工业水处理 ›› 2017, Vol. 37 ›› Issue (7): 62-65. doi: 10.11894/1005-829x.2017.37(7).062

• 试验研究 • 上一篇    下一篇

Ti/SnO2电极隔膜电解处理氨氮废水技术研究

秦微1, 谢陈鑫1, 卫玲2, 王震1, 赵慧1, 张艳芳1   

  1. 1. 中海油天津化工研究设计院有限公司, 天津 300131;
    2. 中国石油乌鲁木齐石化公司炼油厂, 新疆乌鲁木齐 830019
  • 收稿日期:2017-04-18 出版日期:2017-07-20 发布日期:2017-07-31
  • 作者简介:秦微(1987—),硕士,工程师。电话:13332010191,E-mail:274881782@qq.com。

Research on Ti/SnO2 electrode diaphragm electrolysis technology for the treatment of ammonia nitrogen wastewater

Qin Wei1, Xie Chenxin1, Wei Ling2, Wang Zhen1, Zhao Hui1, Zhang Yanfang1   

  1. 1. CenerTech Tianjin Chemical Research and Design Institute Co., Ltd., Tianjin 300131, China;
    2. PetroChina Urumqi Petrochemical Company Refinery, Urumqi 830019, China
  • Received:2017-04-18 Online:2017-07-20 Published:2017-07-31

摘要: 分别以平板Ti/SnO2网状电极和石墨为阳极和阴极,制作隔膜和无隔膜电解反应器并对比处理500mg/L自配氨氮溶液。在处理水量为3.6 L,电流密度为10 mA/cm2,有效阳极面积为1 440 cm2,电流为0.8 A,反应时间70 min 条件下,出水氨氮分别为74、222 mg/L,去除率分别为85.2%、55.6%;当两种反应器吨水电耗均为10.5kW·h时,出水氨氮分别为74、153 mg/L,去除率分别为85.2%、69.4%。在出水氨氮相同时,隔膜电解反应器在吨水电耗、电流效率以及反应速率方面均优于无隔膜电解反应器。

关键词: 隔膜, 电解, 氨氮废水

Abstract: Using Ti/SnO2 tablet mesh electrodes and graphite as anode and cathode respectively,the electrolytic reactors with and without diaphragms have been made,and the treatment results of the self-prepared 500 mg/L of ammonia nitrogen solution compared. Under the conditions as follows:water quantity is 3.6 L,current density 10 mA/cm2,effective anode area 1 440 cm2,electric current 0.8 A,and reaction time 70 min,the ammonia nitrogen effluent is 74 mg/L and 222 mg/L,respectively,and removing rates are 85.2%,55.6%,respectively. When the water/ electric power consumption per ton of the two kinds of reactors both are 10.5 kW·h,the effluent ammonia nitrogen are 74 mg/L and 153 mg/L,respectively,and removing rates 85.2% and 69.4%,respectively. When ammonia nitrogen effluent are the same,the diaphragm electrode reactor is superior to non-disphragm electrode reactor in all respects,such as water/power consumption per ton,electrical current efficiency and reaction rate.

Key words: diaphragm, electrolysis, ammonia nitrogen wastewater

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