Performance characteristics and mechanism of removal of heavy metal ions from wastewater by microbial electrolytic cell

doi:10.19965/j.cnki.iwt.2021-0779

Abstract

Abstract:

Microbial electrolytic cells（MECs），an organic combination of electroactive microorganisms and electrochemical systems，have great potential to overcome the low efficiency，uneconomic and secondary pollution in the purification of low concentration heavy metal wastewater by traditional physicochemical methods. The research status，influencing factors and mechanism of the removal of heavy metals from wastewater by MECs were summarized. The review showed that MECs could effectively remove a variety of heavy metal ions from wastewater through negative/anode reduction reaction，chemical precipitation and microbial adsorption. For Cr（Ⅵ），Cu（Ⅱ） and Ag（Ⅰ） metal ions with high potential，the removal efficiency of MECs could reach 95.0%-99.1% with the cathode reduction as the main removal mechanism. For low potential metal ions，microbial adsorption and chemical precipitation were dominant，and the efficiency reached 40.7%-87.0%. The removal process of heavy metals by MECs was mainly affected by electrode materials，chemical characteristics of solution and auxiliary voltage. Among them，cathode catalytic performance，material cost and long-term stability were the key parameters that affected the MECs efficiency. However，there were few reports about the treatment of heavy metals by MECs at present. Such as investment cost，adaptation scale and technology amplification of MECs devices still restricted the popularization and application of this technology. Strengthening the development of MECs economic electrode，the analysis and control of key factors，the study of purification mechanism and electron transfer pathway were the key to reduce the construction cost，improve the scale of treatment，adapt to the complex wastewater environment and promote the application of MECs technology.

Key words: microbial electrolysis cells, heavy metal, removal performance

摘要：

微生物电解池（MECs）有机结合了电活性微生物与电化学系统，其克服了传统物化法净化低浓度重金属废水时低效、不经济和产生二次污染等缺点，在处理低浓度重金属废水中具有较大应用潜力。总结归纳了MECs处理重金属废水的研究现状、影响因素以及作用机制等。综述表明，MECs可能通过阴/阳极还原反应、化学沉淀以及微生物吸附等机制，有效去除废水中多种重金属离子，对于Cr（Ⅵ）、Cu（Ⅱ）和Ag（Ⅰ）等高电位金属离子，以阴极还原去除为主导，其MECs净化效率达95.0%~99.1%，而对于低电位金属离子，以微生物吸附与化学沉淀为主导，效率达40.7%~87.0%。重金属的MECs去除过程主要受到电极材料、溶液化学特征和辅助电压等因素的影响，其中，阴极催化性能、材料成本和长期稳定性是影响MECs效能的关键参数。但目前MECs处理重金属的报道较少，MECs装置投资成本、适应规模和技术放大等依然制约着该技术推广应用；加强MECs经济电极开发、关键因素分析与调控、净化机制与电子转移途径的研究是降低构造成本、提升处理规模、适应复杂废水环境以及推动MECs技术广泛应用的关键所在。

关键词: 微生物电解池, 重金属, 去除性能

CLC Number:

X703

Xiuding SHI, Jing WANG, Ming JIANG, Tianguo LI, Wenchuang GUAN, Hongyan MA, Xuan ZHU, Jing XIE. Performance characteristics and mechanism of removal of heavy metal ions from wastewater by microbial electrolytic cell[J]. Industrial Water Treatment, 2022, 42(5): 26-33.

石秀顶, 王静, 蒋明, 李天国, 管文闯, 马红艳, 朱煊, 谢晶. 微生物电解池去除废水中重金属的性能特征与机制[J]. 工业水处理, 2022, 42(5): 26-33.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2021-0779

