摘要： 针对生产间羟基-N，N-二乙基苯胺产生的苯胺类废水，研究大孔树脂吸附与微电解-Fenton联合法预处理苯胺类废水的效果。结果表明，选用H-103型树脂，动态吸附流速4 BV/h，吸附量7 BV，解吸速率2 BV/h条件下，COD脱除率达60%以上；微电解-Fenton法处理吸附出水，pH=3、铁屑投加质量浓度100 g/L，铁碳比为3∶1，H₂O₂用量6 mL/L，反应时间4 h，COD脱除率达62%以上。废水可生化性从0.05提高到0.32，达到预处理目的。

关键词: 大孔树脂吸附, 微电解, Fenton氧化

Abstract: Aiming at the aniline wastewater produced from M-hydroxy-N,N-diethylaniline production,the effects of macroporous resin adsorption and micro - electrolysis- Fenton combined process on the pretreatment of aniline wastewater has been studied. The results show that when H-103 resin is used,dynamic adsorption velocity is 4 BV/h,adsorption quantity 7 BV and resolution rate 2 BV/h,the COD removing rate is above 60%. When micro- electrolysis-Fenton process is used for treating adsorbed effluent,its pH is 3,mass concentration of scrap iron dosage 100 g/L,iron/carbon ratio＝3:1,H₂O₂ dosage 6 mL/L,and reaction time 4 h,the COD removing rate could reach 62% above. Its B/C is improved from 0.05 to 0.32,achieving the purpose of pretreatment.

Key words: macroporous resin adsorption, micro-electrolysis, Fenton oxidation

中图分类号: 

• X703.1