Research progress on modification of visible light driven photocatalytic materials

doi:10.11894/iwt.2019-0625

Abstract

Abstract:

As an advanced oxidation technology, photocatalytic oxidation has broad application prospects in organic matter removal and water quality improvement. The light source is the limiting factor for the application of photocatalytic oxidation technology. Catalytic oxidation based on visible light is an important direction for the development of photocatalytic technology. Conventional photocatalytic materials have some defects such as low visible light utilization rate, easy recombination of photogenerated electron holes, and large energy consumption in the photocatalytic reaction. In this paper, the modification of conventional photocatalytic materials driven by visible light are reviewed and their applications in the field of water treatment are prospected.

Key words: photocatalytic material, visible light, modification, organic pollutant

摘要：

作为一种高级氧化技术，光催化氧化在有机物降解、水质改善等方面具有广阔的应用前景。光源是光催化技术应用的限制性因素，基于可见光的催化氧化是光催化技术发展的重要方向。针对光催化反应中存在的可见光利用率低、光生电子空穴易于复合、能量消耗大等不足，通过对催化材料的改性可提升催化体系在可见光驱动下的光催化效率。综述了基于可见光驱动的光催化材料的改性措施及应用，展望了可见光驱动的光催化技术在水处理领域的研究方向。

关键词: 光催化材料, 可见光, 改性, 有机污染物

CLC Number:

X703

Chuangchuang Gao,Fengcui Li,Haicheng Liu,Shuangling Hao,Tingting Xue,Wei Chen. Research progress on modification of visible light driven photocatalytic materials[J]. Industrial Water Treatment, 2020, 40(5): 18-23.

高闯闯,李奉翠,刘海成,郝双玲,薛婷婷,陈卫. 可见光驱动型光催化材料改性研究进展[J]. 工业水处理, 2020, 40(5): 18-23.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/iwt.2019-0625