https://www.iwt.cn/EN/Y2022/V42/I5/26

Figures/Tables 3

References 60

1	周怀东，彭文启.水污染与水环境修复［M］.北京：化学工业出版社，2005：1-5.
2	KURNIAWAN T A， CHAN G Y S， LO W H，et al.Physico-chemical treatment techniques for wastewater laden with heavy metals［J］.Chemical Engineering Journal，2006，118（1/2）：83-98. doi:10.1016/j.cej.2006.01.015
3	王在兴.废水中的重金属处理方法分析［J］.环境与发展，2019，31（1）：63，65.
	WANG Zaixing.Analysis of heavy metal treatment methods in wastewater［J］.Environment and Development，2019，31（1）：63，65.
4	LIU Hong， GROT S， LOGAN B E.Electrochemically assisted microbial production of hydrogen from acetate［J］.Environmental Science & Technology，2005，39（11）：4317-4320. doi:10.1021/es050244p
5	王博，高冠道，李凤祥，等.微生物电解池应用研究进展［J］.化工进展，2017，36（3）：1084-1092. doi:10.1016/j.cej.2016.08.094
	WANG Bo， GAO Guandao， LI Fengxiang，et al.Advance in application of microbial electrolysis cells［J］.Chemical Industry and Engineering Progress，2017，36（3）：1084-1092. doi:10.1016/j.cej.2016.08.094
6	张存胜，崔凤杰，骆琳，等.微生物电解池制氢技术研究进展［J］.现代化工，2015，35（12）：48-51.
	ZHANG Cunsheng， CUI Fengjie， LUO Lin，et al.Advance in hydrogen production from microbial electrolysis cell［J］.Modern Chemical Industry，2015，35（12）：48-51.
7	WRANA N， SPARLING R， CICEK N，et al.Hydrogen gas production in a microbial electrolysis cell by electrohydrogenesis［J］.Journal of Cleaner Production，2010，18：S105-S111. doi:10.1016/j.jclepro.2010.06.018
8	CALL D， LOGAN B E.Hydrogen production in a single chamber microbial electrolysis cell lacking a membrane［J］.Environmental Science & Technology，2008，42（9）：3401-3406. doi:10.1021/es8001822
9	MATHURIYA A S， YAKHMI J V.Microbial fuel cells to recover heavy metals［J］.Environmental Chemistry Letters，2014，12（4）：483-494. doi:10.1007/s10311-014-0474-2
10	WANG Hanwen， WANG Hongbo， GAO Changfei，et al.Enhanced removal of copper by electroflocculation and electroreduction in a novel bioelectrochemical system assisted microelectrolysis［J］.Bioresource Technology，2020，297：122507. doi:10.1016/j.biortech.2019.122507
11	TAO Huchun， ZHANG Lijuan， GAO Zhuyou，et al.Copper reduction in a pilot-scale membrane-free bioelectrochemical reactor［J］.Bioresource Technology，2011，102（22）：10334-10339. doi:10.1016/j.biortech.2011.08.116
12	CHOI C， HU Naixu.The modeling of gold recovery from tetrachloroaurate wastewater using a microbial fuel cell［J］.Bioresource Technology，2013，133：589-598. doi:10.1016/j.biortech.2013.01.143
13	CHOI C， CUI Yufeng.Recovery of silver from wastewater coupled with power generation using a microbial fuel cell［J］.Bioresource Technology，2012，107：522-525. doi:10.1016/j.biortech.2011.12.058
14	ZHANG Yifeng， ANGELIDAKI I.Microbial electrolysis cells turning to be versatile technology：Recent advances and future challenges［J］.Water Research，2014，56：11-25. doi:10.1016/j.watres.2014.02.031
15	CHEN Yiran， SHEN Jingya， HUANG Liping，et al.Enhanced Cd（Ⅱ） removal with simultaneous hydrogen production in biocathode microbial electrolysis cells in the presence of acetate or NaHCO₃ ［J］.International Journal of Hydrogen Energy，2016，41（31）：13368-13379. doi:10.1016/j.ijhydene.2016.06.200
16	LI Meng， ZHOU Shaoqi， XU Yuting.Performance of Pb（Ⅱ） reduction on different cathodes of microbial electrolysis cell driven by Cr（Ⅵ）-reduced microbial fuel cell［J］.Journal of Power Sources，2019，418：1-10. doi:10.1016/j.jpowsour.2019.02.032
17	NANCHARAIAH Y V， MOHAN S V， LENS P N L.Metals removal and recovery in bioelectrochemical systems：A review［J］.Bioresource Technology，2015，195：102-114. doi:10.1016/j.tibtech.2015.11.003
18	WANG Heming， REN Z J.A comprehensive review of microbial electrochemical systems as a platform technology［J］.Biotechnology Advances，2013，31（8）：1796-1807. doi:10.1016/j.biotechadv.2013.10.001
19	LI Yan， WU Yining， LIU Bingchuan，et al.Self-sustained reduction of multiple metals in a microbial fuel cell-microbial electrolysis cell hybrid system［J］.Bioresource Technology，2015，192：238-246. doi:10.1016/j.biortech.2015.05.030
20	MODIN O， WANG Xiaofei， WU Xue，et al.Bioelectrochemical recovery of Cu，Pb，Cd，and Zn from dilute solutions［J］.Journal of Hazardous Materials，2012，235/236：291-297. doi:10.1016/j.jhazmat.2012.07.058
21	HUANG Liping， YAO Binglin， WU Dan，et al.Complete cobalt recovery from lithium cobalt oxide in self-driven microbial fuel cell-Microbial electrolysis cell systems［J］.Journal of Power Sources，2014，259：54-64. doi:10.1016/j.jpowsour.2014.02.061
