染料敏化TiO<sub>2</sub>光催化剂的研究进展

doi:10.19965/j.cnki.iwt.2020-0765

摘要/Abstract

摘要：

TiO₂光催化剂因其耐用性、低成本、低毒性、超亲水性以及出色的化学稳定性，广泛应用于水中有机污染物的降解。但TiO₂的带隙（3.2 eV）较宽，导致TiO₂的光生电子-空穴对易复合，无法充分利用可见光，限制了其实际应用。染料敏化可将TiO₂的光响应范围扩展到可见光区域，提高其光催化活性。综述了染料敏化TiO₂光催化剂的原理、染料敏化剂的分类、不同染料敏化剂的应用现状及效果，以期为染料敏化在TiO₂光催化剂中的应用提供参考。

关键词: 染料敏化, 二氧化钛, 光催化

Abstract:

TiO₂ photocatalyst is widely used in the degradation of organic pollutants in water due to its durability, low cost, low toxicity, super hydrophilicity and excellent chemical stability. However, the wide band gap(3.2 eV) of TiO₂ leads to the easy recombination of the photogenerated electron-hole pairs and cannot make full use of visible light, which limits its practical application. Dye sensitization can extend the light response range of TiO₂ to visible light region and improve its photocatalytic activity. The principle of dye-sensitized TiO₂ photocatalyst, the classification of dye sensitizers, the application status and effects of different dye sensitizers are reviewed, in order to provide a reference for the application of dye-sensitized TiO₂ photocatalyst.

Key words: dye sensitization, titanium dioxide, photocatalysis

中图分类号:

TQ426
X703

汤晓蕾,董延茂,袁妍,杨雨杰. 染料敏化TiO₂光催化剂的研究进展[J]. 工业水处理, 2021, 41(10): 8-13.

Xiaolei TANG,Yanmao DONG,Yan YUAN,Yujie YANG. Research development of dye-sensitized technology on TiO₂ photocatalyst[J]. Industrial Water Treatment, 2021, 41(10): 8-13.

