工业水处理 ›› 2007, Vol. 27 ›› Issue (12): 22-24. doi: 10.11894/1005-829x.2007(12).22

• 试验研究 • 上一篇    下一篇

非均相催化氧化处理对苯二甲酸工业废水

严文瑶, 陈银合, 汤庆华, 李定龙   

  1. 江苏工业学院环境与安全工程系 江苏 常州 213164
  • 收稿日期:2007-09-07 修回日期:2007-09-07 出版日期:2007-12-20 发布日期:2010-10-01
  • 作者简介:严文瑶(1965- ),硕士,高级工程师,主要从事水处理研究和设计工作。电话:13961496773,E-mail:ywy@em.jpu.edu.cn。

The treatment of terephthalic acid industrial wastewater by heterogeneous catalytic oxidation

Yan Wenyao, Chen Yinhe, Tang Qinghua, Li Dinglong   

  1. Department of Environmental and Safety Engineering, Jiangsu Polytechnic University, Changzhou 213164, China
  • Received:2007-09-07 Revised:2007-09-07 Online:2007-12-20 Published:2010-10-01

摘要:

采用非均相催化氧化法处理对苯二甲酸工业废水,研究了反应时间、氧化剂投加量、废水pH和废水起始浓度对CODCr去除率的影响。结果表明,以二氧化氯、次氯酸钠和双氧水作氧化剂,均可使废水的CODCr大幅度下降。采用不同的氧化剂时,废水的pH对CODCr去除率有明显的影响。在酸性条件下,用二氧化氯和次氯酸钠的CODCr去除率较高;而在中性条件下,采用双氧水的CODCr去除率较高。

关键词: 废水处理, 对苯二甲酸, 催化氧化

Abstract:

The experimental study on the treatment of terephthalic acid industrial wastewater by heterogeneous catalytic oxidation has been carried on.The effects of the reaction time,dosage of oxidant,pH and initial concentrations of the wastewater on CODCrremoval rate have been investigated.The results show that,using chlorine dioxide,sodium hypochlorite and H2O2as oxidant,high rates of CODCrreduction could be achieved.When different oxidant is used,pH obviously influences the CODCrremoval rate.When chlorine dioxide or sodium hypochlorite is used as oxidant,the CODCrremoval rate is higher under acidic condition.When H2O2is used as oxidant,the CODCrremoval rate is higher under neutral condition.

Key words: wastewater treatment, terephthalic acid, catalytic oxidation

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