https://www.iwt.cn/EN/Y2020/V40/I5/18

Figures/Tables 1

References 47

1	Daghrir R , Drogui P , Robert D . Modified TiO₂ for environmental photocatalytic applications:a review[J]. Industrial & Engineering Chemistry Research, 2013, 52 (10): 3581- 3599. URL
2	Gmurek M , Olak-Kucharczyk M , Ledakowicz S . Photochemical decomposition of endocrine disrupting compounds-a review[J]. Chemical Engineering Journal, 2017, 310, 437- 456. doi: 10.1016/j.cej.2016.05.014
3	Kim S , Cho H , Joo H , et al. Evaluation of performance with small and scale-up rotating and flat reactors; photocatalytic degradation of bisphenol A, 17β-estradiol, and 17α-ethynyl estradiol under solar irradiation[J]. Journal of Hazardous Materials, 2017, 336, 21- 32. doi: 10.1016/j.jhazmat.2017.04.047
4	Fujishima A , Honda K . Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238 (5358): 37- 38. doi: 10.1038/238037a0
5	Byrne C , Subramanian G , Pillai S . Recent advances in photocatalysis for environmental applications[J]. Journal of Environmental Chemical Engineering, 2018, 6 (3): 3531- 3555. doi: 10.1016/j.jece.2017.07.080
6	Qi K , Cheng B , Yu J , et al. A review on TiO₂-based Z-scheme photo-catalysts[J]. Chinese Journal of Catalysis, 2017, 38 (12): 1936- 1955. doi: 10.1016/S1872-2067(17)62962-0
7	Paweł M , Alicja M , Beata B , et al. The role of lanthanides in TiO₂-based photocatalysis:A review[J]. Applied Catalysis B:Environmental, 2018, 233, 301- 317. doi: 10.1016/j.apcatb.2018.04.019
8	Wu R , Liu Y , Lai H , et al. Promotion effect of Pd on TiO₂ for visible light photocatalytic degradation of gaseous formaldehyde[J]. Journal of Nanoscience and Nanotechnology, 2014, 14 (9): 6792- 6799. doi: 10.1166/jnn.2014.8986
9	Niu M , Huang F , Cui L , et al. Hydrothermal synthesis, structural characteristics, and enhanced photocatalysis of SnO₂/Alpha-Fe₂O₃ semiconductor nanoheterostructures[J]. ACS Nano, 2010, 4 (2): 681- 688. doi: 10.1021/nn901119a
10	Li D , Haneda H . Morphologies of zinc oxide particles and their effects on photocatalysis[J]. Chemosphere, 2003, 51 (2): 129- 137. doi: 10.1016/S0045-6535(02)00787-7
11	Harish S , Prasad P , Archana J , et al. Synergistic interaction of 2D layered MoS₂/ZnS nanocomposite for highly efficient photocatalytic activity under visible light irradiation[J]. Applied Surface Science, 2019, 488, 36- 45. doi: 10.1016/j.apsusc.2019.05.027
12	Zou S , Fu Z , Xiang C , et al. Mild, one-step hydrothermal synthesis of carbon-coated CdS nanoparticles with improved photocatalytic activity and stability[J]. Chinese Journal of Catalysis, 2015, 36 (7): 1077- 1085. doi: 10.1016/S1872-2067(15)60827-0
13	Jonjana S , Anukorn P , Somchai T , et al. Synthesis, characterization and photocatalysis of heterostructure AgBr/Bi₂WO₆ nanocomposites[J]. Materials Letters, 2018, 216, 92- 96. doi: 10.1016/j.matlet.2018.01.005
14	Mamba G , Mishra A . Graphitic carbon nitride(g-C₃N₄) nanocomposites:A new and exciting generation of visible light driven photocatalysts for environmental pollution remediation[J]. Applied Catalysis B:Environmental, 2016, 198, 347- 377. doi: 10.1016/j.apcatb.2016.05.052
15	Malathi A , Madhavan J , Muthupandian A , et al. A review on BiVO₄ photocatalyst:Activity enhancement methods for solar photocatalytic applications[J]. Applied Catalysis A, General, 2018, 555, 47- 74. doi: 10.1016/j.apcata.2018.02.010