https://www.iwt.cn/CN/Y2021/V41/I10/8

图/表 1

参考文献 50

1	LOPES T , ANDRADE L , RIBEIRO H A , et al. Characterization of photoelectrochemical cells for water splitting by electrochemical impedancespectroscopy[J]. International Journal of Hydrogen Energy, 2010, 35 (20): 11601- 11608. doi: 10.1016/j.ijhydene.2010.04.001
2	AMOUYAL E . Photochemical production of hydrogen and oxygen from water: A review and state of the art[J]. Solar Energy Materials & Solar Cells, 1995, 38 (1/2/3/4): 249- 276. URL
3	DOU Hailong , LONG Dan , RAO Xi , et al. The photocatalytic degradation kinetics of gaseous formaldehyde flow using TiO₂ nanowires[J]. Acs Sustainable Chemistry & Engineering, 2019, 7, 4456- 4465. URL
4	KRUTH A , PEGLOW S , ROCKSTROH N , et al. Enhancement of photocatalyic activity of dye sensitised anatase layers by application of a plasmapolymerized allylamine encapsulation[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2014, 290, 31- 37. doi: 10.1016/j.jphotochem.2014.06.005
5	QIU Bocheng , XING Mingyang , ZHANG Jinlong . Mesoporous TiO₂ nano-crystals grown in situ on graphene aerogels for high photocatalysis and lithium-ion batteries[J]. Journal of the American Chemical Society, 2014, 136, 5852- 5855. doi: 10.1021/ja500873u
6	ASENCIOS Y J O , LOURENO V S , CARVALHO W A . Removal of phenol in seawater by heterogeneous photocatalysis using activated carbon materials modified with TiO₂[J]. Catalysis Today, 2020, 5, 213- 219. URL
7	CHEN Xiaoyun , KUO D H , LU Dongfang . Visible light response and superior dispersed S-doped TiO₂ nanoparticles synthesized via ionic liquid[J]. Advanced Powder Technology, 2017, 28 (4): 1213- 1220. doi: 10.1016/j.apt.2017.02.007
8	WANG Qi , QIN Zanan , CHEN Jie , et al. Green synthesis of nickel species in situ modified hollow microsphere TiO₂ with enhanced photocatalytic activity[J]. Applied Surface Science, 2015, 364 (28): 1- 8. URL
9	TAN Lichao , ZHANG Xiaofei , LIU Qi , et al. Synthesis of Fe₃O₄@TiO₂ core-shell magnetic composites for highly efficient sorption of uranium(Ⅵ)[J]. Colloids & Surfaces A: Physicochemical & Engineering Aspects, 2015, 469, 279- 286. URL
10	SHANG Xili , LI Bin , LI Changhai , et al. Preparation and enhanced visible light catalytic activity of TiO₂ sensitized with Benzimidazolone Yellow H3G[J]. Dyes & Pigments, 2013, 98 (3): 358- 366. URL
11	MONTRI A , THANATCHAPORN T , NARIT T , et al. Curcumin modified titanium dioxide nanotubes with enhanced visible light photocatalytic performance[J]. International Journal of Electrochemical Science, 2019, 14, 1954- 1967. URL
12	HE Xinghou , WANG Anzhi , WU Pian , et al. Photocatalytic degradation of microcystin-LR by modified TiO₂ photocatalysis: A review[J]. Science of The Total Environment, 2020, 743, 140- 165. URL
13	NARAYAN M R . Review: Dye sensitized solar cells based on natural photosensitizers[J]. Renewable & Sustainable Energy Reviews, 2012, 16, 208- 215. URL
14	YOUSSEF Z , COLOMBEAU L , NURLYKYZ Y , et al. Dye-sensitized nanoparticles for heterogeneous photocatalysis: Cases studies with TiO₂, ZnO, fullerene and graphene for water purification[J]. Dyes & Pigments, 2018, 159, 49- 71. URL
15	MEIER H . Photosensitization of inorganic solids[J]. Photochemistry & Photobiology, 2008, 16 (4): 219- 241.
16	DOBRUCKI J W . Interaction of oxygen-sensitive luminescent probes Ru(phen)32+ and Ru(bipy)32+ with animal and plant cells in vitro: Mechanism of phototoxicity and conditions for non-invasive oxygen measurements[J]. Journal of Photochemistry & Photobiology B: Biology, 2001, 65 (2/3): 136- 144. URL
