工业水处理 ›› 2017, Vol. 37 ›› Issue (6): 75-77,81. doi: 10.11894/1005-829x.2017.37(6).075

• 试验研究 • 上一篇    下一篇

微电解臭氧氧化深度处理石化企业含盐污水试验研究

许国平, 王湘, 周付健, 贺学军, 镇祝龙   

  1. 岳阳长岭设备研究所有限公司, 湖南岳阳 414012
  • 收稿日期:2017-03-16 出版日期:2017-06-20 发布日期:2017-06-23
  • 作者简介:许国平(1984-),硕士研究生,工程师。E-mail:xuguoping1984040@163.com。
  • 基金资助:
    中石化长岭分公司科研项目(ZC0607-00015)

Experimental study on the advanced treatment of salt-containing wastewater from a refinery by micro-electrolytic and ozonation

Xu Guoping, Wang Xiang, Zhou Fujian, He Xuejun, Zhen Zhulong   

  1. Yueyang Changling Equipment Research Insitute(Co., Ltd. ), Yueyang 414012, China
  • Received:2017-03-16 Online:2017-06-20 Published:2017-06-23

摘要: 针对某石化企业含盐污水的深度处理,开展了微电解氧化和臭氧氧化对比试验研究,比较了2种方法的处理效果。结果表明,对于微电解氧化法,在反应时间为2 h,pH为2~3,填料比为1∶1的条件下,COD去除率为12%~18%,B/C可从原水的0.07升高到0.11,B/C提高幅度小,出水可生化性仍较差,且产生较多沉渣;对于臭氧氧化法,当臭氧投加量为25 g/h,反应时间为2.0 h时,COD去除率达25%,B/C可从原水的0.07升高至0.35,B/C大幅提高,利于后续进一步生化处理。

关键词: 含盐污水, 微电解, 臭氧, 深度处理

Abstract: Aiming at the advanced treatment of salt-containing wastewater in a petrochemical enterprise,the research of comparative tests on micro- electrolytic oxidation and ozone oxidation methods has been accomplished. The treatment effects of the two methods are compared. The results show that for micro-electrolytic oxidation method,when reaction time is 2 h,pH 2-3,filler ratio 1:1,the removing rate of COD reaches 12% -18%,B/C increases from 0.07 to 0.11,and biodegradability is still rather poor. For ozone oxidation method,when the ozone dosage is 25 g/h and reaction time 2.0 h,the COD removing rate reaches 25%,B/C can increase from 0.07 to 0.35 substantially,being advantageous to the subsequent biochemical treatment.

Key words: salt-containing wastewater, micro-electrolytic, ozone, advanced treatment

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