工业水处理 ›› 2009, Vol. 29 ›› Issue (6): 41-43. doi: 10.11894/1005-829x.2009.29(6).41

• 试验研究 • 上一篇    下一篇

微电解/H2O2 工艺预处理TDA 废水的试验研究

王三反1, 刘徽1, 陈霞2   

  1. 1. 兰州交通大学环境与市政工程学院,甘肃兰州730070;
    2. 聊城大学建筑工程学院,山东聊城252059
  • 收稿日期:2008-12-22 出版日期:2009-06-20 发布日期:2010-10-01
  • 作者简介:王三反(1952- ),1982 年毕业于兰州交通大学,教授。电话:13150016917,E-mail:sfwang1612@sina.com

Study on the effect of micro-electrolysis and H2O2 technology on the pretreatment of TDA wastewater

Wang Sanfan1, Liu Hui1, Chen Xia2   

  1. 1. School of Environment and Municipal Engineering , Lanzhou Jiaotong University, Lanzhou 730070,China;
    2. School of Architecture Engineering, Liaocheng University, Liaocheng 252059, China
  • Received:2008-12-22 Online:2009-06-20 Published:2010-10-01

摘要:

通过对微电解法﹑Fenton 法以及微电解/H2O2 法三种工艺的比较,试验确定采用微电解/H2O2 工艺对TDA 废水进行预处理,得出最佳工作条件:pH 为4~5、n(铁)∶n(炭)=1∶1、HRT 为70~80 min、V(Fe2+)∶V(H2O2)=7∶1~9∶1。经其 处理后出水TDA 浓度能够满足后续生物处理系统的要求,保证生物系统的出水达到国家一级排放标准。

关键词: 2, 4-二氨基甲苯, 微电解, Fenton 试剂

Abstract:

The three methods, including micro-electrolysis method, Fenton reagent method and micro-electrolysis combined with H2O2 method, have been compared. It is determined to use micro-electrolysis plus H2O2 method for pretreating TDA wastewater. The best working conditions are as follows: iron/carbon ratio is 1∶1,pH from 4 to 5, HRT from 70 to 80 min, the best volume ratio between Fe2+ and H2O2 from 7∶1 to 9∶1. The TDA’s concentration of effluent quality can meet the requirements of sequent biological treatment system, and ensure that the effluent of biological systems can reach the national first grade discharge standards level.

Key words: 2, 4-toluylene diamine, micro electrolysis, Fenton reagent

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