17	AFZAL S , DAOUD W A , LANGFORD S J . Photostable self-cleaning cotton by a copper(Ⅱ) porphyrin/TiO₂ visible-light photocatalytic system[J]. Applied Materials & Interfaces, 2013, 5 (11): 4753- 4759. URL
18	YAGUB M T , SEN T K , AFROZE S , et al. Dye and its removal from aqueous solution by adsorption: A review[J]. Advance in Colloid and Interface Science, 2014, 209, 172- 184. doi: 10.1016/j.cis.2014.04.002
19	YANG Haiyan , JIANG Liang , LI Yizhou , et al. Highly efficient red cabbage anthocyanin inserted TiO₂ aerogel nanocomposites for photo-catalytic reduction of Cr(Ⅵ) under visible light[J]. Nanomaterials, 2018, 8 (11): 937. doi: 10.3390/nano8110937
20	ELSALAMONY R A , MAHMOUD S A . Preparation of nanostructured ruthenium doped titania for the photocatalytic degradation of 2-chlorophenol under visible light[J]. Arabian Journal of Chemistry, 2017, 10 (2): 194- 205. doi: 10.1016/j.arabjc.2012.06.008
21	FATIMAH I , NURILLAHI R , SAHRONI I , et al. TiO₂-pillared saponite and photosensitization using a ruthenium complex for photocatalytic enhancement of the photodegradation of bromophenol blue[J]. Applied Clay Science, 2019, 183, 105302. doi: 10.1016/j.clay.2019.105302
22	温雅琼, 李作鹏, 王玉珍, 等. [Ru(dpp)₃][(4-Clph)₄B]₂敏化TiO₂/石墨烯复合材料的制备及其光催化性能[J]. 山西大同大学学报: 自然科学版, 2015, 31 (5): 34- 37. doi: 10.3969/j.issn.1674-0874.2015.05.012
23	VALLEJO W , DIAZ-URIBE C , CANTILLO L . Methylene blue photocatalytic degradation under visible irradiation on TiO₂ thin films sensitized with Cu and Zn tetracarboxy-phthalocyanines[J]. Journal of Photochemistry & Photobiology A: Chemistry, 2015, 299, 80- 86. URL
24	LU Guifen , LIU Xudong , ZHAO Luyang , et al. Synergistic photocatalytic performance of chemically modified amino phthalocyanine-GPTMS/TiO₂ for the degradation of Acid Black 1[J]. Inorganic Chemistry Communications, 2020, 113, 795- 801. URL
25	杨晓超, 韦凤喜, 刘蓉. 磁性氧化石墨烯染料敏化复合物制备及其催化性能研究[J]. 化学与黏合, 2017, 39 (5): 328- 334. doi: 10.3969/j.issn.1001-0017.2017.05.005
26	尤会敏, 赵彦英. 2, 3, 9, 10, 16, 17, 23, 24-八羧基酞菁铁敏化TiO₂的合成及光催化性能研究[J]. 浙江理工大学学报: 自然科学版, 2016, 35 (5): 781- 787. URL
27	PRIYANKA K P , SANKARARAMAN S , BALAKRISHNA K M , et al. Enhanced visible light photocatalysis using TiO₂/phthalocyanine nanocomposites for the degradation of selected industrial dyes[J]. Journal of Alloys & Compounds, 2017, 720, 541- 549. URL
28	崔国意, 李卓, 王晨. 亚酞菁/二氧化钛纳米复合材料的制备及其光催化性能[J]. 西北大学学报: 自然科学版, 2018, 48 (2): 219- 225. URL
29	徐延明, 赵明, 李坚. 氨基酞菁-二氧化钛可见-近红外光催化剂的制备及其性能[J]. 化工学报, 2016, 67 (5): 1915- 1921. URL
30	WANG Huigang , ZHOU Dongmei , WU Zhangzhu , et al. The visible light degradation activity and the photocatalytic mechanism of tetra (4-carboxyphenyl) porphyrin sensitized TiO₂[J]. Materials Research Bulletin, 2014, 57, 311- 319. doi: 10.1016/j.materresbull.2014.06.017
31	WECHSLER D , FERNANDEZ C C , HANS-PETER S , et al. Covalent anchoring and interfacial reactions of adsorbed porphyrins on rutile TiO₂(110)[J]. Journal of Physical Chemistry C, 2018, 122 (8): 4480- 4487. doi: 10.1021/acs.jpcc.7b12717
32	LOW J , YU J , JARONIEC M , et al. Heterojunction photocatalysts[J]. Advanced Materials, 2017, 29 (20): 160- 169. URL
33	LI Zhonglu , WANG Chen , SU Zhenping , et al. New porphyrin/Cu(Ⅱ) porphyrin-TiO₂ nanohybrids for improved photocatalytic oxidation and reduction activities[J]. Materials Chemistry and Physics, 2020, 252, 123- 128. URL