22	JIANG Linjie， HUANG Liping， SUN Yuliang.Recovery of flakey cobalt from aqueous Co（Ⅱ） with simultaneous hydrogen production in microbial electrolysis cells［J］.International Journal of Hydrogen Energy，2014，39（2）：654-663. doi:10.1016/j.ijhydene.2013.10.112
23	TAO Huchun， LEI Tao， SHI Gang，et al.Removal of heavy metals from fly ash leachate using combined bioelectrochemical systems and electrolysis［J］.Journal of Hazardous Materials，2014，264：1-7. doi:10.1016/j.jhazmat.2013.10.057
24	CAI Wenfang， GENG Deli， WANG Yunhai.Assessment of cathode materials for Ni（Ⅱ） reduction in microbial electrolysis cells［J］.RSC Advances，2016，6（38）：31732-31738. doi:10.1039/c6ra02082h
25	COLANTONIO N， KIM Y.Cadmium（Ⅱ） removal mechanisms in microbial electrolysis cells［J］.Journal of Hazardous Materials，2016，311：134-141. doi:10.1016/j.jhazmat.2016.02.062
26	LI Jiannan， YU Yanling， CHEN Dahong，et al.Hydrophilic graphene aerogel anodes enhance the performance of microbial electrochemical systems［J］.Bioresource Technology，2020，304：122907. doi:10.1016/j.biortech.2020.122907
27	LI Yan， LU Anhuai， DING Hongrui，et al.Cr（Ⅵ） reduction at rutile-catalyzed cathode in microbial fuel cells［J］.Electrochemistry Communications，2009，11（7）：1496-1499. doi:10.1016/j.elecom.2009.05.039
28	QIN Bangyu， LUO Haiping， LIU Guangli，et al.Nickel ion removal from wastewater using the microbial electrolysis cell［J］.Bioresource Technology，2012，121：458-461. doi:10.1016/j.biortech.2012.06.068
29	LUO Haiping， LIU Guangli， ZHANG Renduo，et al.Heavy metal recovery combined with H₂ production from artificial acid mine drainage using the microbial electrolysis cell［J］.Journal of Hazardous Materials，2014，270：153-159. doi:10.1016/j.jhazmat.2014.01.050
30	SÁNCHEZ C， DESSÌ P， DUFFY M，et al.Microbial electrochemical technologies：Electronic circuitry and characterization tools［J］.Biosensors and Bioelectronics，2020，150：111884. doi:10.1016/j.bios.2019.111884
31	HE Weihua， DONG Yue， LI Chao，et al.Field tests of cubic-meter scale microbial electrochemical system in a municipal wastewater treatment plant［J］.Water Research，2019，155：372-380. doi:10.1016/j.watres.2019.01.062
32	SELEMBO P A， MERRILL M D， LOGAN B E.The use of stainless steel and nickel alloys as low-cost cathodes in microbial electrolysis cells［J］.Journal of Power Sources，2009，190（2）：271-278. doi:10.1016/j.jpowsour.2008.12.144
33	ZHANG Yimin， MERRILL M D， LOGAN B E.The use and optimization of stainless steel mesh cathodes in microbial electrolysis cells［J］.International Journal of Hydrogen Energy，2010，35（21）：12020-12028. doi:10.1016/j.ijhydene.2010.08.064
34	CALL D F， MERRILL M D， LOGAN B E.High surface area stainless steel brushes as cathodes in microbial electrolysis cells［J］.Environmental Science & Technology，2009，43（6）：2179-2183. doi:10.1021/es803074x
35	KUMARG， BAKONYI P， ZHEN Guangyin，et al.Microbial electrochemical systems for sustainable biohydrogen production：Surveying the experiences from a start-up viewpoint［J］.Renewable and Sustainable Energy Reviews，2017，70：589-597. doi:10.1016/j.rser.2016.11.107
36	YU J， KIM S， KWON O S.Effect of applied voltage and temperature on methane production and microbial community in microbial electrochemical anaerobic digestion systems treating swine manure［J］.Journal of Industrial Microbiology and Biotechnology，2019，46（7）：911-923. doi:10.1007/s10295-019-02182-6
37	YANG Qiuyu， ZHAO Nan， WANG Han，et al.Electrochemical and biochemical profiling of the enhanced hydrogenotrophic denitrification through cathode strengthening using bioelectrochemical system（BES）［J］.Chemical Engineering Journal，2020，381：122686. doi:10.1016/j.cej.2019.122686
38	LUO Haiping， FU Shiyu， LIU Guangli，et al.Autotrophic biocathode for high efficient sulfate reduction in microbial electrolysis cells［J］.Bioresource Technology，2014，167：462-468. doi:10.1016/j.biortech.2014.06.058
39	LIU Shujuan， FENG Yujie， NIU Jiaojiao，et al.A novel single chamber vertical baffle flow biocathode microbial electrochemical system with microbial separator［J］.Bioresource Technology，2019，294：122236. doi:10.1016/j.biortech.2019.122236
40	MOGHISEH Z， REZAEE A， GHANATI F，et al.Metabolic activity and pathway study of aspirin biodegradation using a microbial electrochemical system supplied by an alternating current［J］.Chemosphere，2019，232：35-44. doi:10.1016/j.chemosphere.2019.05.186
41	SHEN Jingya， SUN Yuliang， HUANG Liping，et al.Microbial electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced Co（Ⅱ） and Cu（Ⅱ） removal［J］.Frontiers of Environmental Science & Engineering，2015，9（6）：1084-1095. doi:10.1007/s11783-015-0805-y