16	Gómez-Pastora J , Dominguez S , Bringas E , et al. Review and perspectives on the use of magnetic nanophotocatalysts(MNPCs) in water treatment[J]. Chemical Engineering Journal, 2017, 407- 427. URL
17	Zhang J , Fang J , Ye X , et al. Visible photoactivity and antiphotocorrosion performance of CdS photocatalysts by the hybridization of N-substituted carboxyl group polyaniline[J]. Applied Surface Science, 2019, 480, 557- 564. doi: 10.1016/j.apsusc.2019.03.020
18	Li D , Shi W . Recent developments in visible-light photocatalytic degradation of antibiotics[J]. Chinese Journal of Catalysis, 2016, 37 (6): 792- 799. doi: 10.1016/S1872-2067(15)61054-3
19	刘旭, 张西慧. 改性TiO₂光催化剂催化降解双酚A的研究进展[J]. 工业水处理, 2018, 38 (4): 6- 10. URL
20	王雅楠, 李俊航, 杜啟君, 等. 纳米TiO₂/Cu₂O光催化降解活性艳红X-3B的研究[J]. 工业水处理, 2018, 38 (8): 11- 14. URL
21	Yang L , Bai X , Shi J , et al. Quasi-full-visible-light absorption by D35-TiO₂/g-C₃N₄ for synergistic persulfate activation towards efficient photodegradation of micropollutants[J]. Applied Catalysis B:Environmental, 2019, 256, 117759. doi: 10.1016/j.apcatb.2019.117759
22	徐元盛, 李建伟, 马炎, 等. 硫化镉-二氧化钛/分子筛复合光催化材料制备及性能研究[J]. 无机盐工业, 2019, 51 (6): 83- 87. URL
23	Surya C , Agnel A J N , Pandiyan V , et al. Costus speciosus leaf extract assisted CS-Pt-TiO₂ composites:Synthesis, characterization and their bio and photocatalytic applications[J]. Journal of Molecular Structure, 2019, 1195, 787- 795. doi: 10.1016/j.molstruc.2019.06.030
24	欧阳琴, 江卓, 昝菱. TiO₂单晶面负载贵金属Ag形貌及其催化活性[J]. 精细化工, 2016, 33 (9): 984- 990. URL
25	Li Songtao , Li Gen , Chen Qiang , et al. Facile green synthesis of degraded-PVA coated TiO₂ nanoparticles with enhanced photocatalytic activity under visible light[J]. Journal of Physics and Chemistry of Solids, 2019, 129, 92- 98. doi: 10.1016/j.jpcs.2019.01.002
26	Yang L , Yu Y , Zhang J , et al. In-situ fabrication of diketopyrrolopyrrole-carbazole-based conjugated polymer/TiO₂ heterojunction for enhanced visible light photocatalysis[J]. Applied Surface Science, 2018, 434, 796- 805. doi: 10.1016/j.apsusc.2017.10.176
27	Mohamad F , Suriati S , Hameed B , et al. Epigrammatic progress and perspective on the photocatalytic properties of BiVO₄-based photocatalyst in photocatalytic water treatment technology:A review[J]. Journal of Molecular Liquids, 2018, 268, 438- 459. doi: 10.1016/j.molliq.2018.07.051
28	Zhang G , Chen D , Li N , et al. Fabrication of Bi₂MoO₆/ZnO hierarchical heterostructures with enhanced visible-light photocatalytic activity[J]. Applied Catalysis B:Environmental, 2019, 250, 313- 324. doi: 10.1016/j.apcatb.2019.03.055
29	Wang T , Liu X , Men Q , et al. Surface plasmon resonance effect of Ag nanoparticles for improving the photocatalytic performance of biochar quantum-dot/Bi₄Ti₃O₁₂ nanosheets[J]. Chinese Journal of Catalysis, 2019, 40 (6): 886- 894. doi: 10.1016/S1872-2067(19)63330-9
30	Wang G , Cheng D , He T. , et al. Enhanced visible light responsivephotocatalytic activity of Bi₂₅FeO₄₀/Bi₂Fe₄O₉ composites and mechanism investigation[J]. Journal of Materials Science, 2019, 30 (11): 10923- 10933. URL
31	Li Y , Zhao Y , Wu G , et al. Bi superlattice nanopolygons at BiOCl (001) nanosheet assembled architectures for visible-light photocatalysis[J]. Materials Research Bulletin, 2018, 101, 39- 47. doi: 10.1016/j.materresbull.2017.12.041
