工业水处理 ›› 2013, Vol. 33 ›› Issue (6): 61-64. doi: 10.11894/1005-829x.2013.33(6).61

• 试验研究 • 上一篇    下一篇

CuO-H2O2非均相催化氧化染料废水

周凌云1, 郭伟2   

  1. 1. 河南科技学院资源与环境学院, 河南新乡 453003;
    2. 新乡医学院化学学院, 河南新乡 453003
  • 出版日期:2013-06-20 发布日期:2013-06-24
  • 作者简介:周凌云(1980— ),在读博士,讲师。电话:15936521518,E-mail: auto_link@tom.com。

CuO-H2O2 heterogeneous catalytic oxidation of dye wastewater

Zhou Lingyun1, Guo Wei2   

  1. 1. College of Resource and Environment, Henan Institute of Science and Technology, Xinxiang453003, China;
    2. Department of Chemistry, Xinxiang Medical University, Xinxiang 453003, China
  • Online:2013-06-20 Published:2013-06-24

摘要:

以活性艳红X-3B为模拟底物,研究了低温常压条件下CuO-H2O2体系催化氧化染料废水的各种影响因素及反应机制。结果表明,CuO-H2O2体系能高效彻底地氧化活性艳红X-3B,氧化率可高达99%。CuO-H2O2体系降解染料废水的速率随温度、氧化剂和催化剂投加量以及X-3B废水初始浓度的升高而升高。酸性条件能促进X-3B废水的降解。与直接染料相比,CuO-H2O2体系降解活性染料废水更加有效。

关键词: CuO-H2O2, 活性艳红X-3B, 催化氧化

Abstract:

Reactive brilliant red X-3B has been selected as a model pollution substrate. Various influencing factors and reaction mechanism of catalytic oxidation dyestuff wastewater by the CuO-H2O2 system under low temperature and normal atmosphere conditions are studied. The results show that reactive brilliant red X-3B can be oxidized completely and effectively by the CuO-H2O2 system. Its oxidation rate can be as high as 99%. The speed of dyestuff wastewater degradation by CuO-H2O2 system increases with the increase of temperature,and dosages of oxidant andcatalyst,as well as the increase of initial concontration of X-3B wastewater. Acidic condition can promote the degradation of X-3B wastewater. Compared with direct dyestuff,the degradation of reactive dyestuff wastewater by CuOH2O2 system is more efficient.

Key words: CuO-H2O2, reactive brilliant red X-3B, catalytic oxidation

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