Application of dialdehyde modified starch to the treatment of wastewater containing heavy metallic ions

doi:10.11894/1005-829x.2016.36(3).011

Abstract

Abstract:

As a natural high molecular compound, starch has advantages, such as abundant sources, low in price, biodegradable, etc. Modified starch has widely been used for removing heavy metallic ions from wastewater. In order to improve its adsorption capacity, some modified starch with new types of structures is designed and synthesized, among which dialdehyde modified starch is different from traditional ones in structure and characteristics. Based on the introduction of its synthetic method, the types, structures and characteristics of dialdehyde modified starch for removing heavy metallic ions from wastewater are summarized, providing reference for the design of more new modified starch in future.

Key words: dialdehyde modified starch, Schiff base, heavy metal ions, wastewater treatment

摘要：

淀粉作为天然高分子化合物具有来源广泛、价格低廉和可生物降解等优点,改性淀粉被广泛应用于废水中重金属的处理。为了改善其吸附性能,设计并合成了一些新型结构的改性淀粉,其中双醛改性淀粉在结构和特点上与传统的改性淀粉不同。在介绍其合成方法基础上,总结了双醛改性淀粉的种类、结构以及处理废水中重金属的特点,为今后设计更多的新型改性淀粉提供参考。

关键词: 双醛改性淀粉, 希夫碱, 重金属离子, 废水处理

CLC Number:

X703.5

Zhang Xinna, Chen Zhitao, Ji Jin'gou, Mu Xiaojing, Dai Kunyi. Application of dialdehyde modified starch to the treatment of wastewater containing heavy metallic ions[J]. INDUSTRIAL WATER TREATMENT, 2016, 36(3): 11-15.

张新娜, 陈志涛, 季金苟, 穆小静, 代坤义. 双醛改性淀粉在重金属废水处理中的应用[J]. 工业水处理, 2016, 36(3): 11-15.

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URL: https://www.iwt.cn/EN/10.11894/1005-829x.2016.36(3).011

