工业水处理 ›› 2007, Vol. 27 ›› Issue (8): 74-76.

• 经验交流 • 上一篇    下一篇

中和—膜过滤法处理酸性含氟废水的改进

傅秋生1, 阎震1, 谭明2   

  1. 1 宝山钢铁股份有限公司特殊钢分公司,上海 200940;
    2 上海金源希弗环境保护设备工程有限公司,上海 200003
  • 收稿日期:2007-03-21 出版日期:2007-08-20 发布日期:2010-10-01
  • 作者简介:傅秋生(1957-),2004年毕业于同济大学法学专业,工程师.电话:021-26032320,E-mail:tiger_fqs@126.com.

Improvement of the treatment of fluoride-bearing acidic wastewater by neutralization-membrane filtration process

Fu Qiusheng1, Yan Zhen1, Tan Ming2   

  1. 1. Special Steel Branch,Baoshan Iron & Steel Co.,Ltd.,Shanghai 200940,China;
    2. Shanghai Golden Sources-SFC EPE.Eng.Co.,Ltd.,Shanghai 200003,China
  • Received:2007-03-21 Online:2007-08-20 Published:2010-10-01

摘要:

采用中和—膜过滤法处理酸性含氟废水时,当中和池的pH在6~9范围时,处理后废水中的氟离子和金属离子不能稳定控制在上海市污水综合排放标准以内。经研究分析发现,提高中和池的pH在10.5时,可提高废水中氟离子及金属离子的去除率。在排放前回调pH,可使废水水质稳定达标排放。

关键词: 中和, 膜过滤, 溶度积, 含氟酸性废水

Abstract:

A neutralization-membrane filtration process has been used to treat the fluoride-bearing acidic wastewater.The result shows that when the pH of the fluid in the neutralizing tank is ranging from 6 to 9,the concentration of the discharged fluoride ions and the metallic ions in the wastewater can not steadily meet the discharge standard of Shanghai.The tests shows that the removal rates of fluoride ions and metallic ions in the wastewater are raised when the pH reaches 10.5 or above in the neutralization tank.Before discharging the wastewater the pH should be readjusted to 7 to assure each pollutant factors to steadily meet the discharge standard.

Key words: neutralization membrane filtration, solubility product, fluoride-containing acidic wastewater

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