工业水处理 ›› 2008, Vol. 28 ›› Issue (2): 20-22. doi: 10.11894/1005-829x.2012.28(2).20

• 试验研究 • 上一篇    下一篇

PAC絮凝—膜分离法处理油田废水的研究

李爱阳1, 朱志杰2   

  1. 1. 湖南工学院化工系, 湖南衡阳 421008;
    2. 中南大学化学化工学院应用化学系, 湖南长沙 410083
  • 收稿日期:2007-09-27 出版日期:2008-02-20 发布日期:2010-10-01
  • 作者简介:李爱阳(1969- ), 2006年毕业于中南大学, 硕士, 副教授。电话: 13337349883, E-mail:layllp@126.com。
  • 基金资助:

    衡阳市2006年工业科研开发计划项目(06KG59);湖南工学院科研项目(HGY0530)

Study on oilfield wastewater treatment by PAC flocculation-membrane separation

Li Aiyang1, Zhu Zhijie2   

  1. 1. Chemical Engineering Department, Hunan Institute of Technology, Hengyang 421008, China;
    2. Applied Chemistry Department, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • Received:2007-09-27 Online:2008-02-20 Published:2010-10-01

摘要:

油田开发生产过程中产生和排放的含油废水含有多种污染物, 严重污染了生态环境。石油工业含油废水常用PAC絮凝法处理, 但处理后废水的含油量、CODCr难以达标。作者采用PAC絮凝—膜分离法联合处理油田含油废水, 效果显著。实验结果表明:处理后的含油废水出水水质与絮凝条件、过滤条件等操作参数有关。当PAC投加质量浓度为70~80 mg/L, 反应pH为7~8, 反应时间为70 min, 微滤过滤温度为40℃, 错流速度为2 m/s时, 含油废水中的油、CODCr和悬浮物的去除率分别达到99%、98%和91%, 出水水质可达一级排放标准。

关键词: 絮凝, 膜分离, 含油废水, 废水处理

Abstract:

In petroleum production, many kinds of pollutants come into being and are discharged, polluting the ecological environment badly. PAC flocculation was usually applied to the treatment of oil-bearing wastewater in petroleum production. However, the oil-bearing content and CODCr of the wastewater are difficult to reach the criteria by this method. But when PAC flocculation-membrane separation is applied to the treatment of oil-bearing wastewater, remarkable effect has been obtained. The results show that the water quality of the treated oil-bearing wastewater is related to the operational parameters of flocculation condition, filtration condition, etc. When the dosage of PAC is 70-80 mg/L, pH value is 7-8, reaction time is 70 min, micro-filtration temperature is 40℃, and the velocity of flow are 2m/s, the removal rates of oil, CODCr and suspension substances are up to 99%, 98% and 91% respectively. The effluent water quality could reach the first class standard of discharge.

Key words: flocculation, membrane separation, oil-bearing wastewater, wastewater treatment

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