工业水处理 ›› 2018, Vol. 38 ›› Issue (2): 52-54. doi: 10.11894/1005-829x.2018.38(2).052

• 试验研究 • 上一篇    下一篇

偶联剂修饰伊利石处理含Cu2+生产废水

牛云峰1, 刘盼1,2, 吴俊峰1, 王现丽1, 扶咏梅1, 郭一飞1, 朱新锋1, 顾效纲1,3   

  1. 1. 河南城建学院市政与环境工程学院, 河南平顶山 467036;
    2. 郑州大学化学与分子工程学院, 河南郑州 450001;
    3. 郑州大学水利与环境学院, 河南郑州 450001
  • 收稿日期:2017-11-22 出版日期:2018-02-20 发布日期:2018-03-03
  • 通讯作者: 吴俊峰,E-mail:wjf8047@163.com。 E-mail:wjf8047@163.com
  • 作者简介:牛云峰(1977-),硕士,讲师。E-mail:63294997@qq.com。
  • 基金资助:
    河南省高校青年骨干教师资助项目(2015GGJS-014)

Treatment of industrial wastewater containing Cu2+ with coupling agent modified illite

Niu Yunfeng1, Liu Pan1,2, Wu Junfeng1, Wang Xianli1, Fu Yongmei1, Guo Yifei1, Zhu Xinfeng1, Gu Xiaogang1,3   

  1. 1. College of Municipal and Environmental Engineering, Henan University of Urban Construction, Pingdingshan 467036, China;
    2. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China;
    3. School of Water Conservancy and Environment, Zhengzhou University, Zhengzhou 450001, China
  • Received:2017-11-22 Online:2018-02-20 Published:2018-03-03

摘要: 采用氨基硅烷偶联剂KH550对伊利石原矿进行改性,研究了改性伊利石对某企业含铜废水的处理效果。结果表明:在50 mL Cu2+质量浓度为194.65 mg/L的含铜废水中投加1.7 g的改性伊利石,Cu2+去除率可达到99.5%,废水中剩余Cu2+质量浓度为0.97 mg/L,达到《铜、钴、镍工业污染源排放标准》(GB 25467-2010)的铜排放标准要求。改性伊利石对Cu2+的吸附过程以化学吸附为主。

关键词: 氨基硅烷偶联剂KH550, 改性伊利石, 含铜废水

Abstract: Using amino-silane coupling agent KH550 for the modification of illite crude ore,the treatment effect of modified illite on the wastewater containing Cu2+ has been researched. The results show that the removing rate of Cu2+ can reach 99.5%,when 1.7 g of modified illite is added to 50 mL of wastewater containing Cu2+ whose mass concentration is 194.65 mg/L. The residual Cu2+ mass concentration is 0.97 mg/L,achieving the "Discharge Standard of Industrial Pollutants for Copper,Cobalt,Nickel"(GB 25467-2010). The adsorption process of Cu2+ by modified illite is mainly chemical adsorption.

Key words: amino-silane coupling agent KH550, modified illite, wastewater containing Cu2+

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