Research progress in flocculants applied to the treatment of wastewater containing heavy metals

doi:10.11894/1005-829x.2014.34(12).012

Abstract

Abstract:

Flocculation technique,as a kind of important method for wastewater treatment,is characterized by wide application and economic and simple operation. The mechanism and classification of flocculant are outlined. The advantagesand disadvantages,research and application of inorganic,organic,composite and biological flocculants to the treatment of wastewater containing heavy metals are expounded. Meanwhile the prospect and developing trends of flocculants applied to the treatment of wastewater containing heavy metals are looked forward.

Key words: heavy metals, wastewater treatment, flocculants

摘要：

絮凝技术作为废水处理的重要方法,具有应用广泛尧经济简便的特点.概述了絮凝剂的絮凝机理及分类,阐述了无机絮凝剂尧有机絮凝剂尧复合絮凝剂及生物絮凝剂在重金属废水处理中的优缺点尧研究及应用现状,同时展望了絮凝剂用于重金属废水处理的前景及发展趋势.

关键词: 重金属, 废水处理, 絮凝剂

CLC Number:

TQ314.2

Du Fengling, Xu Min, Wang Gang, Chang Qing. Research progress in flocculants applied to the treatment of wastewater containing heavy metals[J]. INDUSTRIAL WATER TREATMENT, 2014, 34(12): 12-16.

杜凤龄, 徐敏, 王刚, 常青. 絮凝剂处理重金属废水的研究进展[J]. 工业水处理, 2014, 34(12): 12-16.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/1005-829x.2014.34(12).012

https://www.iwt.cn/EN/Y2014/V34/I12/12

References

[1] 徐国想,阮复昌.铁系和铝系无机絮凝剂的性能分析[J].重庆环境科学,2001,23(3):52-55.
[2] Fu Fenglian,Chen Runming,Xiong Ya. Application of a novelstrategy:coordination polymerization precipitation to the treatment ofCu²⁺-containing wastewaters[J]. Separation and Purification Techno-logy,2006,52(2):388-393.
[3] Kawaguchi H,Hoshino H,Amagasa H. Modifications of a polymer latex[J]. Journalof Colloidand Interface Science,1984,97(2):465-475.
[4] Kasgöz H,Özgümüs S,Orbay M. Modified Polyacrylamide hydrogelsand their application in removal of heavy metal ions[J]. Polymer,2003,44(6):1785-1793.
[5] Navarro R R,Wada S,Tastumi K. Heavy metal precipitation bypolycation-polyanion complex of PEI and its phosphonomethylatedderivative[J]. Journal of Hazardous Materials,2005,123(1/2/3):203-209.
[6] Chang Qing,An Yu. Preparation of macromolecular heavy metalcoagulant and treatment of wastewater containing copper[J]. WaterEnvironment Research,2007,79(6):587-592.
[7] 王进喜,常青,章敏,等. 高分子重金属絮凝剂MAPEI 的制备及性能研究[J].环境科学学报,2007,27(10):1623-1629.
[8] Wang Fenghe,Ji Yingxue,Wang Junjie. Synthesis of heavy metalchelating agent with four chelating groups of N1,N2,N4,N5-tetrakis(2-mercaptoethyl)benzene-1,2,4,5-tetracarboxamide(TMBTCA)and its application for Cu-containing wastewater [J]. Journal ofHazardous Materials,2012,241-242:427-432.
[9] Wing R E,Swanson C L,Doane W M,et al. Heavy metal removalwith starch xanthate-cationic polymer complex[J]. Journal WaterPollution Control Federation,1974,46(8):2043-2047.
[10] Tare V,Chaudhari S. Evaluation of soluble and insoluble xanthateprocess for the removal of heavy metals from wastewaters[J]. WaterResearch,1987,21(9):1109-1118.
[11] Jawed M,Tare V. Application of starch xanthates for cadmiumremoval:a comparative evaluation[J]. Journal of Applied PolymerScience,1991,42(2):317-324.
[12] Navarro R R,Sumi K,Matsumura M. Improved metal affinity ofchelating adsorbents through graft polymerization[J]. WaterResearch,1999,33(9):2037-2044.
[13] 孙胜玲,王丽,吴瑾,等.壳聚糖及其衍生物对金属离子的吸附研究(上)[J].高分子通报,2005(5):58-68.
[14] Sonmez H B,Senkal B F,Bicak N. Poly(acrylamide)grafts onspherical bead polymers for extremely selective removal of mercuricions fromaqueous solutions[J]. Journal of Polymer Science Part A:Polymer Chemistry,2002,40(17):3068-3078.
[15] 何微娜,相波,李义久.壳聚糖的改性及其在废水处理中的应用[J].净水技术,2007,26(6):62-65.
[16] Chang Qing,Zhang Min,Wang Jinxi. Removal of Cu²⁺ and turbidityfrom wastewater by mercaptoacetyl chitosan[J]. Journal of Hazar-dous Materials,2009,169(1/2/3):621-625.
[17] 刘志远,李昱辰,王鹤立,等.复合絮凝剂的研究进展及应用[J].工业水处理,2011,31(5):5-8.
[18] 邵颖,叶玉汉.聚合铝-壳聚糖复合絮凝剂的絮凝性能及其在重金属废水中的应用[J].宁波大学学报:理工版,2002,15(1):83-85.
[19] 尹大伟,刘玉婷,苗东琳. 复合絮凝剂PAC-CTS 的制备及其絮凝性能研究[J].化工新型材料,2011,39(8):94-95.
[20] Cao Jie,Tan Yebang,Che Yuju,et al. Novel complex gel beadscomposed of hydrolyzed polyacrylamide and chitosan:an effectiveadsorbent for the removal of heavy metal from aqueous solution[J].Bioresource Technology,2010,101(7):2558-2561.
[21] 王亚雄,郭瑾珑,刘瑞霞.微生物吸附剂对重金属的吸附特性[J].环境科学,2001,22(6):72-75.
[22] 国峰,陆斌,黄晓琛.微生物絮凝剂的研究进展与发展趋势[C] 椅第八届全国水处理混凝技术研讨会论文集,2007.
[23] Lian Bin,Chen Ye,Yuan Sheng,et al. Study on the flocculability ofmetal ions by Bacillus mucilaginosus GY03 strain[J]. ChineseJournal of Geochemistry,2004,23(4):380-386.
[24] 姚敏杰,连宾.微生物絮凝剂对高浓度重金属离子废水絮凝作用研究[J].环境科学与技术,2009,32(11):1-4.
[25] 王竞,陶颖,周集体. 细菌胞外高聚物对水中六价铬的生物吸附特性[J].水处理技术,2001,27(3):145-147.
[26] Machado M D,Santos M S F,Gouveia C,et al. Removal of heavymetals using a brewer's yeast strain of Saccharomyces cerevisiae:theflocculationasaseparationprocess[J]. Bioresource Technology,2008,99(7):2107-2115.

Please choose a citation manager

Content to export