工业水处理 ›› 2017, Vol. 37 ›› Issue (7): 70-73. doi: 10.11894/1005-829x.2017.37(7).070

• 试验研究 • 上一篇    下一篇

Ca(OH)2-CaCl2沉淀法处理核工业高氟废水

邵占卫1, 杨江华2, 胡小锐3   

  1. 1. 郑州市市政工程勘测设计研究院, 河南郑州 450060;
    2. 中核建中核燃料元件有限公司, 四川宜宾 644000;
    3. 郑州亦森环保科技有限公司, 河南郑州 450051
  • 收稿日期:2017-03-27 出版日期:2017-07-20 发布日期:2017-07-31
  • 通讯作者: 胡小锐,电话:13653715925,E-mail:yisenhuanbao@163.com。 E-mail:yisenhuanbao@163.com
  • 作者简介:邵占卫(1967—),高级工程师。

Treatment of wastewater from nuclear industry by Ca(OH)2-CaCl2 precipitation process

Shao Zhanwei1, Yang Jianghua2, Hu Xiaorui3   

  1. 1. Zhengzhou City Municipal Engineering Design & Research Institute, Zhengzhou 450060, China;
    2. CNNC Jianzhong Nuclear Fuel Co., Ltd., Yibin 644000, China;
    3. Zhengzhou Yisen Environmental Protection Technology Co., Ltd., Zhengzhou 450051, China
  • Received:2017-03-27 Online:2017-07-20 Published:2017-07-31

摘要: 为强化石灰沉淀法处理高氟废水时混合液的沉降性能,采用烧杯试验,分别考察了药剂投量、混凝剂投量、药剂投加顺序、原水F-浓度等因素对泥水分离性能的影响。研究表明,联合投加Ca(OH)2 和CaCl2处理F-在5 000~10 000 mg/L的废水时,自絮凝会显著改善混合液沉降性能和出水浊度,而投加混凝剂的效果却有限。先Ca(OH)2后CaCl2的投加方式(二步法)比药剂同时投加(一步法)对沉降性能有较大的改善。运用分步加药法在中试规模的同程水平流斜板沉淀池实现了良好的固液分离效果。

关键词: 含氟废水, 沉降性能, 自絮凝, 同程水平流斜板沉淀池

Abstract: In order to enhance the lime sedimentation performance of mixed liquid in the treatment of wastewater containing highly concentrated fluoride by lime precipitation process,beaker tests have been used for investigating the influences of factors,such as chemical agent dosages,coagulant dosage,dosing sequence of the chemical agents, F- concentration in raw water,etc. on the muddy/water separation performance,respectively. The research results show that when adding Ca(OH)2 and CaCl2 jointly for the treatment of F-(5 000-10 000 mg/L)in wastewater,the self- flocculation can obviously improve the sedimentation performance and effluent turbidity of the mixed liquid,but the effect of adding coagulant is limited. The sedimentation performance of the pattern of Ca(OH)2 first and CaCl2 last (two additions)can make greater improvement than that of the pattern of adding agent simultaneously(one addition). Good solid/liquid separation effect can be achieved by a multi-step dosing method in a pilot-scale same-flow-path horizontal flow inclined board settling tank.

Key words: fluoride containing wastewater, sedimentation capacity, self-flocculation, same-flow-path horizontal flow inclined board settling tank

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