高级氧化技术处理苯胺废水应用进展

doi:10.11894/iwt.2020-0641

摘要/Abstract

摘要：

综述了催化湿式氧化法、类Fenton法、过氧化盐法、臭氧催化氧化法、电化学氧化法、光催化氧化法等高级氧化技术在难降解苯胺废水处理中的研究应用进展，具体包括各技术处理的条件、效果和限制工业化应用的原因。研究结果表明，过氧化盐法本身具有氧化性，且反应条件温和；电化学氧化法、光催化氧化法则具有产生氧化基团容易、无运输和储存环节、适用范围宽、离子干扰小（可能还有促进作用）和无二次污染等特点，上述方法在未来苯胺废水处理的工业应用中具有更好的前景。

关键词: 苯胺废水, 高级氧化, 电化学氧化, 光催化氧化

Abstract:

The research and application progress of advanced oxidation technologies such as catalytic wet oxidation, Fenton-like, peroxide salt, ozone catalytic oxidation, electrochemical oxidation and photocatalytic oxidation in the treatment of refractory aniline wastewater were reviewed, detailed contents including treatment condition, effect and the reason of limiting industrial application of each process. It turns out that the peroxide salt method has oxidizability itself and the reaction conditions are mild. The electrochemical oxidation and photocatalytic oxidation have the characteristics of easy generation of oxidizing groups, no transportation and storage need, wide application range, little ion interference(and possibly promoting effect)and no secondary pollution. Thus, the above three method will have a better prospect in the industrial application of aniline wastewater treatment in the future.

Key words: aniline wastewater, advanced oxidation, electrochemical oxidation, photocatalytic oxidation

中图分类号:

X703

张海兵,周亚松,郭绍辉,吕秀荣. 高级氧化技术处理苯胺废水应用进展[J]. 工业水处理, 2021, 41(6): 167-172, 185.

Haibing Zhang,Yasong Zhou,Shaohui Guo,Xiurong Lü. Advances of advanced oxidation process to treat aniline wastewater[J]. Industrial Water Treatment, 2021, 41(6): 167-172, 185.