34	HUANG Cheng , LV Ying , ZHOU Qin , et al. Visible photocatalytic activity and photoelectrochemical behavior of TiO₂ nanoparticles modified with metal porphyrins containing hydroxyl group[J]. Ceramics International, 2014, 40 (5): 7093- 7098. doi: 10.1016/j.ceramint.2013.12.042
35	MURCIA J , AVILA-MARTINEZ E G , ROJAS H , et al. Powder and nantubes titania modified by dye sensitization as photocatalysts for the organic pollutant elimination[J]. Nanomaterials, 2019, 9 (4): 517- 528. doi: 10.3390/nano9040517
36	李佩欣, 冯铭扬, 吴彩平. 基于电子顺磁共振的锌卟啉敏化TiO₂光催化性机理的研究[J]. 物理学报, 2015, (13): 375- 379. URL
37	HAN Xue , YANG Xiaobin , LIU Guangbo , et al. Boosting visible light photocatalytic activity via impregnation-induced RhB-sensitized MIL-125(Ti)[J]. Chemical Engineering Research and Design, 2019, 143, 90- 99. doi: 10.1016/j.cherd.2019.01.010
38	KHAN J A , SAYED M , SHAH N , et al. Synthesis of eosin modified TiO₂ film with co-exposed{001}and{101}facets for photocatalytic degradation of para-aminobenzoic acid and solar H₂ production[J]. Applied Catalysis B: Environmental, 2020, 265, 118557. doi: 10.1016/j.apcatb.2019.118557
39	徐俊英, 李越湘, 彭绍琴. 伊红Y敏化Pt负载(001)晶面占优TiO₂纳米片可见光催化制氢的研究[J]. 功能材料, 2016, 47 (1): 1066- 1071. doi: 10.3969/j.issn.1001-9731.2016.01.014
40	杜雪岩, 王峭, 续京. 曙红, 叶绿素铜三钠共敏化TiO₂纳米颗粒的光催化性能[J]. 材料导报, 2014, 28 (1): 46- 50. URL
41	SHANG Xili , LI Bin , ZHANG Tianyong , et al. Photocatalytic degradation of methyl orange with commercial organic pigment sensitized TiO₂[J]. Procedia Environmental Science, 2013, 18, 478- 485. doi: 10.1016/j.proenv.2013.04.064
42	JENNYFER D A , AUGUSTO A S , MUESE M , et al. Analysis of two dye-sensitized methods for improving the sunlight absorption of TiO₂ using CPC photoreactor at pilot scale[J]. Material Science in Semiconductor Processing, 2019, 103, 640- 651. URL
43	PHONGAMWONG T , DONPHAI W , PRASITCHOKE P , et al. Novel visible-light-sensitized Chl-Mg/P25 catalysts for photocatalytic degradation of rhodamine B[J]. Applied Catalysis B: Environmental, 2017, 207, 326- 334. doi: 10.1016/j.apcatb.2017.02.042
44	徐志兵, 严家平, 钮志远. 光敏化Ag/TiO₂催化剂的制备及其催化性能[J]. 石油化工, 2013, 42 (3): 330- 333. doi: 10.3969/j.issn.1000-8144.2013.03.016
45	CARLOS D U , WILLIAM V , ROMERO E , et al. TiO₂ thin films sensitization with natural dyes extracted from Bactris guineensis for photocatalytic applications: Experimental and DFT study[J]. Journal of Saudi Chemical Society, 2020, 24 (5): 407- 416. doi: 10.1016/j.jscs.2020.03.004
46	ABOU-GAMRA Z M , AHMED M A . Synthesis of mesoporous TiO₂-curcumin nanoparticles for photocatalytic degradation of methylene blue dye[J]. Journal of Photochemistry & Photobiology B: Biology, 2016, 160, 134- 141.
47	MONTRI A , THANATCHAPORN T , NARIT T , et al. Curcumin modified titanium dioxide nanotubes with enhanced visible light photocatalytic performance[J]. International Journal of Electrochemical Science, 2019, 14, 1954- 1967. URL
48	GOULART S , NIEVES L J J , BERNARDIN A M , et al. Sensitization of TiO₂ nanoparticles with natural dyes extracts for photocatalysis activity under visible light[J]. Dyes and Pigments, 2020, 182, 654- 662. URL
49	XIE Wanjie , PAKDEL E , LIANG Yujia , et al. Natural melanin/TiO₂ hybrids for simultaneous removal of dyes and heavy metal ions under visible light[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2019, 389, 292- 308. URL
50	史珺, 吴扬, 缪建文. 天然染料混合二氧化钛光降解醋酸纤维的研究[J]. 南通大学学报: 自然科学版, 2018, 17 (2): 18- 22. URL

