工业水处理 ›› 2011, Vol. 31 ›› Issue (11): 57-59,60. doi: 10.11894/1005-829x.2011.31(11).57

• 试验研究 • 上一篇    下一篇

水热辅助Fenton试剂氧化法深度处理显影废水的研究

曾小君, 王和平   

  1. 常熟理工学院化学与材料工程学院, 江苏常熟 21550
  • 收稿日期:2011-07-18 出版日期:2011-11-21 发布日期:2011-11-22
  • 作者简介:曾小君(1968-),1997年毕业于江西师范大学,副教授.电话:13915611719

Study on the advanced treatment of development wastewater by thehydrothermal-assisted Fenton reagent oxidation process

Zeng Xiaojun, Wang Heping   

  1. School of Chemistry and Material Engineering, Changshu Institute of Science & Technology, Changshu 215500, China
  • Received:2011-07-18 Online:2011-11-21 Published:2011-11-22

摘要:

研究了水热辅助Fenton试剂氧化法对中和沉淀-气浮工艺处理后的显影废水的深度处理效果和影响因素。结果表明,在最佳反应条件下,当进水CODCr为300~400 mg/L时,处理出水CODCr<60 mg/L,达到《污水综合排放标准》(GB 8978—1996)一级标准要求。在实验条件下,最佳反应参数为:初始pH为2.5,反应温度为110℃,FeSO4.7H2O投加质量浓度为3.6 g/L,30%H2O2投加质量浓度为3.3~3.7 g/L,反应时间为1~2 h。水热辅助Fenton试剂氧化法的CODCr去除率可达85.2%。

关键词: 显影废水, Fenton试剂, 水热辅助, 氧化法, 深度处理

Abstract:

The advanced treatment efficiency and influencing factors of hydrothermal-assisted Fenton reagent oxidation method on the development wastewater pretreated by neutral precipitation -flotation process have beeninvestigated. The results show that under the optimum condition,i.e. when the influent CODCr is 300-400 mg/L,theeffluent CODCr is less than 60 mg/L,meeting the requirements of the first grade Comprehensive Standard of Wastewater Discharge(GB 8978—1996). Under the experiment conditions,the optimal operating parameters are as follows:initial pH is 2.5,reaction temperature 110 ℃,FeSO4·7H2O dosage 3.6 g/L,30%H2O2 dosage 3.3-3.7 g/L,and reaction time 1 -2 h. The removing rate of CODCr by hydrothermal-assisted Fenton reagent oxidation method reaches 85.2%.

Key words: development wastewater, Fenton reagent, hydrothermal-assisted, oxidation method, advanced treatment

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