https://www.iwt.cn/CN/Y2021/V41/I6/167

参考文献 42

1	Sarasa J , Cortes S , Ormad P , et al. Study of the aromatic by-products formed from ozonation of anilines in aqueous solution[J]. Water Research, 2002, 36 (12): 3035- 3044. doi: 10.1016/S0043-1354(02)00003-9
2	Levec J , Pintar A . Catalytic wet-air oxidation processes: A review[J]. Catalysis Today, 2007, 124 (3/4): 172- 184. URL
3	Gomes H T , Machado B F , Ribeiro A , et al. Catalytic properties of carbon materials for wet oxidation of aniline[J]. Journal of Hazardous Materials, 2008, 159 (3/4): 420- 426. URL
4	Morales-Torres S , Silva A M T , Maldonado-Hódar F J , et al. Pt-catalysts supported on activated carbons for catalytic wet air oxidation of aniline: Activity and stability[J]. Applied Catalysis B: Environmental, 2011, 105 (1/2): 86- 94. URL
5	Song Mingguang , Wang Yunsong , Guo Yun , et al. Catalytic wet oxidation of aniline over Ru catalysts supported on a modified TiO₂[J]. Chinese Journal of Catalysis, 2017, 38 (7): 1155- 1165. doi: 10.1016/S1872-2067(17)62848-1
6	李祥, 杨少霞, 祝万鹏, 等. 碳纳米管催化湿式氧化苯酚和苯胺的研究[J]. 环境科学, 2008, 29 (9): 2522- 2527. doi: 10.3321/j.issn:0250-3301.2008.09.023
7	Garcia J , Gomes H T , Serp P , et al. Carbon nanotube supported ruthenium catalysts for the treatment of high strength wastewater with aniline using wet air oxidation[J]. Carbon, 2006, 44 (12): 2384- 2391. doi: 10.1016/j.carbon.2006.05.035
8	Gomes H T , Selvam P , Dapurkar S E . Transition metal(Cu, Cr, and V) modified MCM-41 for the catalytic wet air oxidation of aniline[J]. Microporous and Mesoporous Materials, 2005, 86, 287- 294. doi: 10.1016/j.micromeso.2005.07.022
9	Stüber F , Font J , Fortuny A , et al. Carbon materials and catalytic wet air oxidation of organic pollutants in wastewater[J]. Topics in Catalysis, 2005, 33, 3- 50. doi: 10.1007/s11244-005-2497-1
10	Liu Yucan , Zhang Guangming , Fang Shunyan , et al. Degradation of aniline by heterogeneous Fenton's reaction using a Ni-Fe oxalate complex catalyst[J]. Journal of Environmental Management, 2016, 182, 367- 373. doi: 10.1016/j.jenvman.2016.07.084
11	Anotai J , Su C C , Tsai Y C , et al. Effect of hydrogen peroxide on aniline oxidation by electro-Fenton and fluidized-bed Fenton processes[J]. Journal of Hazardous Materials, 2010, 183 (1/2/3): 888- 893. URL
12	Anotai J , Su C C , Tsai Y C , et al. Comparison of aniline oxidation by electro-Fenton and fluidized-bed Fenton processes[J]. Journal of Environment Engineering, 2011, 137 (5): 363- 370. doi: 10.1061/(ASCE)EE.1943-7870.0000325
13	Zhang Shengxiao , Zhao Xiaoli , Niu Hongyun , et al. Superparamagnetic Fe₃O₄ nanoparticles as catalysts for the catalytic oxidation of phenolic and aniline compounds[J]. Journal of Hazardous Materials, 2009, 167 (1/2/3): 560- 566. URL
14	李业文. 硝基苯类及苯胺类高浓污水处理工程实践[J]. 建筑工程技术与设计, 2018, (32): 1645- 1646.
15	Zhou Guanliang , Zhou Li , Sun Hongqi , et al. Carbon microspheres supported cobalt catalysts for phenol oxidation with peroxymonosulfate[J]. Chemical Engineering Research and Design, 2015, 101, 15- 21. doi: 10.1016/j.cherd.2015.07.009
16	Zhu Junyi , Chen Cheng , Li Yuxin , et al. Rapid degradation of aniline by peroxydisulfate activated with copper-nickel binary oxysulfide[J]. Separation and Purification Technology, 2019, 209, 1007- 1015. doi: 10.1016/j.seppur.2018.09.055
17	Li Li , Huang Jun , Hu Xuebin , et al. Activation of sodium percarbonate by vanadium for the degradation of aniline in water: Mechanism and identification of reactive species[J]. Chemosphere, 2019, 215, 647- 656. doi: 10.1016/j.chemosphere.2018.10.047
18	Buthiyappan A , Abdul Aziz A R , Wan Daud W M A . Recent advances and prospects of catalytic advanced oxidation process in treating textile effluents[J]. Review in Chemical Engineering, 2016, 32 (1): 1- 7. doi: 10.1515/revce-2015-0034
19	Esmaili-Hafshejani J , Nezamzadeh-Ejhieh A . Increased photocatalytic activity of Zn(Ⅱ)/Cu(Ⅱ) oxides and sulfides by coupling and supporting them onto clinoptilolite nanoparticles in the degradation of benzophenone aqueous solution[J]. Journal of Hazardous Materials, 2016, 316, 194- 203. doi: 10.1016/j.jhazmat.2016.05.006
20	Huang Qianqian , Zhang Jiayin , He Zhengyu . Direct fabrication of lamellar self-supporting Co₃O₄/N/C peroxymonosulfate activation catalysts for effective aniline degradation[J]. Chemical Engineering Journal, 2017, 313, 1088- 1098. doi: 10.1016/j.cej.2016.11.002
21	Qin Xin , Fang Shuwen , Zhao Lei , et al. Cobalt super-microparticles anchored on nitrogen-doped graphene for aniline oxidation based on sulfate radicals[J]. Science of the Total Environment, 2017, 601/602, 99- 108. doi: 10.1016/j.scitotenv.2017.05.198