42	DONG Yue， HE Weihua， LIANG Dandan，et al.Operation strategy of cubic-meter scale microbial electrochemistry system in a municipal wastewater treatment plant［J］.Journal of Power Sources，2019，441：227124. doi:10.1016/j.jpowsour.2019.227124
43	LI Xiao， ZENG Cuiping， LU Yaobin，et al.Development of methanogens within cathodic biofilm in the single-chamber microbial electrolysis cell［J］.Bioresource Technology，2019，274：403-409. doi:10.1016/j.biortech.2018.12.002
44	RAGO L， ZECCHIN S， MARZORATI S，et al.A study of microbial communities on terracotta separator and on biocathode of air breathing microbial fuel cells［J］.Bioelectrochemistry，2018，120：18-26. doi:10.1016/j.bioelechem.2017.11.005
45	安秋颖，郭璐露，黄泽波，等.含铬污水的生物修复技术研究现状及展望［J］.工业水处理.
	AN Qiuying， GUO Lulu， HUANG Zebo， CHEN Zigui， ZHAO Ran. Research status and prospect of bio-remediation technology for chromium-containing wastewater［J］. Industrial Water Treatment.
46	TANDUKAR M， TEZEL U， PAVLOSTATHIS S G.Biological chromium（Ⅵ） reduction in microbial fuel cell：A three in one approach［J］.Proceedings of the Water Environment Federation，2009（17）：527-535. doi:10.2175/193864709793955744
47	HUANG Liping， CHEN Jingwen， QUAN Xie，et al.Enhancement of hexavalent chromium reduction and electricity production from a biocathode microbial fuel cell［J］.Bioprocess and Biosystems Engineering，2010，33（8）：937-945. doi:10.1007/s00449-010-0417-7
48	周瑞康.定量评价不同阴极材料对Cd（Ⅱ）还原微生物电解池影响研究［D］.广州：华南理工大学，2020. doi:10.1016/j.biortech.2020.123198
	ZHOU Ruikang.Quantitative evaluation of the effects of different cathode materials on Cd（Ⅱ）-reduced microbial electrolysis cells［D］.Guangzhou：South China University of Technology，2020. doi:10.1016/j.biortech.2020.123198
49	赵欣，吴忆宁，靳敏.单室微生物电解池处理含镍模拟废水［J］.环境工程学报，2017，11（5）：2792-2796. doi:10.12030/j.cjee.201511007
	ZHAO Xin， WU Yining， JIN Min.Nickel efficiency removal in single-chamber microbial electrolysis cells［J］.Chinese Journal of Environmental Engineering，2017，11（5）：2792-2796. doi:10.12030/j.cjee.201511007
50	HUANG Liping， LI Tianchi， LIU Chuan，et al.Synergetic interactions improve cobalt leaching from lithium cobalt oxide in microbial fuel cells［J］.Bioresource Technology，2013，128：539-546. doi:10.1016/j.biortech.2012.11.011
51	WANG Zejie，LIM B， CHOI C.Removal of Hg²⁺ as an electron acceptor coupled with power generation using a microbial fuel cell［J］.Bioresource Technology，2011，102（10）：6304-6307. doi:10.1016/j.biortech.2011.02.027
52	ZHANG Baogang， ZHOU Shungui， ZHAO Huazhang，et al.Factors affecting the performance of microbial fuel cells for sulfide and vanadium（Ⅴ） treatment［J］.Bioprocess and Biosystems Engineering，2010，33（2）：187-194. doi:10.1007/s00449-009-0312-2
53	毛艳萍.微生物燃料电池中硫化物氧化和生物阴极的研究［D］.上海：华东理工大学，2010.
	MAO Yanping.Study on sulfide oxidation and biological cathode in microbial fuel cell［D］.Shanghai：East China University of Science and Technology，2010.
54	LI Zhongjian， ZHANG Xingwang， LEI Lecheng.Electricity production during the treatment of real electroplating wastewater containing Cr⁶⁺ using microbial fuel cell［J］.Process Biochemistry，2008，43（12）：1352-1358. doi:10.1016/j.procbio.2008.08.005
55	WANG Qiang， HUANG Liping， YU Hongtao，et al.Assessment of five different cathode materials for Co（Ⅱ） reduction with simultaneous hydrogen evolution in microbial electrolysis cells［J］.International Journal of Hydrogen Energy，2015，40（1）：184-196. doi:10.1016/j.ijhydene.2014.11.014
56	ABOURACHED C， CATAL T， LIU Hong.Efficacy of single-chamber microbial fuel cells for removal of cadmium and zinc with simultaneous electricity production［J］.Water Research，2014，51：228-233. doi:10.1016/j.watres.2013.10.062
57	Natalie C B E. Heavy metal removal from wastewater using microbial electrolysis cells［D］.Hamilton：McMaster University，2016.
58	PANDA G C， DAS S K， BANDOPADHYAY T S，et al.Adsorption of nickel on husk of Lathyrus sativus：Behavior and binding mechanism［J］.Colloids and Surfaces B：Biointerfaces，2007，57（2）：135-142. doi:10.1016/j.colsurfb.2007.01.022
59	CHOI C， HU Naixu，LIM B.Cadmium recovery by coupling double microbial fuel cells［J］.Bioresource Technology，2014，170：361-369. doi:10.1016/j.biortech.2014.07.087
60	LIU Liang， YUAN Yong， LI Fangbai，et al.In-situ Cr（Ⅵ） reduction with electrogenerated hydrogen peroxide driven by iron-reducing bacteria［J］.Bioresource Technology，2011，102（3）：2468-2473. doi:10.1016/j.biortech.2010.11.013