32	Hu K , Chen C , Zhu Y , et al. Ternary Z-scheme heterojunction of Bi₂WO₆ with reduced graphene oxide(rGO) and meso-tetra(4-carboxyphenyl) porphyrin(TCPP) for enhanced visible-light photocatalysis[J]. Journal of Colloid And Interface Science, 2019, 540, 115- 125. doi: 10.1016/j.jcis.2019.01.013
33	Wang Jie , Hao Xiaoyun , Jiang Youxiang , et al. Synthesis, structure, and photocatalytic activity of PANI/BiOCl nanocomposites[J]. Materials Research Express, 2019, 6 (8): 0850C1. doi: 10.1088/2053-1591/ab1fa5
34	Xu Y , Ma Y , ji X , et al. Conjugated conducting polymers PANI decorated Bi1₂O₁₇Cl₂ photocatalyst with extended light response range and enhanced photoactivity[J]. Applied Surface Science, 2018, 434, 796- 805. doi: 10.1016/j.apsusc.2017.10.176
35	高生旺, 郭昌胜, 吕佳佩, 等. 磁性BiOI/Fe₃O₄的合成及光催化降解水中的双酚S[J]. 环境工程学报, 2016, 10 (11): 6349- 6356. doi: 10.12030/j.cjee.201605012
36	李小娟, 汤端莲, 汤帆, 等. Bi₂WO₆-NiFe₂O₄磁性可见光催化剂的制备及其性能研究[J]. 功能材料, 2015, 46 (9): 9106- 9110. URL
37	Dong F , Xiong T , Sun Y , et al. A semimetal bismuth element as a direct plasmonic photocatalyst[J]. Chemical Communications, 2014, 50 (72): 10386- 10389. doi: 10.1039/C4CC02724H
38	Zhang X , Yu S , Liu Y , et al. Photoreduction of non-noble metal Bi on the surface of Bi₂WO₆ for enhanced visible light photocatalysis[J]. Applied Surface Science, 2017, 396, 652- 658. doi: 10.1016/j.apsusc.2016.11.002
39	Wu W , Zhang J , Fan W , et al. Remedying defects in carbon nitride to improve both photooxidation and H₂ generation efficiencies[J]. ACS Catalysis, 2016, 6 (5): 3365- 3371. doi: 10.1021/acscatal.6b00879
40	Dong F , Wu L , Sun Y , et al. Efficient synthesis of polymeric g-C₃N₄ layered materials as novel efficient visible light driven photocatalysts[J]. Journal of Materials Chemistry, 2011, 21 (39): 15171- 15174. doi: 10.1039/c1jm12844b
41	Kang M , Yu H , Li W , et al. Efficient Fe₂O₃/C-g-C₃N₄ Z-scheme heterojunction photocatalyst prepared by facile one-step carbonizing process[J]. Journal of Physics and Chemistry of Solids, 2019, 130, 93- 99. doi: 10.1016/j.jpcs.2019.02.017
42	Liu W , Zhou J , Hu Z . Nano-sized g-C₃N₄ thin layer@CeO₂ sphere core-shell photocatalyst combined with H₂O₂ to degrade doxycycline in water under visible light irradiation[J]. Separation and Purification Technology, 2019, 227, 115665. doi: 10.1016/j.seppur.2019.06.003
43	Huang J , Li D , Li R , et al. An efficient metal-free phosphorus and oxygen co-doped g-C₃N₄ photocatalyst with enhanced visible light photocatalytic activity for the degradation of fluoroquinolone antibiotics[J]. Chemical Engineering Journal, 2019, 374, 242- 253. doi: 10.1016/j.cej.2019.05.175
44	Wang D , Sun H , Luo Q , et al. An efficient visible-light photocatalyst prepared from g-C₃N₄ and polyvinyl chloride[J]. Applied Catalysis B:Environmental, 2014, 156/157, 323- 330. doi: 10.1016/j.apcatb.2014.03.034
45	Han H , Fu M , Li Y , et al. In-situ polymerization for PPy/g-C₃N₄ composites with enhanced visible light photocatalytic performance[J]. Chinese Journal of Catalysis, 2018, 39, 831- 840. doi: 10.1016/S1872-2067(17)62997-8
46	唐旭, 倪良, 韩娟, 等. 三元磁性氮化碳复合光催化剂的制备和表征及其在可见光下去除四环素的应用(英文)[J]. 催化学报, 2017, (3): 447- 457. URL
47	Gebrehiwot G , Pankaj B , Umesh C , et al. Novel g-C₃N₄/graphene/NiFe₂O₄ nanocomposites as magnetically separable visible light driven photocatalysts[J]. Journal of Photochemistry & Photobiology A:Chemistry, 2019, 382, 111960. URL