22	Faria P C C , órfao J J M , Pereira M F R . Ozonation of aniline promoted by activated carbon[J]. Chemosphere, 2007, 67, 809- 815. doi: 10.1016/j.chemosphere.2006.10.020
23	Goncalves A , Silvestre-Albero J , Ramos-Fernández E V . Highly dispersed ceria on activated carbon for the catalyzed ozonation of organic pollutants[J]. Applied Catalysis B: Environmental, 2012, 113/114, 308- 317. doi: 10.1016/j.apcatb.2011.11.052
24	Zhang Jing , Wu Yao , Qin Chao . Rapid degradation of aniline in aqueous solution by ozone in the presence of zero-valent zinc[J]. Chemosphere, 2015, 141, 258- 264. doi: 10.1016/j.chemosphere.2015.07.066
25	徐雪璐, 蒋云飞, 金琪, 等. Mn-Ce负载型催化剂催化臭氧氧化苯胺实验研究[J]. 工业水处理, 2019, 39 (3): 54- 58. URL
26	Kasprzyk-Hordern B , Ziólek M , Nawrocki J . Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment[J]. Applied Catalysis B: Environmental, 2003, 46 (4): 639- 669. doi: 10.1016/S0926-3373(03)00326-6
27	Jiao Weizhou , Qiao Jingjuan , Qin Yuejiao , et al. Effects of coexisting substances on aniline degradation with ozone-based advanced oxidation process in high-gravity fields[J]. Chemical Engineering & Processing: Process Intensification, 2019, 138, 36- 40. URL
28	Li Xiaoliang , Shao Dan , Xu Hao , et al. Fabrication of a stable Ti/TiO_xH_y/Sb-SnO₂ anode for aniline degradation in different electrolytes[J]. Chemical Engineering Journal, 2016, 285, 1- 10. doi: 10.1016/j.cej.2015.09.089
29	Li Xiaoliang , Xu Hao , Yan Wei . Electrocatalytic degradation of aniline by Ti/Sb-SnO₂, Ti/Sb-SnO₂/Pb₃O₄ and Ti/Sb-SnO₂/PbO₂ anodes in different electrolytes[J]. Journal of Electroanalytical Chemistry, 2016, 775, 43- 51. doi: 10.1016/j.jelechem.2016.05.033
30	Panizza M , Michaud P A , Cerisola G , et al. Electrochemical treatment of wastewaters containing organic pollutants on boron-doped diamond electrodes[J]. Electrochemistry Communications, 2001, 3 (7): 336- 339. doi: 10.1016/S1388-2481(01)00166-7
31	Karthikeyan S , Viswanathan K , Boopathy R . Three dimensional electro catalytic oxidation of aniline by boron doped mesoporous activated carbon[J]. Journal of Industrial and Engineering Chemistry, 2015, 21, 942- 950. doi: 10.1016/j.jiec.2014.04.036
32	Duan Xiaoyue , Chen Yawen , Liu Xinyue , et al. Synthesis and characterization of nanometal-ordered mesoporous carbon composites as heterogeneous catalysts for electrooxidation of aniline[J]. Electrochimica Acta, 2017, 251, 270- 283. doi: 10.1016/j.electacta.2017.08.118
33	Su C C , Pagaling E D , Peralta G L . Comparison of aniline degradation by Fenton and electro-Fenton reactors using plate and rod electrodes[J]. Environmental Progress & Sustainable Energy, 2013, 32 (4): 1111- 1117. URL
34	Su C C , Pagaling E D , Genandrialine L . Degradation of aniline by plate and rod electrode fered-Fenton reactors: Effects of current density, Fe²⁺, H₂O₂, and aniline concentrations[J]. Environmental Progress & Sustainable Energy, 2014, 33 (2): 410- 418. URL
35	姚迎迎, 唐琪玮, 黄磊. BDD电化学氧化技术对工业废水的处理[J]. 净水技术, 2018, 37 (S1): 119- 123. URL
36	Li Xiaolian , Xu Hao , Yan Wei . Electrochemical oxidation of aniline by a novel Ti/TiOxHy/Sb-SnO₂ electrode[J]. Chinese Journal of Catalysis, 2016, 37 (11): 1860- 1870. doi: 10.1016/S1872-2067(16)62555-X
37	Yu Xiaoying , Barker J R . Hydrogen peroxide photolysis in acidic aqueous solutions containing chloride ions.Ⅱ. Quantum yield of·OH(aq) radicals[J]. Journal of Physical Chemistry A, 2003, 107, 1313- 1324. doi: 10.1021/jp0266648
38	Zabihi-Mobarakeh H , Nezamzadeh-Ejhieh A . Application of supported TiO₂ onto Iranian clinoptilolite nanoparticles in the photodegradation of mixture of aniline and 2, 4-dinitroaniline aqueous solution[J]. Journal of Industrial and Engineering Chemistry, 2015, 26, 315- 321. doi: 10.1016/j.jiec.2014.12.003
39	Szczepanik B , Slomkiewicz P . Photodegradation of aniline in water in the presence of chemically activated halloysite[J]. Applied Clay Science, 2016, 124/125, 31- 38. doi: 10.1016/j.clay.2016.01.045
40	Pirsaheb M , Shahmoradi B , Beikmohammadi M , et al. Photocatalytic degradation of Aniline from aqueous solutions under sunlight illumination using immobilized Cr: ZnO nanoparticles[J]. Scientific Reports, 2017, 7 (1): 1473. doi: 10.1038/s41598-017-01461-5
41	Durán A , Monteagudo J M , San Martín I , et al. Photocatalytic degradation of aniline using an autonomous rotating drum reactor with both solar and UV-C artificial radiation[J]. Journal of Environmental Management, 2018, 210, 122- 130. URL
42	高金龙, 赵文婕, 谷娜. ClO₂氧化-可见光催化联合处理苯胺废水的研究[J]. 工业水处理, 2012, 32 (10): 57- 60. URL