[1]	靳亚斌, 徐甜甜, 赵德中, 张乐, 万振杰, 张高明. Bi₂O₃基复合光催化剂的制备及其在水处理中的应用进展[J]. 工业水处理, 2025, 45(3): 10-21.
[2]	周朝云, 令玉林, 蒋文雪, 周建红. WO₃/rGO/BiOBr的制备及其光催化降解环丙沙星废水的性能研究[J]. 工业水处理, 2025, 45(1): 73-78.
[3]	代佳汐, 姜建辉, 韩宇凡, 张文涛, 田明霞, 张园. Cd（OH）₂/BiOCl复合材料的制备及其光催化性能[J]. 工业水处理, 2024, 44(9): 136-142.
[4]	董玮, 林莉, 顾怀章, 罗云强, 马平, 李向阳. 双Z型异质结Bi₂MoO₆/Bi₂WO₆/Ag₃PO₄的光催化研究[J]. 工业水处理, 2024, 44(8): 81-89.
[5]	张宏伟, 席晓晶, 田文杰, 张慧盈, 马晓梦, 魏敏洁, 陈华军. 易回收碳纤维/g-C₃N₄纳米片阵列制备及光催化和光电催化研究[J]. 工业水处理, 2024, 44(8): 99-106.
[6]	毕付英, 孙浩然, 刘彦彦, 陈峻峰. 改性TiO₂/膨胀珍珠岩光催化剂对赤潮微藻的抑制[J]. 工业水处理, 2024, 44(7): 113-118.
[7]	郎明娇, 杨朝美, 曾广勇. 光催化膜的构筑及其在废水处理中的研究进展[J]. 工业水处理, 2024, 44(7): 47-56.
[8]	谭斌, 郝慧茹, 向宇桐, 刘宇宁, 张倩. 基于BC-BiOI/PMS的光催化体系降解恩诺沙星的研究[J]. 工业水处理, 2024, 44(6): 143-150.
[9]	黄宏森, 郑欣钰, 林振锋, 郭永福. Z型异质结BiO_2- _x /ZnWO₄对水中抗生素的光催化研究[J]. 工业水处理, 2024, 44(4): 138-146.
[10]	王宁, 林家一, 李涛, 薛安, 陈璐, 黎阳. 石墨烯基/半导体金属氧化物复合光催化剂制备工艺研究进展[J]. 工业水处理, 2024, 44(2): 63-72.
[11]	安宁, 郝玉莹, 胡绍伟, 陈鹏, 王飞, 王永, 刘芳, 李函霏. 二氧化铈/氮掺杂氮化碳光催化处理焦化废水[J]. 工业水处理, 2024, 44(12): 184-191.
[12]	解鹤, 唐彬, 陈兵兵, 李佳利, 詹海鹃. 掺杂型钴基钙钛矿的合成及光催化降解有机废水[J]. 工业水处理, 2024, 44(12): 131-137.
[13]	王钧, 付双, 侯鹏, 刘军, 孙春雪, 张洪光. S型TiO₂/CoPc异质结的构筑及光催化降解四环素的研究[J]. 工业水处理, 2024, 44(12): 118-122.
[14]	姚有智, 华飞, 吴康, 叶舟, 张忠亮, 钱程. 石墨烯基复合材料光催化降解废水有机污染物的研究进展[J]. 工业水处理, 2024, 44(11): 1-8.
[15]	刘国煜, 曹向禹, 郑建华. 钴基氧化物光催化剂在降解有机污染物中的研究进展[J]. 工业水处理, 2024, 44(11): 27-34.

选择文件类型/文献管理软件名称

选择包含的内容

染料敏化TiO₂光催化剂的研究进展

Research development of dye-sensitized technology on TiO₂ photocatalyst

RichHTML

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 1

参考文献 50

相关文章 15

编辑推荐

Metrics

本文评价

模态框（Modal）标题

选择文件类型/文献管理软件名称

选择包含的内容

染料敏化TiO2光催化剂的研究进展

Research development of dye-sensitized technology on TiO2 photocatalyst

RichHTML

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 1

参考文献 50

相关文章 15

编辑推荐

Metrics

本文评价

染料敏化TiO₂光催化剂的研究进展

Research development of dye-sensitized technology on TiO₂ photocatalyst