半导体	禁带宽度/eV	吸收波长/nm	吸收光类型	参考文献
TiO₂	3.2	387	UV	〔8〕
SnO₂	3.8	318	UV	〔9〕
ZnO	3.2	387	UV	〔10〕
ZnS	3.7	335	UV	〔11〕
CdS	2.5	496	UV、Vis	〔12〕
Bi₂WO₆	2.7	460	UV、Vis	〔13〕
g-C₃N₄	2.7	475	UV、Vis	〔14〕
BiVO₄	2.4	520	UV、Vis	〔15〕

半导体	禁带宽度/eV	吸收波长/nm	吸收光类型	参考文献
TiO₂	3.2	387	UV	〔8〕
SnO₂	3.8	318	UV	〔9〕
ZnO	3.2	387	UV	〔10〕
ZnS	3.7	335	UV	〔11〕
CdS	2.5	496	UV、Vis	〔12〕
Bi₂WO₆	2.7	460	UV、Vis	〔13〕
g-C₃N₄	2.7	475	UV、Vis	〔14〕
BiVO₄	2.4	520	UV、Vis	〔15〕

[1]	Yabin JIN, Tiantian XU, Dezhong ZHAO, Le ZHANG, Zhenjie WAN, Gaoming ZHANG. Advances in the synthesis of Bi₂O₃-based composite photocatalysts and the applications in water treatment [J]. Industrial Water Treatment, 2025, 45(3): 10-21.
[2]	Chaoyun ZHOU, Yulin LING, Wenxue JIANG, Jianhong ZHOU. Preparation of WO₃/rGO/BiOBr and its photocatalytic degradation performance for ciprofloxacin wastewater [J]. Industrial Water Treatment, 2025, 45(1): 73-78.
[3]	Wei DONG, Li LIN, Huaizhang GU, Yunqiang LUO, Ping MA, Xiangyang LI. Photocatalytic properties of dual Z-scheme Bi₂MoO₆/Bi₂WO₆/Ag₃PO₄ heterojunction [J]. Industrial Water Treatment, 2024, 44(8): 81-89.
[4]	Yiwei PAN, Qifeng FAN, Ganwei ZHANG, Shusu SHEN. Progress in preparation and application of water treatment membranes modified with imine based covalent organic frameworks [J]. Industrial Water Treatment, 2024, 44(8): 29-37.
[5]	Pan LIU. Adsorption and regeneration performances of the modified zeolite for high-concentration ammonium in real coal chemical wastewater [J]. Industrial Water Treatment, 2024, 44(7): 141-149.
[6]	Jinfeng FANG, Ying QU, Yubo ZHAO, Rupeng LIU, Zhen ZHANG, Zhen QI, Haoyu FAN, Weichen ZHU. Research progress of nitrate removal from water via capacitive deionization [J]. Industrial Water Treatment, 2024, 44(7): 29-37.
[7]	Jie ZHAO, Junfeng WU, Yanyan DOU, Fedorov Svyatoslav VIKTOROVICH, Xianli WANG, Biao LIU, Xinfeng ZHU, Yanli MAO, Hongbin GAO. Research progress on degradation of organic pollutants by single atom activated persulfate [J]. Industrial Water Treatment, 2024, 44(7): 38-46.
[8]	Yunchao CHEN, Wandan LONG, Peiqiang ZHUANG, Guolong ZHONG, Mingdong ZHANG, Jingli MU. Removal of phosphorus from aquaculture tailwater by different biochars [J]. Industrial Water Treatment, 2024, 44(7): 74-82.
[9]	Zhongqi JIA, Jinqiu WEI, Hui SU, Xianbin LIU. Research on nanoscale zero-valent iron coupled advanced oxidation process for wastewater treatment [J]. Industrial Water Treatment, 2024, 44(7): 9-18.
[10]	Fan WANG, Qiuyue FANG. Preparation and properties of PVDF membrane modified by polyethylene imine grafting/microsphere blending [J]. Industrial Water Treatment, 2024, 44(6): 165-171.
[11]	Huixia ZHANG, Chenxin XIE, Lishan ZHOU, Chunyan REN, Hui ZHAO, Taiping LEI, Lingzhi ZHU. Preparation and photo-electrocatalytic performance of Ag-Ti³⁺-TiO₂ nanocone [J]. Industrial Water Treatment, 2024, 44(3): 159-167.
[12]	Mengmeng YIN, Yuhan WANG, Kun ZHANG, Guan WANG, Weiguo XU, Bo WANG. Research progress of anti-pollution modification of nanofiltration membranes based on zwitterion [J]. Industrial Water Treatment, 2024, 44(3): 37-44.
[13]	Shiqi GUO, Wen QIN, Qingyun LI, Aixing TANG, Youyan LIU. Study on the adsorption effect and mechanism of modified Aspergillus flavus A5P1 for dye acid blue 25 [J]. Industrial Water Treatment, 2024, 44(2): 95-104.
[14]	He XIE, Bin TANG, Bingbing CHEN, Jiali LI, Haijuan ZHAN. Synthesis of doped Co based perovskite and photocatalytic degradation of organic wastewater [J]. Industrial Water Treatment, 2024, 44(12): 131-137.
[15]	Yuting XIONG, Caigui LUO, Xuekun TANG, Xianping LUO. Study on the performance of mesoporous sludge biochar for the removal of Rhodamine B [J]. Industrial Water Treatment, 2024, 44(12): 94-103.

Please choose a citation manager

Content to export