工业水处理 ›› 2016, Vol. 36 ›› Issue (12): 35-38. doi: 10.11894/1005-829x.2016.36(12).008

• 试验研究 • 上一篇    下一篇

活性炭负载铁催化剂催化氧化聚乙烯醇废水

肖冠南1, 王梓屹2, 宋翔2, 张正国1,3   

  1. 1. 合肥工业大学化学与化工学院, 安徽合肥 230009;
    2. 四川理工学院材料与化学工程学院, 四川自贡 643000;
    3. 北方民族大学化学与化学工程学院, 宁夏银川 750021
  • 收稿日期:2016-10-19 出版日期:2016-12-20 发布日期:2016-12-26
  • 通讯作者: 张正国,博士,讲师。E-mail:zhangzhengguo1119@126.com。 E-mail:zhangzhengguo1119@126.com
  • 作者简介:肖冠南(1992-),硕士。电话:15255598996,E-mail:455832552@qq.com。
  • 基金资助:

    国家自然科学基金项目(21565001);北方民族大学科研项目(2016HG-KY05)

Catalytic oxidation of polyvinyl alcohol wastewater with activated carbon supported Fe catalyst

Xiao Guannan1, Wang Ziyi2, Song Xiang2, Zhang Zhengguo1,3   

  1. 1. School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China;
    2. School of Materials and Chemical Engineering, Sichuan University of Science and Engineering, Zigong 643000, China;
    3. School of Chemistry & Chemistry Engineering, Beifang University of Nationalities, Yinchuan 750021, China
  • Received:2016-10-19 Online:2016-12-20 Published:2016-12-26

摘要:

为解决膜技术处理聚乙烯醇(PVA)废水时出现的膜材料孔道堵塞、设备反洗频繁等问题,以等体积浸渍法制备了Fe/活性炭(AC)催化剂,并采用H2O2催化氧化法预处理PVA模拟废水。结果表明,Fe/AC催化剂在H2O2催化氧化PVA废水工艺中能够高效降解水中的PVA,将0.2 g Fe/AC催化剂和4 mL H2O2加入到200 mL质量浓度为500 mg/L的PVA模拟废水中,PVA去除率达到91%。

关键词: 聚乙烯醇, 催化氧化, 活性炭, 铁催化剂

Abstract:

To solve the problems of membrane technologies for the treatment of polyvinyl alcohol(PVA) wastewater,such as channel obstruction of membrane materials,frequent equipment backwashing,etc.,activated carbon(AC) supported Fe catalyst has been prepared by isometric impregnation method,and the PVA simulated wastewater is pretreated by H2O2 catalytic oxidation method. The results reveal that AC supported Fe catalyst can efficiently degrade the PVA in wastewater in the process of H2O2 catalytic oxidation. The PVA removing rate reaches 91% by adding 0.2 g of catalyst and 4 mL of H2O2 to 200 mL of PVA simulated wastewater whose mass concentration is 500 mg/L.

Key words: polyvinyl alcohol, catalytic oxidation, activated carbon, Fe catalyst

中图分类号: