工业水处理 ›› 2017, Vol. 37 ›› Issue (7): 55-57,95. doi: 10.11894/1005-829x.2017.37(7).055

• 试验研究 • 上一篇    下一篇

纳滤工艺深度处理焦化废水的中试研究

王姣1, 陈景辉2, 张艳1, 卢冰3, 罗方亮1   

  1. 1. 河北能源职业技术学院, 河北唐山 063004;
    2. 唐山中润煤化工有限公司, 河北唐山 063000;
    3. 开滦(集团)有限责任公司技术中心, 河北唐山 063000
  • 收稿日期:2017-04-17 出版日期:2017-07-20 发布日期:2017-07-31
  • 作者简介:王姣(1982—),硕士,副教授。电话:13513071810,E-mail:wjiao82@126.com。
  • 基金资助:
    河北省教育厅自然科学项目(Z2014119);开滦集团技术创新项目(Z2015-2)

Pilot study on the advanced treatment of coking wastewater by NF process

Wang Jiao1, Chen Jinghui2, Zhang Yan1, Lu Bing3, Luo Fangliang1   

  1. 1. Hebei Vocational College of Energy Sources Technology, Tangshan 063004, China;
    2. Tangshan Zhongrun Coal Chemical Industry Co., Ltd., Tangshan 063000, China;
    3. Technology Administration Dept., Kailuan(Group) Liability Corporation Ltd., Tangshan 063000, China
  • Received:2017-04-17 Online:2017-07-20 Published:2017-07-31

摘要: 以焦化废水为研究对象,考察了取消超滤预处理系统后,纳滤处理系统对该类废水污染物的处理效果。结果表明:纳滤工艺可直接应用于焦化废水的深度处理,COD去除率稳定在70%以上,出水COD维持在45mg/L以下;对氨氮的去除率可达50%以上;对总硬度的脱除率达96%以上,出水硬度维持在3.5 mg/L左右,各项水质均优于循环冷却水要求。虽然单独纳滤工艺稳定运行周期相对双膜工艺较短,但两种工艺的污染差异可通过化学清洗加以消除。

关键词: 纳滤, 焦化废水, 深度处理, 膜污染

Abstract: Using coking wastewater as research target,after the cancellation of UF pretreatment system,the treatment effect of NF systems on this kind of wastewater pollutants has been investigated. The results show that the NF process can be applied to the advanced treatment of coking wastewater directly,and its COD removing rate stays at above 70%,effluent COD maintains at 45% or less,SO4+-N removing rate is above 50%,total hardness removing rate reaches 96% or more,the effluent hardness maintains at about 3.5 mg/L. The water quality of every item is superior to the requirements for circulating cooling water. Although the stable operation period of single NF process is shorter than that of double membrane process,the pollution gap of these two kinds of processes can be eliminated by chemical cleaning.

Key words: NF, coking wastewater, advanced treatment, membrane pollution

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