INDUSTRIAL WATER TREATMENT ›› 2012, Vol. 32 ›› Issue (3): 42-44. doi: 10.11894/1005-829x.2012.32(3).42

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Study on the treatment of U(Ⅵ)-bearing wastewater by nano zero-valent iron

Wan Xiaogang, Yang Shengya   

  1. China Academy of Engineering Physics, Mianyang 621900, China
  • Received:2011-12-05 Online:2012-03-20 Published:2012-03-19

纳米级零价铁处理含铀废水初步实验研究

万小岗, 杨胜亚   

  1. 中国工程物理研究院, 四川绵阳 621900
  • 作者简介:万小岗(1979-),2002年毕业于西安交通大学环化学院,工程师,主要从事放射性“三废”治理工作.电话:13548425533,0816-3626984,E-mail:wxg_2000@163.com.

Abstract:

The removing effectiveness of U(Ⅵ) in U(Ⅵ)-bearing wastewater by nano zero-valent iron has been studied.The effects of the dosage of nano zero-valent iron,pH and competitive ions on treatment effiency are investigated.The results indicate that the U(Ⅵ) removing rate is 99%,when the pH of simulated U(Ⅵ)-bearing wastewater is 5.The common cations have no evident influence on U(Ⅵ) removing rate,while bivalent anions,such as SO42-,CO32-,do.Under the same conditions,the removing efficiency of nano zero-valent iron is remarkably better than common iron powder,and the deoxidizing velocity is 15 times higher than that of common iron powder.

Key words: zero-valent iron, wastewater treatment, U(Ⅵ)

摘要:

研究了纳米级零价铁对废水中铀(Ⅵ)的去除效果,考察了纳米级零价铁投加量、pH及竞争离子等因素对处理效果的影响。结果表明,当模拟含铀(Ⅵ)废水的pH=5时,铀去除率达到99%。常见的阳离子对铀去除率没有明显影响,但二价阴离子SO42-、CO32-对铀去除率的影响显著。在相同条件下,纳米铁对铀(Ⅵ)的去除效果明显优于普通铁粉,还原速率比普通铁粉提高了15倍。

关键词: 零价铁, 废水处理, 铀(Ⅵ)

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