工业水处理 ›› 2014, Vol. 34 ›› Issue (1): 68-70,76. doi: 10.11894/1005-829x.2014.34(1).068

• 油气田水处理 • 上一篇    下一篇

适合海上油田配聚水软化的弱酸型树脂性能研究

陈士佳1,2, 吴晓燕2, 朱洪庆1,2, 陈斌2, 田津杰2, 易飞1,2   

  1. 1. 海洋石油高效开发国家重点实验室, 天津 300452;
    2. 中海油能源发展股份有限公司工程技术分公司, 天津 300452
  • 收稿日期:2013-11-05 出版日期:2014-01-20 发布日期:2014-02-27
  • 作者简介:陈士佳(1981-),工程师。E-mail:chenshj2@cnooc.com.cn
  • 基金资助:

    “十一五”国家科技重大专项(2008ZX05024-002)

Research on the characteristics of weak-acid type resin suitable for offshore oilfield polymer preparing water softening

Chen Shijia1,2, Wu Xiaoyan2, Zhu Hongqing1,2, Chen Bin2, Tian Jinjie2, Yi Fei1,2   

  1. 1. State Key Laboratory of Offshore Oil Exploitetion, Tianjin 300452, China;
    2. CNOOC EnerTech-Drilling & Production Co., Tianjin 300452, China
  • Received:2013-11-05 Online:2014-01-20 Published:2014-02-27

摘要:

针对渤海绥中36-1油田配聚水硬度高、黏度损失大的问题,通过静态与动态试验研究了弱酸薄壳型离子交换树脂BHS-1的软化性能。结果表明:该树脂耐温可达75 ℃,最高耐矿化度可达20 000 mg/L,耐铁可以达到5 mg/L。在油藏条件下,树脂的泄漏点能保证在7 h以上,具有良好的除钙能力;BHS-1树脂的耐铁性试验结果表明:随着原水中铁离子浓度的增大,泄漏点将会提前。在铁离子达到5 mg/L时,树脂在5 h内产水基本不发生泄漏,且容易再生,不会产生铁污染问题。

关键词: 离子交换, 弱酸型树脂, 海上油田, 水软化

Abstract:

Based on the situation that BHSZ36-1 oilfield polymer preparing water has high hardness and viscosity loss, the softening capacity of weak-acid type and thin-shell type ion exchange resin BHS-1 has been studied by static and dynamic experiments. The experimental results show that the BHS-1 has good temperature resistance 75 ℃, salinity resistance 20 000 mg/L, hardness resistance and anti-iron property. Under oil reservoir conditions, the leakage point of resin would surely appear after 7 h or longer, having pretty good capacity of calcium removing. The iron-resistance experimental results of resin BHS-1 show that with the increase of iron ions concentration in raw water, the leakage point would appear earlier. The resin produced water leakage will almost not occur within 5 h, and it is liable to regeneration with no iron pollution problems.

Key words: ion exchange, weak-acid type resin, offshore oilfield, water softening

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