煤化工废水处理技术研究与进展

doi:10.11894/1005-829x.2017.37(1).001

摘要/Abstract

摘要：

介绍了煤化工废水的来源、水质特点和处理难题。针对煤化工废水主要处理技术，即分离技术、生物技术和高级氧化技术，综述了国内外有关研究的现状、发展趋势和应用。展望了未来的研究方向，指出各种处理技术的组合和优化，缓解废水对生物工艺的毒性抑制性，达到高效生物脱氮的效果，是实现煤化工废水“零排放”的必然趋势。

关键词: 煤化工废水, 分离技术, 生物技术, 高级氧化技术

Abstract:

The sources, characteristics of water quality and difficulties in the treatment of coal chemical wastewater are introduced.Aiming at the main treatment technologies, including three aspects:the separation technology, bio-logical technology and advanced oxidation technology, the relevant research status, development trend and applica-tion in China and abroad are summarized.The future research directions are predicted, and the combination and op-timization of various treatment technologies are pointed out, so as to alleviate the inhibition of wastewater, achieving the effect of efficient biological denitrification.It is an inevitable trend to realize the ‘zero discharge’ of coal chemical wastewater.

Key words: coalchemical wastewater, separation technology, biological treatment process, advanced oxidation process

中图分类号:

X703

庄海峰, 袁小利, 韩洪军. 煤化工废水处理技术研究与进展[J]. 工业水处理, 2017, 37(1): 1-6.

Zhuang Haifeng, Yuan Xiaoli, Han Hongjun. Research and progress in the treatment technology of coal chemical wastewater[J]. INDUSTRIAL WATER TREATMENT, 2017, 37(1): 1-6.