https://www.iwt.cn/EN/Y2016/V36/I3/11

References

[1] 张燕萍. 变性淀粉的制造与应用[M]. 北京:化学工业出版社, 2007:73-151.
[2] Cheng Rumei,Ou Shengju,Li Yijiu,et al. Kinetics and molecular mechanism of chromate uptake by dithiocarbamate functionalized starch[J]. Journal of Applied Polymer Science,2012,124(4):2930-2936.
[3] Li Yijiu,Xiang Bo,Ni Yaming. Removal of Cu(Ⅱ) from aqueous solutions by chelating starch derivatives[J]. Journal of Applied Polymer Science,2004,92(6):3881-3885.
[4] Sancey B,Trunfio G,Charles J,et al. Heavy metal removal from industrial effluents by sorption on cross-linked starch:Chemical study and impact on water toxicity[J]. Journal of Environmental Management,2011,92(3):765-772.
[5] Amal A A. Preparation,characterization and evaluation of anionic starch derivatives as flocculants and for metal removal[J]. Starch-Stärke,2006,58(8):391-400.
[6] Chan Wuchung,Wu Junyi. Dynamic adsorption behaviors between Cu²⁺ ion and water-insoluble amphoteric starch in aquous solutions[J].Journal of Applied Polymer Science,2001,81(12):2849-2855.
[7] Cao Liqin,Xu Shimei,Feng Shun,et al. Adsorption of Zn(Ⅱ) ion onto crosslinked amphoteric starch in aqueous solutions[J]. Journal of Polymer Research,2004,11(2):105-108.
[8] Guo Lei,Liu Junshen,Xing Guoxiu,et al. Adsorption and desorption of Zinc(Ⅱ) on water-insoluble starch phosphates[J]. Journal of Applied Polymer Science,2009,11(2):1110-1114.
[9] Xu Shimei,Feng Shun,Peng Gui,et al. Removal of Pb(Ⅱ) by cross-linked amphoteric starch containing the carboxymethyl group[J]. Carbohydrate Polymers,2005,60(3):301-305.
[10] Baek K,Yang J S,Kwon T S,et al. Cationic starch-enhanced ultra-filtration for Cr(Ⅵ) removal[J]. Desalination,2007,206(1/2/3):245-250.
[11] El-Hamshary H,Fouda M M,Moydeen M,et al. Removal of heavy metal using poly(N-vinylimidazole)-grafted-carboxymethylated starch[J]. International Journal of Biological Macromolecules,2014, 66:289-294.
[12] Salisu A A,Musa H,Abba H,et al. Preparation and characterization of dialdehyde starch and its' cross-linking with copper(Ⅱ) ion[J]. Journal of Chemical and Pharmaceutical Research,2013,5(5):153-158.
[13] Yin Qiangfeng,Ju Benzhi,Zhang Shufen,et al. Preparation and characteristics of novel dialdehyde aminothiazole starch and its adsorption properties for Cu(Ⅱ) ions from aqueous solution[J]. Carbo-hydrate Polymers,2008,72(2):326-333.
[14] Ding Wen,Zhao Ping,Li Rong. Removal of Zn(Ⅱ) ions by dialde-hyde 8-aminoquinoline starch from aqueous solution[J]. Carbohydrate Polymers,2011,83(2):802-807.
[15] Liu Juntao,Dong Zhengping,Ding Wen,et al. Adsorption of Zn(Ⅱ) on dialdehyde m-phenylenediamine starch[J]. Water Science and Technology,2012,66(2):321-327.
[16] Zhao Ping,Jiang Jian,Zhang Fengwei,et al. Adsorption separation of Ni(Ⅱ) ions by dialdehyde o-phenylenediamine starch from aque-ous solution[J]. Carbohydrate Polymers,2010,81(4):751-757.
[17] Kweon D K,Choi J K,Kim E K,et al. Adsorption of divalent metal ions by succinylated and oxidized corn starches[J]. Carbohydrate Polymers,2001,46(2):171-177.
[18] Ding Wen,Zhai Shenyong,Liu Juntao,et al. Preparation and adsorption properties of dialdehyde 8-aminoquinoline starch[J].Water Science and Technology,2013,67(2):306-310.
[19] 游效曾,孟庆金,韩万书. 配位化学进展[M]. 北京:高等教育出版社,2000:16-27.
[20] Liu Juntao,Zhang Kunyu,Wang Peng,et al. Adsorption behavior of Cd(Ⅱ) from aqueous solution using dialdehyde 5-aminophenan-throline starch[J]. Separation Science and Technology,2013,48(5):766-774.
[21] 叶玲,张敬阳. 邻菲罗啉对蒙脱石吸附镍离子性能影响[J]. 环境科学学报,2012,32(6):1381-1387.
[22] Fiedorowicz M,Para A. Structural and molecular properties of dial-dehyde starch[J]. Carbohydrate Polymers,2006,63(3):360-366.
[23] 易先君,具本植,张淑芬. 高羰基含量水溶性氧化淀粉氨基噻唑希夫碱的合成及吸附性能[J]. 精细化工,2013,30(7):766-770.
[24] Awokoya K N,Moronkola B A. 2-amino-4,6-dihydroxylpyrimidine modified corn starches for uptake of Cu(Ⅱ) ions from aqueous me-dia[J]. International Journal of Engineering and Science,2013, 2(5):49-55.
[25] Para A,Karolczyk-Kostuch S,Fiedorowicz M. Dihydrazone of dial-dehyde starch and its metal complexes[J]. Carbohydrate Polymers,2004,56(2):187-193.
[26] Ropek D,Para A. The effect of heavy metal ions and their complex-ions upon growth,sporulation and pathogenicity of the entomopatho-genic fungus Paecilomyces farinosus[J]. Polish Journal of Environmental Studies,2003,12(2):227-230.
[27] Para A,Karolczyk-Kostuch S. Semicarbazone of starch dialdehyde and its complexes with metal ions[J]. Carbohydrate Polymers,2002, 48(1):55-60.
[28] Fiedorowicz M,Kapusniak J,Karolczyk-Kostuch S. Selected novel materials from polysaccharides[J]. Polimery,2006,51(7/8):517-523.
[29] ?abanowska M,Bidzinska E,Para A,et al. EPR investigation of Cu(Ⅱ)-complexes with nitrogen derivatives of dialdehyde star-ch[J]. Carbohydrate Polymers,2012,87(4):2605-2613.
[30] Wang Rou,Liu Juntao,Li Chunyang. Removal of transition metal ions from aqueous solution using dialdehyde phenylhydrazine starch as adsorbent[J]. Water Science and Technology,2014,69(3):479-485.
[31] Wang Rou,Dong Zhengping,Wang Renqi. Efficient removal of Cd²⁺ by dialdehyde phenylhydrazine starch from aqueous solution[J].RSC Advances,2013,3(43):20480-20487.
[32] Battagli L P,Ferrari M B,Boggi R. Synthesis and characterization of lead(Ⅱ)-semicarbazone complexes. Crystal structures of dinitrato-di-2-pyridylketone semicarbazone lead(Ⅱ) and dichloro-cyclohex-ane-1,2-dione bis(semicarbazone)dimethylformamidelead(Ⅱ)[J]. Inorganica Chimica Acta,1994,215(1/2):85-90.
[33] Souza P,Sanz L,Fernandez V,et al. Complexes of Zn,Cd and Hg halides with S and N polydentate Schiff-base-Metal template effect in the synthesis of analogous oxygenated base-Crystal-structure of[Zn(btsc)₂Cl₂] and [Cd(btsc)₂Br₂][J]. Zeitschrift für Naturforsch-ung Section B:A Journal of Chemical Sciences,1991,46(6):767-774.
[34] Para A. Complexation of metal ions with dioxime of dialdehyde starch[J]. Carbohydrate Polymers,2004,57(3):277-283.
[35] 李静,闫云峰. 双醛淀粉尿素螯合树脂对Cu(Ⅱ)吸附性能的研究[J]. 甘肃农业大学学报,2014,49(3):165-170.
[36] Dong Aiqin,Xie Jie,Wang Wenmin,et al. A novel method for amino starch preparation and its adsorption for Cu(Ⅱ) and Cr(Ⅵ)[J]. Journal of Hazardous Materials,2010,181(1/2/3):448-454.
[37] 殷强峰. 双醛淀粉Schiff碱衍生物的合成与应用[D]. 大连:大连理工大学,2007.

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