工业水处理 ›› 2012, Vol. 32 ›› Issue (5): 35-38. doi: 10.11894/1005-829x.2013.33(6).35

• 试验研究 • 上一篇    下一篇

微波/催化剂/H2O2降解酸性红B的研究

汪昆平, 汪春燕, 杨林   

  1. 重庆大学城市建设与环境工程学院, 重庆 400044
  • 收稿日期:2012-02-23 出版日期:2012-05-20 发布日期:2012-05-18
  • 通讯作者: 汪春燕,E-mail:564452889@qq.com E-mail:564452889@qq.com
  • 作者简介:汪昆平(1965-),2005年毕业于重庆大学,博士,副教授。
  • 基金资助:

    国家科技攻关计划重大项目(2006BAJ08B08);中央高校基本科研业务基金资助项目(CDJRC10210006);重庆市自然科学基金项目(CSTC,2008BB7299)

Study on the degradation of acidic red B by microwave/catalyst/H2O2

Wang Kunping, Wang Chunyan, Xu Qianqian, Yang Lin   

  1. College of Urban Construction & Environmental Engineering, Chongqing University, Chongqing 400044, China
  • Received:2012-02-23 Online:2012-05-20 Published:2012-05-18

摘要:

以颗粒活性炭为载体,分别负载Fe3+、Cu2+或Fe3+-Cu2+制备出催化剂,采用微波/催化剂/H2O2工艺对酸性红B进行降解研究,并考察了各种因素对酸性红B降解效果的影响。研究结果表明,活性炭负载Fe3+-Cu2+型催化剂对酸性红B的处理效果最好,适宜的Fe3+、Cu2+负载量均为1.0%;对于100 mL初始质量浓度为100 mg/L的酸性红B模拟染料废水,适宜的处理条件为初始pH=3、催化剂投加量0.1 g、H2O2.05 mL、微波功率300 W。在此条件下处理4 min后酸性红B去除率超过99%,说明微波/催化剂/H2O2工艺能够有效去除酸性红B。

关键词: 微波, 偶氮染料, 酸性红B, 催化氧化

Abstract:

The catalyst has been prepared with granular activated carbon which is used as carrier and loaded with Fe3+,Cu2+or Fe3+-Cu2+ respectively. The research on the degradation is carried out by using microwave/catalyst/H2O2 process. The effects of various influencing factors on the degradation effectiveness of acidic red B are investigated.The results show that the treatment effectiveness of the catalyst using activated carbon which has been loaded with Fe3+-Cu2+ is the best. The appropriate carrying capacity of Fe3+ and Cu2+ are all 1.0%. For 100 mL of acidic red B simulated wastewater whose initial mass concentration is 100 mg/L,the appropriate treatment conditions are initial pH=3,catalyst dosage 0.1 g,H2O2 0.05 mL and microwave power 300 W. Under these conditions,the removing rate of acidic red B after being treated for 4 min is more than 99%. It shows that the acidic red B can be removed by microwave/catalyst/H2O2 process effectively.

Key words: microwave, azo dye, acidic red B, catalytic oxidation

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