序号	目标离子	装置布置及关键参数	净化效果	途径与机制	参考文献
1	Co²⁺	双室MFCs-MECs耦合系统；石墨毡为MFCs和MECs阳极，以及MFCs阴极，碳棒为MECs阴极	可有效回收Co²⁺	阴极还原	〔21〕
2	Ni²⁺	双室MECs；石墨纤维刷为阳极，铜片为阴极	去除率达40.7%	阴极还原	〔24〕
3	Cd²⁺	单室MECs；石墨纤维刷为阳极，不锈钢网为阴极	24 h内去除率达50%~67%	阴极还原/Cd（OH）₂沉淀/CdCO₃沉淀	〔25〕
4	Cr⁶⁺	双室MFCs；阴极由天然金红石涂层抛光石墨制成，阳极为未抛光的石墨板	去除率达97%（26 h）	Cr₂O₇ ^2-被还原为Cr₂O₃/Cr（OH）₃沉淀	〔27〕
5	Ni²⁺	双室MECs；碳毡为阳极，不锈钢网为阴极；外加电压1.1 V	去除率达67%	阴极还原	〔28〕
6	Zn²⁺	双室MECs；碳毡为阳极，钛丝为阴极；外加电压1.7 V	3 h内去除率达65.8%	阴极还原	〔20〕
7	Cu²⁺、Ni²⁺	双室MECs；石墨刷为阳极，载铂碳布为阴极；外加电压1.0 V	24 h内Cu²⁺去除率达95%，42 h内Ni²⁺去除率达87%	阴极还原	〔29〕
8	Co²⁺	双室MECs；石墨刷为阳极，石墨毡为阴极；外加电压0.3~0.5 V	6 h内去除率达92.2%	阴极还原	〔22〕
9	Ag⁺	双室MFCs；碳刷为阳极，带钛丝的碳纤维为阴极	去除率达98.26%~99.91%	阴极还原	〔13〕
10	Au³⁺	双室MFCs；碳刷为阳极，碳布为阴极	回收率达99.89%	阴极还原	〔12〕