[1]	钟全发, 钟琳, 徐国徽, 金青海, 余瑾, 徐飞, 何頔. 垃圾渗滤液膜浓缩液全量化处理中溶解性有机物分子水平转化特征[J]. 工业水处理, 2025, 45(2): 109-117.
[2]	郑国庆, 黄煜坤, 韩要丛, 薛兴勇, 卢彦越, 蓝丽红, 陈贞南. 锰渣活化过一硫酸盐降解罗丹明B[J]. 工业水处理, 2025, 45(1): 79-86.
[3]	李守彪, 吴亚品, 徐凤麒, 郭宇, 颜薇, 江波. ClO _x ^-产物对电氧化去除COD性能评价及水体毒性影响[J]. 工业水处理, 2024, 44(9): 143-150.
[4]	贾仲琪, 卫金秋, 宿辉, 刘宪斌. 纳米零价铁耦合高级氧化技术处理废水的研究进展[J]. 工业水处理, 2024, 44(7): 9-18.
[5]	傅翔宇, 李亚峰. 三维电极电Fenton处理阿奇霉素制药废水研究[J]. 工业水处理, 2024, 44(6): 158-164.
[6]	张玉红, 张盾超, 宋秀兰, 何娜. 碱激活PMS氧化法协同SBBR深度处理焦化废水研究[J]. 工业水处理, 2024, 44(6): 94-100.
[7]	商伟伟, 杨焱, 沈芸, 赵世荣, 薛罡, 钱雅洁. 高铁酸盐耦合过氧乙酸深度处理水中甲硝唑的特性研究[J]. 工业水处理, 2024, 44(5): 111-119.
[8]	刘臻, 刘浪, 郑鹏, 刘荣, 袁绍春, 李聪, 陈垚. 电化学高级氧化技术再生活性炭研究进展[J]. 工业水处理, 2024, 44(5): 42-51.
[9]	李天羽, 张峰, 杨艳青, 窦哲华, 崔建国. 基于亚硫酸盐活化体系的Cr（Ⅵ）和罗丹明B同步去除[J]. 工业水处理, 2024, 44(2): 157-165.
[10]	李倩, 龚豪, 薛罡, 钱雅洁. 铁刨花活化过一硫酸盐氧化破络Cu-EDTA的特性研究[J]. 工业水处理, 2024, 44(1): 73-79.
[11]	黄俪欣, 曾祥健, 谭杰, 潘湛昌, 胡光辉, 许燕滨, 伍尚权. 电化学法处理养殖场臭气吸收剂及其循环利用的研究[J]. 工业水处理, 2023, 43(9): 126-132.
[12]	徐莹莹, 赵秋雨, 常志淼, 于翔霏. 有机磷阻燃剂水体污染处理技术的研究进展[J]. 工业水处理, 2023, 43(5): 25-33.
[13]	刘佳露, 朱彧, 刘兆煐, 胡苧尹, 肖调兵. PDS/CoFe₂O₄活化体系在四环素废水处理中的应用[J]. 工业水处理, 2023, 43(4): 139-143.
[14]	李明安, 王榕, 罗从伟, 宋阳, 武道吉, 谭凤训, 成小翔. LED-UV₃₆₅/PDS体系降解碘帕醇的效能及机制研究[J]. 工业水处理, 2023, 43(4): 63-70.
[15]	徐啸, 刘杰, YUN Jiayin, 彭伟, 左梅梅, 丁昭霞, 胡家兴. Mn₃O₄-MnOOH复合材料催化过硫酸氢钾降解罗丹明B[J]. 工业水处理, 2023, 43(3): 124-131.

选择文件类型/文献管理软件名称

选择包含的内容