DMF废水生物处理研究进展

doi:10.11894/iwt.2018-0579

摘要/Abstract

摘要：

N，N-二甲基甲酰胺（DMF）是一种性能优良的有机溶剂，广泛应用于农药、医药、工业领域中。由于其具有毒性高、稳定性高、难降解等特点，近年来关于DMF废水的处理已成为国内外研究的重点和难点。综述了DMF废水的生物处理研究进展，包括国内外DMF高效降解菌、降解代谢研究进展以及DMF生物处理工艺研究进展，并对其未来发展前景进行了展望。

关键词: N, N-二甲基甲酰胺, 降解菌, 降解代谢, 生物处理

Abstract:

N, N-dimethylformamide(DMF) is a kind of organic solvent with excellent properties, and is widely used in pesticides, pharmaceuticals, and industrial fields. The treatment of DMF wastewater has become an emphasis and aporia in China and abroad in recent years, due to its characteristics of high toxicity, high stability and hard to be degraded. The research progress in the biological treatment of DMF wastewater, including DMF efficient degradation bacteria, degradation metabolism and DMF biological treatment process, in China and abroad is summarized, and the prospects for its future development previewed.

Key words: N, N-dimethylformamide(DMF), degrading bacteria, degradation and metabolism, biological treatment

中图分类号:

X703

张鹤,李泽兵,安凯,吴双,张艳梅. DMF废水生物处理研究进展[J]. 工业水处理, 2019, 39(6): 13-17.

He Zhang,Zebing Li,Kai An,Shuang Wu,Yanmei Zhang. Research progress in the biological treatment of DMF wastewater[J]. Industrial Water Treatment, 2019, 39(6): 13-17.

https://www.iwt.cn/CN/Y2019/V39/I6/13

图/表 2

参考文献 51

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时间	菌株名称	最适温度/℃	最适pH	DMF耐受性/（mg·L^-1）	DMF的72 h去除率
1999年	Alcaligenes sp. KUFA-1^〔6〕	30	7.0	500	2%DMF接种量，可去除100%
2004年	Pseudomonas sp. DVK1^〔7〕	30±2	7.0	400	0.4%DMF接种量，可去除50%
2006年	Ochrobactrum sp. DGVK1^〔8〕	30	7.0	250	3%DMF接种量，可去除71.3%
2009年	Paracoccus sp. strain DMF^〔9〕	37	7.0	15 000	4%DMF接种量，可去除93%
2010年	Paracoccus pantotrophu DMF-3^〔10〕	30	7.0	5 000	0.5%DMF接种量，可去除80%
2011年	Psewfiomonai1 sp.MBYD-3^〔11〕	30	7.0	400	2%DMF接种量，可去除100%
2012年	Ochrobactrum sp. DGVK1^〔12〕	30	7.0	250	2.5%DMF接种量，可去除100%
2013年	Paracoccus denitrificans SD1^〔13〕	30±2	7.0	300	3%DMF接种量，可去除91.3%
2013年	Bacillus subtilis^〔14〕	37	7.0~9.2	200
2014年	Paracoccus sp. SKG^〔15〕	30	7.0	600
2015年	Paracoccus sp. strains MKU1^〔16〕	30	7.2	1 000	1%DMF接种量，可去除55%
2015年	Paracoccus sp. strains MKU2^〔16〕	30	7.2	1 000	1%DMF接种量，可去除46%
2016年	Paracoccus huijuniae DM-2^〔17〕	30	7.0	5 000	0.5%DMF接种量，可去除95%

时间	菌株名称	最适温度/℃	最适pH	DMF耐受性/（mg·L^-1）	DMF的72 h去除率
1999年	Alcaligenes sp. KUFA-1^〔6〕	30	7.0	500	2%DMF接种量，可去除100%
2004年	Pseudomonas sp. DVK1^〔7〕	30±2	7.0	400	0.4%DMF接种量，可去除50%
2006年	Ochrobactrum sp. DGVK1^〔8〕	30	7.0	250	3%DMF接种量，可去除71.3%
2009年	Paracoccus sp. strain DMF^〔9〕	37	7.0	15 000	4%DMF接种量，可去除93%
2010年	Paracoccus pantotrophu DMF-3^〔10〕	30	7.0	5 000	0.5%DMF接种量，可去除80%
2011年	Psewfiomonai1 sp.MBYD-3^〔11〕	30	7.0	400	2%DMF接种量，可去除100%
2012年	Ochrobactrum sp. DGVK1^〔12〕	30	7.0	250	2.5%DMF接种量，可去除100%
2013年	Paracoccus denitrificans SD1^〔13〕	30±2	7.0	300	3%DMF接种量，可去除91.3%
2013年	Bacillus subtilis^〔14〕	37	7.0~9.2	200
2014年	Paracoccus sp. SKG^〔15〕	30	7.0	600
2015年	Paracoccus sp. strains MKU1^〔16〕	30	7.2	1 000	1%DMF接种量，可去除55%
2015年	Paracoccus sp. strains MKU2^〔16〕	30	7.2	1 000	1%DMF接种量，可去除46%
2016年	Paracoccus huijuniae DM-2^〔17〕	30	7.0	5 000	0.5%DMF接种量，可去除95%

时间	处理工艺	处理对象	最佳条件	处理效果
2000年	好氧处理法^〔35〕	DMF	质量分数为0.2%的NaCl，pH=7.0	DMF降解率达95.1%
2007年	膨胀颗粒污泥床（EGSB）^〔36〕	DMF、COD	COD 9 000 mg/L，水力停留时间30 h	COD及DMF去除率均达到85%
2013年	超净生物膜污水处理技术^〔37〕	DMF、BOD₅、COD	进出水设定流量18 L/h，污水在试验机中停留时间6 d	BOD₅降解率为99.68%，COD、DMF去除率可达75%
2014年~ 2015年	AO法、A²O法^〔38-39〕	二甲基亚酰胺（NDMA）4种初期产物	水力停留时间10 h，pH 8~9，温度30~35 ℃	NDMA初期产物去除率在85%~98%
2016年	混合式床生物膜反应器和活性污泥反应器^〔40〕	DMF	水力停留时间24 h，反应温度20 ℃	单独反应器处理DMF降解率分别为55.6%、43.6%，联合处理DMF降解率为94.17%
2016年	生态水箱^〔41〕	DMF、TOC、N	水力停留时间10 d	DMF去除率为91.7%

时间	处理工艺	处理对象	最佳条件	处理效果
2000年	好氧处理法^〔35〕	DMF	质量分数为0.2%的NaCl，pH=7.0	DMF降解率达95.1%
2007年	膨胀颗粒污泥床（EGSB）^〔36〕	DMF、COD	COD 9 000 mg/L，水力停留时间30 h	COD及DMF去除率均达到85%
2013年	超净生物膜污水处理技术^〔37〕	DMF、BOD₅、COD	进出水设定流量18 L/h，污水在试验机中停留时间6 d	BOD₅降解率为99.68%，COD、DMF去除率可达75%
2014年~ 2015年	AO法、A²O法^〔38-39〕	二甲基亚酰胺（NDMA）4种初期产物	水力停留时间10 h，pH 8~9，温度30~35 ℃	NDMA初期产物去除率在85%~98%
2016年	混合式床生物膜反应器和活性污泥反应器^〔40〕	DMF	水力停留时间24 h，反应温度20 ℃	单独反应器处理DMF降解率分别为55.6%、43.6%，联合处理DMF降解率为94.17%
2016年	生态水箱^〔41〕	DMF、TOC、N	水力停留时间10 d	DMF去除率为91.7%

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