序号	目标离子	装置布置及关键参数	净化效果	途径与机制	参考文献
1	Co²⁺	双室MFCs-MECs耦合系统；石墨毡为MFCs和MECs阳极，以及MFCs阴极，碳棒为MECs阴极	可有效回收Co²⁺	阴极还原	〔21〕
2	Ni²⁺	双室MECs；石墨纤维刷为阳极，铜片为阴极	去除率达40.7%	阴极还原	〔24〕
3	Cd²⁺	单室MECs；石墨纤维刷为阳极，不锈钢网为阴极	24 h内去除率达50%~67%	阴极还原/Cd（OH）₂沉淀/CdCO₃沉淀	〔25〕
4	Cr⁶⁺	双室MFCs；阴极由天然金红石涂层抛光石墨制成，阳极为未抛光的石墨板	去除率达97%（26 h）	Cr₂O₇ ^2-被还原为Cr₂O₃/Cr（OH）₃沉淀	〔27〕
5	Ni²⁺	双室MECs；碳毡为阳极，不锈钢网为阴极；外加电压1.1 V	去除率达67%	阴极还原	〔28〕
6	Zn²⁺	双室MECs；碳毡为阳极，钛丝为阴极；外加电压1.7 V	3 h内去除率达65.8%	阴极还原	〔20〕
7	Cu²⁺、Ni²⁺	双室MECs；石墨刷为阳极，载铂碳布为阴极；外加电压1.0 V	24 h内Cu²⁺去除率达95%，42 h内Ni²⁺去除率达87%	阴极还原	〔29〕
8	Co²⁺	双室MECs；石墨刷为阳极，石墨毡为阴极；外加电压0.3~0.5 V	6 h内去除率达92.2%	阴极还原	〔22〕
9	Ag⁺	双室MFCs；碳刷为阳极，带钛丝的碳纤维为阴极	去除率达98.26%~99.91%	阴极还原	〔13〕
10	Au³⁺	双室MFCs；碳刷为阳极，碳布为阴极	回收率达99.89%	阴极还原	〔12〕