https://www.iwt.cn/CN/Y2017/V37/I1/1

参考文献

[1] Attwood T,Fung V,Clark W W. Market opportunities for coal gasifi-cation in China[J]. Journal of Cleaner Production,2003,11(4):473-479.
[2] 吴春来. 21世纪我国煤炭综合利用趋势浅析[J]. 煤化工,2000(4):3-5.
[3] 程宗泽,张十川. 新型煤化工产业发展近况与思考[J]. 煤,2009, 18(6):39-42.
[4] Minchener A J. Coal gasification for advanced power generation[J]. Fuel,2005,84(17):2222-2235.
[5] Lai P,Zhao H,Wang C,et al. Advanced treatment of coking waste-water by coagulation and zero-valent iron processes[J]. Journal of Hazardous Materials,2007,147(1/2):232-239.
[6] 周学双,赵秋月. 对我国煤炭利用与煤化工产业发展的环保思索[J]. 中国煤炭,2009,35(11):106-109.
[7] 何绪文,王春荣. 新型煤化工废水零排放技术问题与解决思路[J]. 煤炭科学技术,2015,43(1):120-124.
[8] 盖恒军,江燕斌,钱宇,等. 煤气化废水处理过程瓶颈及改进措施分析[J]. 化学工程,2007,35(8):57-60.
[9] 钱宇,周志远,陈赟,等. 煤气化废水酚氨分离回收系统的流程改造和工业实施[J]. 化工学报,2010,61(7):1821-1828.
[10] Feng D,Yu Z,Chen Y,et al. Novel single stripper with side-draw to remove ammonia and sour gas simultaneously for coal-gasification wastewater treatment and the industrial implementation[J]. Indus-trial & Engineering Chemistry Research,2009,48(12):58165823.
[11] 张能一,唐秀华,邹平,等. 我国焦化废水的水质特点及其处理方法[J]. 净水技术,2005,24(2):42-47.
[12] 耿俊峰,韩义军. 气浮技术在处理哈尔滨气化厂煤加压气化废水中的应用[J]. 煤炭技术,2002,21(2):52-53.
[13] Han H J,Zhao Q,Xu C Y,et al. Coal gasification wastewater pre-treatment with coagulation and N₂ flotation combined system[J]. Journal of Harbin Institute of Technology(New Series),2013,20(5):20-24.
[14] 赵庆良,管凤伟. 不同混凝剂处理煤气废水生物出水的研究[J]. 黑龙江大学自然科学学报,2010,27(2):233-236.
[15] 崔晓君,谢俊. 高COD焦化废水的吸附研究[J]. 工业安全与环保,2007,33(9):27-28.
[16] 刘心中,姚德,董凤芝,等. 粉煤灰在废水处理中的应用[J]. 化工矿物与加工,2002,31(8):4-7.
[17] 韩超,叶杰旭,孙德智. O₃-MBR法深度处理煤气废水[J]. 环境科学研究,2010,23(7):970-974.
[18] Jia S Y,Han H J,Hou B L,et al. Treatment of coal gasification waste-water by membrane bioreactor hybrid powdered activated carbon(MBR-PAC) system[J]. Chemosphere,2014,117:753-759.
[19] 闻晓今,周正,魏钢,等. 超滤-纳滤对焦化废水深度处理的试验研究[J]. 水处理技术,2010,36(3):93-95.
[20] Kim Y M,Park D,Jeon C O,et al. Effect of HRT on the biological pre-denitrification process for the simultaneous removal of toxic pollutants from cokes wastewater[J]. Bioresource Technology, 2008,99(18):8824-8832.
[21] Ramakrishnan A,Gupta S K. Anaerobic biogranulation in a hybrid reactor treating phenolic waste[J]. Journal of Hazardous Materials,2006,137(3):1488-1495.
[22] Wang W,Han H J,Yuan M,et al. Enhanced anaerobic biodegrada-bility of real coal gasification wastewater with methanol addition[J]. Journal of Environmental Sciences,2010,22(12):1868-1874.
[23] Wang W,Ma W C,Han H J,et al. Thermophilic anaerobic digestion of Lurgi coal gasification wastewater in a UASB reactor[J]. Biore-source Technology,2011,102(3):2441-2447.
[24] Jia S Y,Han H J,Zhuang H F,et al. Impact of high external circula-tion ratio on the performance of anaerobic reactor treating coal gasification wastewater under thermophilic condition[J]. Bioreso-urce Technol.,2015,192:507-513.
[25] 王晨,马放,山丹,等. 用于煤气废水深度处理的脱酚菌的特性[J]. 江苏大学学报:自然科学版,2008,29(3):255-259.
[26] Liu Y S,Han H J,Fang F. Application of bioaugmentation to impove the long-chain alkanes removal efficiency in coal gasification waste-water[J]. Fresenius Environmental Bulletin,2013,22(8A):2448-2455.
[27] Fang F,Han H J,Zhao Q,et al. Bioaugmentation of biological con-tact oxidation reactor(BCOR) with phenol-degrading bacteria for coal gasification wastewater(CGW) treatment[J]. Bioresource Tech-nology,2013,150C(3):314-320.
[28] Li H Q,Han H J,Du M A,et al. Removal of phenols,thiocyanate and ammonium from coal gasification wastewater using moving bed biofilm reactor[J]. Bioresource Technology,2011,102(7):4667-4673.
[29] 韩洪军,李慧强,杜茂安,等. 厌氧/好氧/生物脱氨工艺处理煤化工废水[J]. 中国给水排水,2010,26(6):75-77.
[30] 张文启,马军,邱立平. 煤气废水好氧-缺氧-好氧生物处理研究[J]. 工业水处理,2006,26(2):32-35.
[31] Na S,Ahn Y,Cui M,et al. Significant diethyl phthalate(DEP) de-gradation by combined advanced oxidation process in aqueous solu-tion[J]. Journal of Environmental Management,2012,101(2):104110.
[32] 张娴娴,尹光志,李东伟. Fenton试剂催化氧化法处理焦化废水的实验研究[J]. 矿业安全与环保,2005,32(2):12-13.
[33] 赵晓亮,魏宏斌,陈良才,等. Fenton试剂氧化法深度处理焦化废水的研究[J]. 中国给水排水,2010,26(3):93-95.
[34] 朱凌峰,罗琳,蒋宏国,等. Fenton试剂在微波条件下处理稻壳热解发电含酚废水的试验[J]. 水资源保护,2010,26(3):53-56.
[35] Duesterberg C K,Mylon S E,Waite T D. pH effects on iron-cataly-zed oxidation using Fenton's reagent[J]. Environmental Science & Technology,2008,42(22):8522-8527.
[36] 陈颖敏,邓海燕. 应用三维电极-电生成Fenton试剂法处理含酚废水[J]. 理化检验:化学分册,2009(10):1166-1168.
[37] Wang W,Liu Y,Li T,et al. Heterogeneous Fenton catalytic degra-dation of phenol based on controlled release of magnetic nanoparticles[J]. Chemical Engineering Journal,2014,242:1-9.
[38] Nawrocki J,Kasprzyk-Hordern B. The efficiency and mechanisms of catalytic ozonation[J]. Applied Catalysis B Environmental,2010, 99(1/2):27-42.
[39] Beltran F J,Garcia-Araya J F,Alvarez P M. pH sequential ozona-tion of domestic and wine-distillery wastewaters[J]. Water Research, 2001,35(4):929-936.
[40] Liotta L F,Gruttadauria M,Di Carlo G,et al. Heterogeneous cata-lytic degradation of phenolic substrates:Catalysts activity[J]. Journal of Hazardous Materials,2009,162(2/3):588-606.
[41] 刘金泉,李天增,王发珍,等. O₃、H₂O₂/O₃及UV/O₃在焦化废水深度处理中的应用[J]. 环境工程学报,2009,3(3):501-505.
[42] 韩洪军,庄海峰,赵茜,等. 非均相催化臭氧处理煤化工生化出水[J]. 哈尔滨工业大学学报,2014,46(6):50-54.
[43] 吕贵芬,吴丁财,符若文. 炭气凝胶三维电极催化氧化处理苯酚废水的研究[J]. 中山大学学报:自然科学版,2008,47(3):75-78.
[44] Zhu X,Ni J,Lai P. Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using boron-doped diamond electrodes[J]. Water Research,2009,43(17):4347-4355.
[45] 唐受印,汪大,刘先德,等. 高浓度酚水的湿式氧化研究[J]. 环境科学研究,1995,8(6):37-41.
[46] 陈拥军,窦和瑞,杨民,等. 催化湿式氧化法在苯酚废水预处理中的应用研究[J]. 工业水处理,2002,22(6):19-22.
[47] Wang Y,Wang S,Guo Y,et al. Oxidative degradation of Lurgi coal-gasification wastewater with Mn₂O₃,Co₂O₃, and CuO catalysts in supercritical water[J]. Industrial & Engineering Chemistry Rese-arch,2012,51(51):16573-16579.

选择文件类型/文献管理软件名称

选择包含的内容