Research progress in the combined electro-catalytic oxidation technologies for treating refractory organic wastewater

doi:10.11894/1005-829x.2009.29(6).1

Abstract

Abstract:

Various kinds of combined electro-catalytic oxidation technologies for treating refractory organic wastewater is introduced. The combined electro-catalytic oxidation technologies mainly include photoelectro-catalytic oxidation， ultrasound electro-catalytic oxidation， ozone electro-catalytic oxidation， electro-catalytic-bio-reaction and membrane filtration electro-catalytic oxidation. The properties， advantages and disadvantages of the combined electro- catalytic oxidation technologies are discussed， respectively. The analysis shows that the combined electrocatalytic oxidation technologies used for treating wastewater have synergic effect. Their industrialized will soon be realized in the near future through researches on the electro-catalytic materials and the process technologies.

Key words: electro-catalytic oxidation, refractory organic wastewater, wastewater treatment, current efficiency

摘要：

介绍了难降解有机废水的各种联合电催化氧化处理技术,主要包括:光电催化氧化技术、超声-电催化氧化技术、臭氧电催化氧化技术、电催化-生物反应技术、膜过滤电催化氧化技术。讨论了联合电催化氧化技术各自的特点、优势与不足。分析表明,联合电催化氧化技术在废水处理上具有协同作用。通过电催化材料和工艺技术的研究,有可能实现电催化氧化技术的产业化。

关键词: 电催化氧化, 难降解有机废水, 废水处理, 电流效率

CLC Number:

X703.1

Zhang Tengyun, Fan Hongbo, Liao Shijun1. Research progress in the combined electro-catalytic oxidation technologies for treating refractory organic wastewater[J]. INDUSTRIAL WATER TREATMENT, 2009, 29(6): 1-4.

张腾云, 范洪波, 廖世军. 联合电催化氧化处理难降解有机废水研究进展[J]. 工业水处理, 2009, 29(6): 1-4.

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References

[1] Mohan N， Balasubramanian N， Basha C A. Electrochemical oxidation of textile wastewater and its reuse [J]. Journal of Hazardous Materials， 2007， 147(1/2): 644-651.
[2] Rajkumar D， Palanivelu K. Electrochemical treatment of industrialwastewater[J]. Journal of Hazardous Materials， 2004， 113(1/2/3):123-129.
[3] Suresh K B， James T， Jaidev P， et al. Wet oxidation and catalytic wet oxidation [J]. Industrial ＆ Engineering Chemistry Research，2006， 45(4): 1221-1258.
[4] Zhou Minghua， Wu Zucheng， Ma Xiangjuan， et al. A novel fluidized electrochemical reactor for organic pollutant abatement [J]. Separation and Purification Technology， 2004， 34(1/2/3): 81-88.
[5] Hubert D， Jean N F. Wet air oxidation for the treatment of industrial wastes. Chemical aspects， reactor design and industrial applications in Europe[J]. Waste Manage.， 2000， 20(1): 15-25.
[6] Luck F. Wet air oxidation: Past， present and future[J]. Catalysis Today， 1999， 53(1): 81-91.
[7] Rajeshwar K， Ibanez J G， Swain G M. Electrochemistry and the environment [J]. Journal of Applied Electrochemistry， 1994， 24(11): 1077-1091.
[8] Rajeshwar K， Ibanez J G. Environmental Electrochemistry: Fundamentals and Applications in Pollution Abatement [M]. San Diego，CA: Academic Press， 1997：361-380.
[9] Sanroman M A， Pazos M， Ricart M T， et al. Electrochemical decolourisation of structurally different dyes[J]. Chemosphere， 2004，57(3): 233-239.
[9] 苑宝玲，王洪杰. 水处理新技术原理与应用[M]. 北京：化学工业出版社， 2006：62-63.
[10] 刘亚子，孙成，洪军. TiO²光电催化技术降解有机污染物研究进展[J]. 环境科学与技术， 2006， 29(4): 109-112.
[11] 董秋花，赵中一. 二氧化钛光电催化降解水中有机污染物的研究进展[J]. 安徽化工， 2005(2): 41-43.
[12] 陈佩仪，李彦旭，孙楹煌，等. 光电催化水处理技术研究进展[J]. 工业水处理， 2005， 25(12): 13-17.
[13] 肖俊霞，胡记杰，阎虹，等. 光电催化氧化技术中光电反应器的研究与发展[J]. 化工进展， 2007， 26(3): 331-336.
[14] Mason T J， Lorimer J P， Walton D J. Sonoelectrochemistry [J].Ultrasonics， 1990， 28(5): 333-337.
[15] 李少婷，张青，汤亚飞，等. 电催化氧化处理难降解废水技术研究进展[J]. 四川环境， 2005， 24(5): 83-87.
[16] Walton D J， Burke L D， Murphy M M.Sonoelectrochemistry: chlorine，hydrogen and oxygen evolution at platinised platinum [J].Electrochimica Acta， 1996， 41(17): 2747-2751.
[17] Compton R G， Eklund J C， Marken F， et al . Electrodes process at the surfaces of sonotrodes [J]. Electrochimica Acta， 1996， 41(2): 315-320.
[18] 庄琳懿，马前，宋卫峰，等. 超声辅助电催化氧化降解水杨酸的研究[J]. 四川环境， 2006， 25(5): 4-8.
[19] Kishimoto N， Morita Y， Tsuno H， et al. Advanced oxidation effect of ozonation combined with electrolysis [J]. Water Research，2005， 39(19): 4661-4672.
[20] Kishimoto N， Yasuda Y， Mizutani H， et al. Applicability of ozonation combined with electrolysis to 1，4 -dioxane removalfrom wastewater containing radical scavengers[J]. Ozone: Science＆ Engineering， 2007， 29(1): 13-22.
[21] Kishimoto N， Nakagawa T， Asano M， et al. Ozonation combined with electrolysis of 1，4-dioxane using a two-compartment electrolyticflow cell with solid electrolyte[J]. Water Research， 2008，42(1 ／ 2): 379 - 385.
[22] 冯晓静，谢益民，洪卫. 电化学-固定化微生物技术联合深度处理制浆造纸废水[J]. 中国造纸， 2007， 26(9): 22-25.
[23] Bejankiwar R S， Lokesh K S， HalappaGowda T P. Colour and organic removal of biologically treated coffee curing wastewater by electro-chemical oxidation method [J]. Journal of Environmental Sciences， 2003， 15(3): 323-327.
[242] 王鹏，刘伟藻. 电化学氧化与厌氧技术联用渗沥水[J]．环境化学，2001，22(5)：70-73．
[25] 符德学，缪娟. 电解—UASB—渗滤法处理印染废水[J]. 洛阳大学学报， 2005， 20(2): 37-40.
[26] 曹宏斌，李玉平，徐红彬，等. 电催化还原—生物降解耦合处理硝基苯废水[J]. 环境科学， 2004， 25(增刊): 95-97.
[27] 曹宏斌，李玉平，陈燕丽，等. 电解—生物耦合技术处理酸性红A 染料废水[J]. 过程工程学报， 2003， 3(6): 570-575.
[]李玉平，曹宏斌，张懿. 生物电催化方法处理三氯乙酸的研究[J].环境科学， 2005， 26(4): 55-58.
[28] 徐红，刘德佳，姜梅，等. 电化学氧化—超滤组合工艺在炼油厂水处理中的应用[J]. 石油炼制与化工， 2006， 37(7): 62-66.
[29] 迟娟，黄全辉，李敏哲，等. 内电解—MBR 工艺处理制药废水的研究[J]. 工业水处理， 2006， 26(1): 27-29.
[30] Chen Xuejun， Shen Zhemin， Zhu Xiaolong， et al. Advancedtreatment of textile wastewater for reuse using electrochemicaloxidation and membrane filtration [J]. Water SA， 2005， 31(1):127-132.
[31] García-Gabaldón M， PérezHerranz V， Sánchez E， et al. Effect of porosity on the effective electrical conductivity of different ceramic membranes used as separators in electrochemical reactors [J].Journal of Membrane Science， 2006， 280(1/2): 536-544.
[32] 张梅玲，蔚东升，顾国锋，等. 离子膜电解去除味精废水中氨氮的研究[J]. 膜科学与技术， 2007， 27(2): 61-65.
[33] 康娟，徐泽林，陶阳宇，等. 离子膜电解法降解苯胺硝基苯废水的研究[J]. 环境科学与技术， 2006， 29(12): 20-22.
[34] 徐泽林，康娟，陶阳宇，等. 离子膜电解法预处理聚乙烯醇退浆废水研究[J]. 中国给水排水， 2007， 23(1): 69-76.
[35] Pierna A R， Sistiaga M， Navascués C， et al. Influence of glass diaphragms and anionic membranes in the electrochemical oxidation of aromatic aqueous solutions[J]. Electrochimica Acta， 2000，46(2/3): 315-322.
[36] Khan J， Tripathi B P， Saxena A， et al. Electrochemical membrane reactor：In situ separation and recovery of chromic acid and metal ions[J]. Electrochimica Acta， 2007， 52(24): 6719-6727.
[37] Pribyl M， Chmelíková R， Hasal P， et al. Penicillin G hydrolysis in an electromembrane reactor with immobilized penicillin G acylase [J]. Enzyme and Microbial Technology， 2003， 33(6): 793-801.

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