以宣, 何兴龙, 刘耀中. MOFs@气凝胶吸附去除水中污染物的研究进展[J]. 工业水处理, 2024, 44(6): 12-21.
[2]	金鑫, 赵清, 丁璠, 毛珊珊, 高芒来. 双子羧酸型甜菜碱改性黏土对染料的吸附性能研究[J]. 工业水处理, 2024, 44(5): 120-131.
[3]	赵文璞, 赵晓东, 季惠明, 马元良, 马生花, 沈铸睿. SiO₂/g-C₃N₄复合材料的3D打印制备及对染料废水的处理性能[J]. 工业水处理, 2024, 44(3): 64-73.
[4]	王宁, 林家一, 李涛, 薛安, 陈璐, 黎阳. 石墨烯基/半导体金属氧化物复合光催化剂制备工艺研究进展[J]. 工业水处理, 2024, 44(2): 63-72.
[5]	同凡珂, 关通, 周双喜, 王维. 磁性多孔氧化石墨烯的制备及其对典型磺胺类药物的吸附去除[J]. 工业水处理, 2024, 44(12): 109-117.
[6]	姚有智, 华飞, 吴康, 叶舟, 张忠亮, 钱程. 石墨烯基复合材料光催化降解废水有机污染物的研究进展[J]. 工业水处理, 2024, 44(11): 1-8.
[7]	杨秀贞, 成双婵, 张浩麟, 周斌, 侯保林. 金属有机框架掺杂氧化石墨烯对水中锑的吸附研究[J]. 工业水处理, 2023, 43(9): 72-83.
[8]	卓佐西, 徐颜军, 刘春红, 祁志福, 董莹, 李宇航, 高强生. 影响活性炭吸附处理高盐有机废水性能的结构性因素探究[J]. 工业水处理, 2023, 43(7): 144-151.
[9]	黄世燕, 娄蒙蒙, 李璟孜, 李方. 抗润湿GO复合膜的制备及其在印染废水膜蒸馏处理中的应用[J]. 工业水处理, 2023, 43(7): 169-176.
[10]	林龙利, 刘国光, 施丽华, 刘斯眉, 刘敬勇. 改进TiO₂光催化降解水体中萘普生的研究[J]. 工业水处理, 2023, 43(4): 85-91.
[11]	陈宝宁, 丁春华, 方岩雄, 刘全兵. Ag₂O/WO₃-SiO₂气凝胶的制备及光催化性能研究[J]. 工业水处理, 2023, 43(2): 136-141.
[12]	牛经纬, 周育智, 苏永东, 龙林丽, 胡翩, 蒋志洋, 陈孝杨. 农业固废生物炭及其改性材料对重金属的吸附研究[J]. 工业水处理, 2023, 43(12): 26-35.
[13]	杨赟, 赵莹鑫, 王玉龙, 杨水金. 镍掺杂MIL-53（Fe）吸附亚甲基蓝性能研究[J]. 工业水处理, 2023, 43(11): 154-160.
[14]	王小平, 龚诚, 赖玲燕, 程俊. 去除水体中PPCPs的4种改性新型吸附材料研究进展[J]. 工业水处理, 2022, 42(9): 23-37.
[15]	祖林鹏, 邓斌, 杨成, 王章鸿, 刘涛泽, 刘庆友. 笋壳渣对阴阳离子染料的吸附特征及机制研究[J]. 工业水处理, 2022, 42(7): 109-117.

选择文件类型/文献管理软件名称

选择包含的内容

石墨烯气凝胶复合材料制备及吸附性能的研究进展

Research progress in the preparation and adsorption capability of graphene aerogel composite materials

RichHTML

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 1

参考文献 50

相关文章 15

编辑推荐

Metrics

本文评价

模态框（Modal）标题

选择文件类型/文献管理软件名称

选择包含的内容

石墨烯气凝胶复合材料制备及吸附性能的研究进展

Research progress in the preparation and adsorption capability of graphene aerogel composite materials

RichHTML

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 1

参考文献 50

相关文章 15

编辑推荐

Metrics

本文评价