[1]	Xiuling LI, Bing BIN, Yingying GONG, Zhe WU, Xiangchu ZENG. Construction of iron-manganese modified mulberry branch biochar and the adsorption of aqueous phosphorus [J]. Industrial Water Treatment, 2025, 45(3): 175-184.
[2]	Weiqiu YANG, Guangyu SHI. Design and operation of wastewater treatment project for lithium battery production [J]. Industrial Water Treatment, 2025, 45(3): 206-211.
[3]	Zhao CHEN, Shihao LIU, Lijuan ZHU, Dezheng CHANG, Yan GAO. Responses of microalgal-nitrifying granular sludge to cadmium stress [J]. Industrial Water Treatment, 2025, 45(2): 126-131.
[4]	Dian LI, Xun WANG, Yingming LIU. Characteristics and treatment modes of industrial wastewater in new energy vehicles industrial park [J]. Industrial Water Treatment, 2025, 45(1): 26-31.
[5]	Zhihua DENG, Rui LIU, Biqing LI. Preparation of different biochars and their adsorption performance for heavy metals and antibiotics [J]. Industrial Water Treatment, 2025, 45(1): 94-103.
[6]	Ya HU, Xiaolei SUN, Jingyu LU, Xiuyun SUN. Preparation of Tymycin waste salt activated carbon and its adsorption performance for EDTA-Pb(Ⅱ) [J]. Industrial Water Treatment, 2024, 44(8): 133-139.
[7]	Chaochun TANG, Haoyou XU, Junjie CHEN, Wentao FENG, Yixuan RUAN, Xinglong HE, Yaozhong LIU. Research progress on removal of pollutants from water by MOFs@aerogel adsorption [J]. Industrial Water Treatment, 2024, 44(6): 12-21.
[8]	Jie LIU, Yuan BAI, Rui MA, Zongxian JING, Xinwen WAN, Hailong WU, Weiting HUANG. Research progress of MXene adsorption for removal of pollutants from water [J]. Industrial Water Treatment, 2024, 44(6): 40-52.
[9]	Xuemin FENG, Xiaoqing ZHANG, Aijun ZHANG, Junrui CAO, Xiyuan KOU, Hanwen SONG, Jinquan QIU. Identification of the risk factors in concentrated seawater from seawater desalination process [J]. Industrial Water Treatment, 2024, 44(6): 53-59.
[10]	Wei ZHANG, Xubiao LUO, Ting OUYANG, Zhengwei LIU, Ping XIONG. Research progress on removing typical organic heavy metal complexes from water by adsorption [J]. Industrial Water Treatment, 2024, 44(6): 60-68.
[11]	Danhua ZHAO, Xinxin LIAO, Yingxin DENG, Liuming CHEN, Lanfang LIANG, Jiahao HUANG, Zuoyi CHEN. Removal characteristics of heavy metals chelating agent N,N-bis(dithiocarboxy) ethylenediamine (EDTC) for synergistic treatment of EDTA-Cu/RhB [J]. Industrial Water Treatment, 2024, 44(5): 141-148.
[12]	Bing LI, Di WU, Yan SHI, Haixiang LI, Fu LI, Yi MA. Effect of membrane coupling technology on concentration and water purification of biogas slurry [J]. Industrial Water Treatment, 2024, 44(5): 156-163.
[13]	Cairui SUN, Zhu OUYANG, Lu CAO, Ying HU, Haiming HUANG, Bingqian WANG, Kehua LONG, Leyao TAO. Experimental study on the recovery of nitrogen and phosphorus from electroplating wastewater by struvite crystallization method [J]. Industrial Water Treatment, 2024, 44(4): 113-119.
[14]	Ying FENG, Kexin LI, Hong ZHANG, Hanzhe YU, Biao MA, Jianwei ZHANG, Xin DONG. Preparation of chitosan composite hydrogel and its application in water treatment [J]. Industrial Water Treatment, 2024, 44(2): 17-26.
[15]	Zishuai HE, Haitao LI, Hong GAO. Preparation of sludge-based activated carbon and its application for phosphorus adsorption [J]. Industrial Water Treatment, 2024, 44(12): 138-146.

Please choose a citation manager

Content to export